MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT/MANUFACTURER S IDENTITY
Formula ID Number: SM10
Mark 10 Bathroom Cleaner
Product Name:
MSDS File Name: MARK 10 BATHROOM CLNR HAZARD
Concentrate In Dilution
RATING
ST-734, ST-746 EPA Reg #: None
Synonyms:
4 = Extreme
DOT Hazard Class: ORM-D 0 0
Flammability
3 = High
Stearns Packaging Corporation DOT Shipping Name: Consumer Commodity, ORM-D
Company: 2 1
Health
2 = Moderate
4200 Sycamore Avenue (53714) Hazard Label: ORM-D 0 0
Reactivity
1 = Slight
PO Box 3216
NSF Certified: C2, 7/20/04 None None
Special Hazard 0 = Insignificant
Madison, WI 53704-0216
800-655-5008
Phone:
Abbreviation Key: N.A.=Not Applicable,
Emergency Contact: CHEM-TEL, 800-255-3924
608-246-5149
Fax:
N.D.=Not Determined
www.stearnspkg.com
Website:
SECTION 2 HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
CHEMICAL IDENTIFICATION CAS NO. OSHA PEL ACGIH TLV OTHER LIMITS %(Optional)
Water 7732-18-5
Phosphoric acid 7664-38-2 1 mg/m3 1 mg/m3 3 mg/m3 (STEL) 25-35
Alkyl dimethyl benzyl ammonium chloride 68391-01-5 5
Alkyl dimethyl ethyl benzyl ammonium chloride 68956-79-6 5
Polyethylene glycol mono nonyl phenyl ether 9016-45-9 1-3
SARA Section 313 Title III Notification Required: Yes; Chemical in Product: Phosphoric acid; CAS#: 7664-38-2; Weight % of Chemical: 25-35
SECTION 3 PHYSICAL DATA
Solubility in water: Complete Vapor Pressure (mm Hg): N.D. pH (Concentrate): 0.28
Appearance and Odor:
Clear liquid, slight detergent Boiling Point: N.D. Vapor Density (Air=1): N.D. pH (1% Solution): 1.9 @ 22?C
chemical odor, no fragrance Melting Point: N.A. Evaporation Rate (Water=0.3): N.A. Specific Gravity: 1.182
added
SECTION 4 FIRE AND EXPLOSION HAZARD DATA
Flash Point and Method: Non-combustible, >200癋 Special Fire Fighting Procedures: Use full protective clothing and self-contained
breathing apparatus. Thermal decomposition emits toxic fumes of oxides
LEL: N.A.
Flammable Limits 3
of phosphorous and sulfur.
UEL: N.A.
Extinguishing Media: CO2, water, dry chemical Unusual Fire & Explosion Hazards: Extinguish all nearby sources of ignition since
flammable hydrogen gas will be liberated from contact with some metals.
Reacts violently with strong bases.
SECTION 5 REACTIVITY DATA
Chemical Stability: Stable: X Unstable: Hazardous Polymerization: May Occur Will Not Occur X
Conditions to Avoid: Freezing and extremes of heat. Hazardous Decomposition or By-Products: Oxides of phosphorous upon
decomposition and at flame temperatures.
Incompatibility (Materials to Avoid): Strongly alkaline (caustic) materials,
reactive metals (mild steel, aluminum), nitric acid, cyanides or sulfides.
SECTION 6 HEALTH HAZARD DATA/FIRST AID PROCEDURES
Health Hazards (Acute and Chronic): Irritation or corrosion may occur to Emergency and First Aid Procedures:
exposed tissues, especially eyes, skin, throat, nasal cavities and other Eyes: Flush with cool water for at least 15 minutes. Consult a physician.
mucous membranes from contact with the product, its use solutions, Skin: May be irritating. If contact occurs, flush with water and wear gloves in
or mists and vapors generated by the product. Eye contact may cause the future to minimize exposure. Wash hands after handling. Discontinue
blindness. Ingestion may be harmful or fatal. use if irritation persists and consult a physician.
Signs and Symptoms of Exposure: Irritation of exposed tissues. Chronic Inhalation: Remove from exposure. Obtain medical attention immediately.
exposure causes burns. Eyes, skin and mucous membranes may be Ingestion: May be harmful if swallowed. Drink large amounts of water or milk.
DO NOT induce vomiting. Get medical attention immediately. Avoid
simultaneously irritated or burned if exposed to mists of product or
solutions. contamination of foods.
Medical Conditions Aggravated by Exposure: Dermatitis.
Carcinogenicity: IARC Monographs? Yes No X
NTP? Yes No X OSHA Regulated? Yes No X
NOTE TO PHYSICIAN: Extremely corrosive agent which will burn exposed tissues upon (other than very brief) contact. Flush eyes, skin and mucous
membranes with water. Consult an ophthalmologist for any corneal burns. In case of ingestion, dilute with water, milk or demulcent liquids, but
attempts to neutralize with a base should be avoided because of excessive base and heat formation, which may increase the threat of esophagogastic
perforation. Vomiting and diarrhea (laxative effect of phosphates) are to be expected with large doses. Parenteral fluid administration may be needed if
losses are severe, or if shock ensues. Use supportive care for complication such as glottal edema, hematemesis and perforation (unlikely). Induced
vomiting should be avoided because local tissue injury may be aggravated. Watch the patient for hyperphospaternia and hypocalcemia. Milk or other
demulcent liquids may be worthwhile for gastric irritation.
SECTION 7 PREVENTATIVE AND CONTROL MEASURES
Steps to be Taken if Material is Spilled or Released: Small spills: Mop up and
Ventilation: Local Exhaust: To control below TLV of 1 ppm for phosphoric
dispose of in DOT approved waste container. Large spills: Contain by
acid in 8 hours.
diking with soil or other absorbent material and carefully neutralize with
Mechanical: To control below TLV of 1 ppm for phosphoric acid
soda ash or lime. If soda ash is used, provide adequate ventilation to
in 8 hours.
dissipate carbon dioxide gas. Keep unneutralized material out of sewers,
Skin Protection: Use neoprene, rubber, or other chemical resistant gloves.
storm drains, surface waters and soil.
Eye Protection: Avoid eye contact.
Waste Disposal: Comply with all local, state and federal regulations. Consult
Respiratory Protection: In general, respirators are not needed if the product is
your state DNR or the EPA for specific questions. Wastewater should
used in a well-ventilated area.
never enter a fresh water body without treatment.
Other Precautions: Empty container may have residues, gases and mists,
and are subject to proper waste disposal, as above. Always obey Handling and Storage: Store in a dry, well-ventilated place, above 50癋. Store
away from all other chemicals and potential sources of contamination. Do
hazard warnings and handle empty containers as if they were full.
not use pressure to empty container. Wash thoroughly after handling. Do
Keep out of the reach of children.
not get in eyes, on skin, or on clothing.
SECTION 8 OTHER REGULATORY INFORMATION
California Safe Drinking Water and Toxic Enforcement Act of 1986: Ethylene oxide 75-21-8
Massachusetts & Pennsylvania Right-to-Know law: Ethylene Oxide 75-21-8 rev. 07/09/09
This MSDS data relates only to the material designated and does not relate to its use with any other material or process. The data is believed to be accurate. However, since use conditions
vary and are outside our control, Stearns Packaging Corporation makes no warranties, expressed or implied, and assumes no liability for failure to follow directions and safety precautions.
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