MATERIAL SAFETY DATA SHEET
S E C TION 1 - CHEMICAL AND COMPANY I D E N T I F I C AT I O N
IDENTITY DATE PREPARED
FluoroEtch?Safety Solvent May 14, 2008
SYNONYMS, CHEMICAL NAMES, COMMON NAMES USE
Sodium Naphthalene Complex in Glycol Ether Fluorpolymer Etchant
SUPPLIER'S NAME EMERGENCY TELEPHONE NUMBER
Acton Technologies CHEMTREC: 800-424-9300
ACTON Certification #10102.01 Certification #40102.01
TECHNOLOGIES
NOR T H A M E R I C A N O P E R A T I O N S E U R O PEAN OPERATIONS O N L I N E O R D E R I N G : W W W . A C T ONTECH.COM
100 THOMPSON STREET P.O. BOX 726 ADARE COUNTY LIMERICK
PITTSTON, PENNSYLVANIA 18640 USA IRELAND A N I S O 9 0 0 1 C E R T I F I E D COMPANY
INQU I R I E S , O R D E R S A N D T E C H N I C A L A S S I S T A NCE: A N I S O 1 4 0 0 1 C E R T I F I E D COMPANY
PHONE: +353.61.395.222
PHONE: 570.654.0612
FAX: 570.654.2810 FAX: +353.61.395.333
S E C TION 2 - COMPOSITION, INFORMATI O N O N I N G R E D I E N T S
HAZARDOUS COMPONENTS OSHA PEL ACGIH TLV %
2-Methoxyethyl ether (CAS# 111-96-6) None established None established >80%
Sodium Naphthalene Complex None established None established <20%
(CAS# 7440-23-5) 10 ppm TWA 10 ppm TWA
(CAS# 91-20-3) 15 ppm STEL
R 19, R 22, R 36/37/38, R 60, R 61, N, R 51/53, S 7, S 16, S 26, S 36/37/38, S 45, S 53
Remaining components, if any, are not hazardous or hazardous components are present at less than 1% (0.1% for carcinogens).
EME R G E N C Y O V E R V I E W
Combustible liquid and vapor. May form explosive peroxides. May be irritating to skin, eyes, respiratory, and/or digestive tract.
May cause skin sensitization. Reproductive hazard.
S E C TION 3 - HAZARDOUS IDENTIFICATIO N
PRIMARY ROUTE(s) OF EXPOSURE: Inhalation; skin; eyes; ingestion
IRRITATION DATA:
Open irritation test: Dermal (Rabbit): mild reaction @495 mg Naphthalene
Standard Draize test: Eye (Rabbit): mild @100 mg Naphthalene
?2008 Acton Technologies, Inc. FluoroEtch?is a registered trademark of Acton Technologies, Inc. Rev. 1/1
M AT E R I A L S A F E T Y D ATA S H E E T
INHAL ATIO N
Breathing of mists, vapors, or fumes may irritate the nose, throat, and lungs. Symptoms may include drowsiness,
ACUTE:
dizziness, headache, incoordination, difficulty breathing, blurred vision, fatigue, stomach pain, nausea, or vomiting,
tremors, convulsions, loss of consciousness, cyanosis, central nervous system depression, coma, respiratory arrest
and death, depending on the concentration and duration of exposure.
Male reproductive effects. The glycol ether solvent may be a reproductive risk for women of child bearing poten-
CHRONIC:
tial. Overexposure may lead to altered kidney function and blood abnormalities.
SKIN CONTACT
Skin contact may cause mild alkali burns. Can cause skin photosensitization. Harmful if absorbed through the skin.
ACUTE:
CHRONIC: May cause allergic reactions to certain individuals. Prolonged exposure can cause dermatitis.
EYE CONTACT
ACUTE: May cause irritation, pain, conjunctivitis, and possible corneal damage.
CHRONIC: May cause conjunctivitis. Overexposure may lead to development of lenticular (eye) opacity and possible cataract
formation.
INGESTION
ACUTE: May cause irritation of the mouth, throat, and gastrointestinal tract. May cause central nervous system depression
or effects. May cause headache, pain, visual disturbance, salivation, dizziness, diarrhea, and nausea.
CHRONIC: Toxic to kidneys. Overexposure may cause blood abnormalities such as hypochromia, anemia, and polynucleosis.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Persons with pre-existing skin, eye or respiratory tract conditions may be at increased risk from exposure.
SECTION 4 - EMERGENCY AND FIRST AID PROCEDURES
INHALATION: Remove from exposure to fresh air immediately. If breathing has stopped, give artificial respiration. Oxygen may be given if breathing
is difficult. Get medical attention immediately.
SKIN CONTACT: Remove contaminated clothing and shoes immediately. Wash affected area with soap and water until no evidence of the chemical
remains. Get medical attention if irritation develops.
EYE CONTACT: Flush thoroughly with water for at least 15 minutes, occasionally lifting the upper and lower lids, until no evidence of the chemical
remains. Get immediate medical attention.
INGESTION: Get immediate medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT FLAMMABLE LIMITS: LEL: 1.5
158?F (Cleveland Open Cup) (Glycol ether solvent) UEL: 17.4
AUTOIGNITION TEMPERATURE: 370?F
SENSITIVITY TO MECHANICAL IMPACT: Not available
SENSITIVITY TO STATIC DISCHARGE: Not available
EXTINGUISHING MEDIA: Dry Chemical, Alcohol Foam, Water Spray, CO2
FIRE AND EXPLOSION HAZARDS: Combustible liquid. May be ignited by heat, sparks, or flames. Vapors may travel to a source
of ignition and flash back. Container may explode in heat of fire.
?2008 Acton Technologies, Inc. FluoroEtch?is a registered trademark of Acton Technologies, Inc. Rev. 1/1
M AT E R I A L S A F E T Y D ATA S H E E T
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters should wear NIOSH approved positive pressure self-contained breathing apparatus and protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Water will deactivate the sodium in FluoroEtch?and form a caustic solution. Solution is non-pyrophoric.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Steps to be taken if material is released or spilled:
Isolate from all ignition sources. Keep ignition sources out of the area.
Flood with water.
Neutralize with acetic or hydrochloric acid.
Absorb the solution in sand, inert absorbent, or caustic spill kit.
SECTION 7 - HANDLING AND STORAGE
FOR INDUSTRIAL USE ONLY
HANDLING
Wear protective equipment when opening container or using liquid.
Follow procedure for flammable and caustic materials.
Open cautiously to gently release any build up of pressure.
Sources of static discharge must be grounded.
Warm to room temperature prior to use.
Do not return used portions to original container.
Use with adequate ventilation.
STORAGE
Store in a cool place, away from heat, sources of ignition, and incompatibles.
Keep container tightly closed when not in use.
Avoid long exposure to the atmosphere.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
RESPIRATORY PROTECTION
Where airborne concentrations may exceed guidelines for permissible air concentrations, choose a respirator in accordance with OSHA Respirator
Standard 29 CFR 1910.134.
VENTILATION
Local exhaust recommended. Use protection in the absence of adequate ventilation.
PROTECTIVE GLOVES
Use impervious butyl or neoprene rubber or polyethylene gloves chosen in accordance with OSHA Personal Protective Equipment Standard 29 CFR
1910.132.
EYE PROTECTION
Use safety glasses with side shields, chemical goggles, or face shield chosen in accordance with
OSHA 29 CFR 1910.133.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Appropriate protective clothing to minimize skin contact with this material. If conditions warrant, use butyl rubber apron and boots. Emergency eye wash
fountain and shower should be available
RECOMMENDED EXPOSURE LIMITS
The manufacturer suggest the following occupational exposure limits for the glycol ether:
5 ppm TWA: occupational exposure limit
25 ppm: short term exposure limit
For women of child bearing potential, the manufacturer recommends an occupational exposure limit of 1 ppm (8hour TWA) and a STEL of 5 ppm.
?2008 Acton Technologies, Inc. FluoroEtch?is a registered trademark of Acton Technologies, Inc. Rev. 1/1
M AT E R I A L S A F E T Y D ATA S H E E T
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT 162癈 glycol ether SPECIFIC GRAVITY 1.04
PH Alkaline MELTING POINT -64?deg C
VAPOR PRESSURE (mm Hg) 1.7 @ 20癈 VISCOSITY Not applicable
VAPOR DENSITY (Air = 1) 4.6 EVAPORATION RATE 0.36
(Butyl acetate = 1)
SOLUBILITY IN WATER ~90%
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not available.
ODOR THRESHOLD: >0.3ppm (naphthalene)
APPEARANCE AND ODOR: Green black liquid with odor of naphthalene and ether.
SECTION 10 - STABILITY AND REACTIVITY
STABILITY Unstable Conditions to Avoid:
Stable X If exposed to air, organic peroxides may develop.
INCOMPATIBILITY (Materials to Avoid)
Water, oxidizing materials.
HAZARDOUS DECOMPOSITION PRODUCTS
Reacts with water to form caustic soda, naphthalene, glycol ether, and peroxides. Heating to decomposition can emit acrid smoke and fumes.
HAZARDOUS May Occur Conditions to Avoid
POLYMERIZATION Will Not Occur X None known.
SECTION 11 - TOXICOLOGICAL INFORMATION
Oral LD50 (rat): 5400 mg/kg 2-Methoxyethyl ether
Ipr LD50 (mouse): 4 gm/kg Sodium
Oral LD50 (rat): 490 mg/kg Naphthalene
Inh LC50 (rat): >340 mg/m3/1H Naphthalene
Dermal LD50 (rat): >2500 mg/kg Naphthalene
Reproductive data: RTECS 2-Methoxyethyl ether; Naphthalene
Mutagen data: RTECS 2 Methoxyethyl ether; Naphthalene
Tumorigenic data: RTECS Naphthalene
Teratogenic effects have been demonstrated to occur causing birth defects and reversible testicular and sperm damage in some glycol ethers. A study
with laboratory animals indicates that chronic alcohol (ethanol) ingestion may increase the potential for teratogenic or other toxic effects from exposure
to glycol ethers and diethers. There may be a particular risk for women of child bearing potential regarding this compound. Exposure to vapors or mists
should be avoided, especially for women of child bearing potential.
Skin Sensitization: Naphthalene: positive
Toxicologically synergistic materials: Chronic alcohol (ethanol) ingestion may increase the potential for teratogenic or other toxic effects
from exposure to glycol ethers and diethers.
Carcinogenicity: Not listed by IARC, NTP, or ACGIH
Target Organs: Skin, eyes, digestive tract, kidney, blood, CNS, and reproductive system.
?2008 Acton Technologies, Inc. FluoroEtch?is a registered trademark of Acton Technologies, Inc. Rev. 1/1
MATERIAL SAFETY DATA SHEET
SECTION 12 ?ECOLOGICAL INFORMATION
This product has not been tested for ecological impact information.
The components of this material may be considered a water pollutant and releases of this product should be prevented from contaminating soil and water
and from entering drainage and sewer systems. If product is released to the environment, take immediate steps to stop and contain release. Caution
should be exercised regarding personnel safety and exposure to the released product. Notify local authorities and the National Response Center, if required.
This product is not biodegradable or biodegrades very slowly in the environment.
2-Methoxyethyl ether has a fish and bacterial toxicity (LCO) of >1000 mg/L.
SECTION 13 ?DISPOSAL CONSIDERATIONS
Dilute with water, neutralize with acid, filter solids.
Dispose of solids and neutralized liquid in accordance with all applicable federal, state, and local environmental regulations.
SECTION 14 ?TRANSPORT INFORMATION
Dot: Not regulated
Not applicable
Shipping name:
Not applicable
Hazard Class:
Not applicable
Packing group:
SECTION 15 ?REGULATORY INFORMATION
This material is classified as hazardous under OSHA regulations.
OSHA:
TSCA: All components are listed.
All components are listed.
EINECS:
All components are listed.
DSL:
This material is a B3, D2A, D2B Controlled Product. This material has been classified in accordance with the hazard criteria of the
WHMIS:
CPR and the MSDS contains all the information required by the CPR.
EU:
R 19 May form explosive peroxides S7 Keep container tightly closed
R 22 Harmful if swallowed S 16 Keep away from sources of ignition
R 36/37/38 Irritating to eyes, respiratory S26 In case of contact with eyes, rinse
system, and skin immediately with plenty of water and seek
medical attention
R 60 May impair fertility S36/37/38 Wear suitable protective clothing, gloves,
and eye/face protection
R 61 May cause harm to the unborn S53 Avoid exposure-obtain special instructions
child before use.
N, R51/53 Toxic to aquatic animals; may
cause long-term adverse effects in
the aquatic environment
?2008 Acton Technologies, Inc. FluoroEtch?is a registered trademark of Acton Technologies, Inc. Rev. 1/1
MATERIAL SAFETY DATA SHEET
SARA TITLE III - TOXIC CHEMICALS LIST 40 CFR 372.65:
2-Methoxyethyl ether CAS# 111-96-6 >80%
Naphthalene CAS# 91-20-3 <20%
SARA HAZARD CATEGORIES:
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure No
Reactivity No
CERCLA HAZARDOUS SUBSTANCES 40 CFR 302:
91-20-3
Naphthalene RQ: 100 pounds
RCRA HAZARDOUS WASTE CODES 40 CFR 261.21, 261.23:
As purchased, this material is not a RCRA hazardous waste.
CALIFORNIA PROPOSITION 65:
This product contains the following chemicals known to the State of California to cause cancer or reproductive harm: None
S E CTION 16 - OTHER INFORMATION
HMIS Rating NFPA Rating
Health 2 Health 2
Flammability 2 Flammability 2
Reactivity 1 Reactivity 1
Where 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe
This data is furnished gratuitously, independent of any sale of the product, and only for your independent investigation
and verification. While this data is believed to be correct, Acton makes no representation as to the accuracy of the data.
Acton makes no warranties, guaranties, or representations of any kind or nature with respect to this product or this data,
either expressed or implied, and whether arising by law or otherwise, including but not limited to any implied warranty of
merchantability or fitness for any particular purpose. Acton shall in no event be liable for any personal injury, property or
other damages of any nature whatsoever, whether special, indirect, consequential or compensatory, directly or indirectly
resulting from the publication or use or of reliance upon this data.
ACTON Certification #10102.01 Certification #40102.01
TECHNOLOGIES
NOR T H A M E R I C A N O P E R A T I O N S E U R OPEAN OPERATIONS O N L I N E O R D E R I N G : W W W . A C T ONTECH.COM
100 THOMPSON STREET P.O. BOX 726 ADARE COUNTY LIMERICK
PITTSTON, PENNSYLVANIA 18640 USA IRELAND A N I S O 9 0 0 1 C E R T I F I E D COMPANY
INQ U I R I E S , O R D E R S A N D T E C H N I C A L A S S I S T ANCE: A N I S O 1 4 0 0 1 C E R T I F I E D COMPANY
PHONE: +353.61.395.222
PHONE: 570.654.0612
FAX: 570.654.2810 FAX: +353.61.395.333
?2008 Acton Technologies, Inc. FluoroEtch?is a registered trademark of Acton Technologies, Inc. Rev. 1/1
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