FLUOROPOLYMER
ETCHANT
MATERIAL SAFETY
DATA SHEET
SECTION I - IDENTIFICATION
PRODUCT NAME: FLuoropolymer GENERIC DESCRIPTION: Sodium Naphthalene Complex in
Etchant Glycol Ether
PROPER SHIPPING NAME (49CFR 172.101):
MANUFACTURER: RELTEK, LLC
2345 Circadian Way D.O.T. HAZARD NAME (49CFR 172.101): Not regulated
Santa Rosa, CA 95407 D.O.T. ID NO (49CFR 172.101): Not regulated
(707) 284-8808 D.O.T. HAZARD CLASS (49CFR 172.101): Not applicable
RCRA HAZARD CLASS (40CFR 261.21, .23)(if
(800) 535-5053 discarded): Not RCA Hazardous Waste
EMERGENCY: E.P.A. PRIORITY POLLUTANTS (40CFR 122.53):
02-21-07 Rev a HEALTH (NFPA): Not applicable
DATE: NA FLAMMABILITY (NFPA): 2
SUPERSEDES: REACTIVITY (NFPA): 2
SARA SEC 312: Fire, Pressure:, Reactivity: 1
(EPCRA) Acute, Chronic: Yes, No, No
Yes, Yes
SECTION II - HAZARDOUS INGREDIENTS 29 CFR 1910.1200
------ EXPOSURE LIMITS -----
INGREDIENT C.A.S. NO. PERCENT VALUE UNIT TYPE AUTH
2 Methoxyethyl ether 111-96-6 >80% Not established
Sodium Naphthalene Complex 7440-23-5 <20% Not established
91-20-3 <20% 10ppm TWA, 15 ppm STEL
SECTION III - PHYSICAL DATA
BOILING POINT: [760 MM HG] VOLATILITY BY WEIGHT: Not established
162C
SPECIFIC GRAVITY:[77EF/25EC] EVAPORATION RATE: .36
1.04
MELTING POINT: SOLUBILITY IN WATER: approx 90%
-64 C
VAPOR PRESSURE: [77EF/25EC] ODOR: Naphthalene and ether
1.7 @ 20
VAPOR DENSITY: [77EF/25EC] APPEARANCE: / COLOR: Green black liquid
4.6
SECTION IV - HEALTH HAZARD DATA
EYE: Acute: May cause irritation, pain, conjunctivitis, and possible corneal Flush thoroughly with water for at
damage. least 15 minutes, occasionally lifting
Chronic: May cause conjunctivitis. Overexposure may lead to the upper and lower lids until no
development of lenticular (eye) opacity and possible cataract evidence of the chemical remains.
formation. Get immediate medical attention
Remove contaminated clothing and
SKIN: shoes immediately. Wash affected
Acute: Skin contact may cause mild alkali burns. Can cause skin area with soap and water until no
photosensitization. Harmful if absorbed through the skin evidence of the chemical remains.
Chronic: May cause allergic reactions to certain individuals. Prolonged Get medical attention if irritation
exposure can cause dermatitis. develops.
Move away from exposure to fresh air
INHALATION: immediately. If breathing has
Acute: Breathing of mists, vapors or fumes may irritate the nose, throat an stopped, give artificial respiration.
lungs. Symptoms may include drowsiness, dizziness, headache, incoordination, Oxygen may be given if breathing is
difficulty breathing, blurred vision, faticgue, stomach pain, nausea or vomiting, difficult. Get medical attention
tremors, convultions, loss of conciousness, cyanosis, central nervous system immediately.
depression, coma, respiratory arrest and death, depending on the
concentration an duration of exposure.
Chronic: Male reproductive effects. The glycol ether solvent may be a
reproductive risk for women of child bearing potential. Overexposure may
lead to altered kidney function and blood abnormalities. Get immediate medical attention.
ORAL
Acute: May cause irritation of the mouth, throat, and gastrointestinal tract.
May cause central nervous system depression or effects. May cause headache,
pain, visual disturbance, salivation, dizziness, diarrhea and nausea
Chronic: Toxic to kidneys. Overexposure may cause blood abnormalities such
ad hypochondria, anemia and polynucleosis.
COMMENTS:
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SECTION V - FIRE AND EXPLOSION DATA
FLASH POINT: SPECIAL FIRE NIOSH approved positive pressure self-
Open cup, 158F
FIGHTING contained breathing apparatus and
AUTOIGNITION: PROCEDURES: protective clothing should be worn. Use
379F
Dry chemical, Alcohol Foam, Water Spray,
FLAMMABILITY LIMITS IN AIR: CO2
LOWER: 1.5
UPPER: 17.4
OSHA FIRE HAZARD CLASS:
UNUSUAL FIRE Reacts with water to form caustic soda,
N/D
EXTINGUISHING MEDIA: AND EXPLOSION naphthalene, glycol ether, and peroxides.
HAZARDS: Solution is non-pyrophoric.
Dry chemical X Alcohol Foam X
Water Spray X CO2
SECTION VI - REACTIVITY DATA
STABILITY: Stable HAZARDOUS
DECOMPOSITION Caustic soda, naphthalene, glycol ether
INCOMPATIBILITY: Water, oxidizing materials PRODUCTS: and peroxides.
CONDITIONS TO AVOID:
None known POLYMERIZATION: Will not occur.
SECTION VII - SPILL, LEAK, MAINTENANCE/REPAIR AND DISPOSAL PROCEDURES
SPILL Isolate from all ignition sources. Keep ignition REPORTABLE HAZARD: None
RESPONSE: sources out of area. Flood with water. Neutralice
with acetic or hydrochloric acid. Use absorbent REPORTABLE CONCENTRATION: Not applicable
material to collect and contain for salvage or disposal
in closed container. REPORTABLE QUANTITY: Not applicable
WASTE Dilute with water, neutralize with acid, filter solids.
DISPOSAL Dispose of solids and neutralized liquid in accordance
METHOD: with all applicable federal, state and local
environmental laws. Since regulations vary, consult
applicable regulations before disposal.
SECTION VIII - PRECAUTIONS FOR SAFE HANDLING
EYES: Use safety glasses with side shields, EXHAUST: Recommended
chemical goggles of face shield chosen in MECHANICAL: Recommended
accordance with OSHA 19 CFR 1910.133
Emergency eye wash fountain should be PRECAUTIONS TO Wear protective equipment when opening
available. BE TAKEN IN container or using liquid. Follow procedure
SKIN: Use impervious butyl or neoprene rubber or HANDLING AND for flammable and caustic materials. Open
polyethylene gloves chosen in accordance STORING: cautiously to gently release any build up of
with OSHA Personal Protective Equipment pressure. Sources of static discharge must
Standard 29 CFR 1910.132. Appropriate be grounded. Warm to room temperature
protective clothing to minimize skin contact prior to use. Do not return used portions to
with this material. If conditions warrant, original container. Use with adequate
use butyl rubber apron and boots. ventilation. Store in a cool place, away
Emergency shower should be available. from heat, sources of ignition, and
Where airborne concentrations may exceed incompatibles. Keep container tightly
INHALATION guidelines for permissible air concentrations closed when not in use. Avoid long
AND choose a respirator in accordance with exposure to the atmosphere.
VENTILATION: OSHA Respirator Standard 29 CFR
1910.134. Local exhaust recommended. Recommended Exposure Limits for glycol
Use protection in the absence of adequate COMMENT: ether:
ventilation. 5 ppm TWA: occupational exposure limit
25 PPM: short term exposure limit.
For women of child bearing potential, an
occupational exposure limit of 1ppm (8 hour
TWA) and a STEL of 5 ppm.
SECTION IX ?COMMENTS
OSHA Hazard Communication Standard (29CFR1910.1200) hazard class: EPA SARA Title III Section 312 (40CFR372.65) hazard class:
Immediate Health Hazard, Delayed health hazard. EPA SARA Title III Section 313 (40CFR372) toxic chemicals above "de minimis" levels:
2-Methoxyethely ether >80%, Naphthalene <20%. TSCE, EINECS, DSL: All components are listed. WHMIS: This material is a B3, D2A,
D2B Controlled Product. This material has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all
the information required by the CPR.
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