Material Safety Data Sheet chemcan
Section I. Chemical Product and Company Identification
VANFRE?UN
Product Name/ Code 49753
Trade Name
Mixture
CAS#
Supplier R.T. VANDERBILT COMPANY, INC.
In case of Call (203)853-1400
30 WINFIELD STREET Emergency
NORWALK, CT 06855
Fatty alcohol phosphate, unneutralized
Synonym
Phosphoric acid, C8-C16 alkyl esters
Chemical Name
Not available.
Chemical Family
Not applicable.
Chemical Formula
Material Uses Industrial applications: Release agent.
Section II. Composition and Information on Ingredients
Name CAS # % by
Weight
Proprietary fatty alcohol phosphate (NJTSR No. 850201001-5376P) 95-100
1-octanol 111-87-5 0-2
1-decanol 112-30-1 0-2
Section III. Hazards Identification
Straw colored liquid. Corrosive liquid. Causes burns to eyes and skin. Avoid inhalation or ingestion of this
Emergency Overview
material.
Section IV. First Aid Measures
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
Eye Contact
keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as
Skin Contact
possible, protecting your own hands and body. Place the victim under a deluge shower. If the chemical got
on the victim's exposed skin, such as the hands : Gently and thoroughly wash the contaminated skin with
running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. If
irritation persists, seek medical attention. Wash contaminated clothing before reusing.
Allow the victim to rest in a well ventilated area. Seek immediate medical attention
Inhalation
Do not induce vomiting. Immediately give two glasses of water, a little at a time. Never give anything by
Ingestion
mouth to an unconscious person. Call a physician. If vomiting occurs spontaneously, lower head below waist
to prevent fluid from entering the lungs
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Section V. Fire and Explosion Data
Not available.
Flammability of the Product
The lowest known value is 288癈 (550.4癋) (1-decanol).
Auto-Ignition Temperature
CLOSED CUP: 99癈 (210.2癋). (Pensky-Martens.)
Flash Points
Not available.
Flammable Limits
These products are carbon oxides (CO, CO2).
Products of Combustion
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Not available.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section VI. Accidental Release Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal
Small Spill
Corrosive liquid.
Large Spill
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water
inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry
into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance
on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the
MSDS and with local authorities.
Section VII. Handling and Storage
Keep container dry. Keep in a cool place. Ground all equipment containing material. Corrosive materials
Storage
should be stored in a separate safety storage cabinet or room.
Avoid breathing vapor or mist. Do not get on skin or clothing. Do not get in eyes. Keep container closed.
Handling Procedures and
Use only with adequate ventilation. Wash thoroughly after handling.
Equipment
Section VIII. Exposure Controls/Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below
Engineering Controls
their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Protection
Gloves. Boots.
1-octanol
TLV/PEL
TWA: 50 (mg/m?
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Section IX. Physical and Chemical Properties
Straw color. Liquid.
Appearance
Not applicable.
Molecular Weight
2 [Acidic.]
pH (1% soln/water)
>100癈
Boiling/Condensation Point
Not available.
Melting/Sublimation Point
0.98 (Water = 1)
Specific Gravity
0.98 g/ml at 25癈 (77癋)
Density
Not available.
Vapor Pressure
The highest known value is 5.46 (Air = 1) (1-decanol). Weighted average: 4.98 (Air = 1)
Vapor Density
Volatility Not available.
Odor / Odor Threshold Fatty - alcohol like.
Evaporation rate Not available.
Not available.
Viscosity
Not available.
Water/Oil Dist. Coeff.
Solubility Very slightly soluble in cold water.
Section X. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Reactive with metals and bases.
Incompatibility with
Various Substances
Not available.
Corrosivity
Special Remarks on Reactivity Not available.
Section XI. Toxicological Information
Eye contact. Inhalation. Ingestion.
Routes of Entry
Acute oral toxicity (LD50): 5500 mg/kg [Rat].
Toxicity to Animals
Acute dermal toxicity (LD50): 8000 mg/kg [Rabbit]
Toxic effects described in animals from repeated exposures by ingestion include body weight loss, gastritis
Special Remarks on
and deaths.
Toxicity to Animals
Acute Effects
Hazardous in case of eye contact (irritant, corrosive).
Eye contact
Hazardous in case of skin contact (corrosive, irritant).
Skin contact
This product was not a skin sensitizer in animal testing.
Sensitization
Although acute toxicity is low, corrosive properties of this material may cause burns to mouth, throat and
Ingestion
stomach.
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No data available for this product. Based on testing of similar materials, may be an inhalation hazard causing
Inhalation
irritation and discomfort.
Not available.
Remark
CARCINOGENIC EFFECTS Not available.
:
Chronic Effects on
MUTAGENIC EFFECTS Not available.
:
Humans
DEVELOPMENTAL TOXICITY Not available.
:
REPRODUCTIVE TOXICITY Not available.
:
Not available.
Remarks
Section XII. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
Not available.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Section XIII. Disposal Considerations
Determine the pH of the actual waste. If pH is less than 2, dispose according to RCRA 40 CFR 261.22.
Waste information
Not available.
Waste stream
Section XIV. Transport Information
Class 8: Corrosive material
TDG Road/Rail
8
Shipping name: Corrosive liquid, Acidic, Organic, n.o.s. (mixed alkyl acid orthophosphate), 8, UN: 3265, PG:
III
Not available.
Remarks
Not available.
Maritime
Transportation
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VANFRE?UN Page Number: 5
Section XV. Other Regulatory Information and Pictograms
Federal & Provincial
CEPA DSL: VANFRE?UN
Regulations.
Class D-2B: Material causing other toxic effects (TOXIC).
WHMIS (Canada)
Class E: Corrosive liquid.
Remark Not available.
Other regulatory lists TSCA 8(b) inventory: VANFRE?UN
EINECS: This product is on the European Inventory of Existing Commercial Chemical
Substances.
National Fire
3
Hazardous Material Health Hazard Flammability
1
Protection Association
Information System 1
Fire Hazard
3 0
(U.S.A.)
(U.S.A.) Reactivity
Health
0
Reactivity COR
Personal Protection Specific hazard
WHMIS (Canada)
(Pictograms)
Protective Clothing
(Pictograms)
Section XVI. Other Information
Not available.
References
Not available.
Other Special
Considerations
Validated by Erin A. Bendig on 1/10/2003. Verified by Erin A. Bendig.
Printed 1/10/2003.
Information Contact David Bower, Ph.D. (203) 853-1400 ext. 233
Corporate Risk Management
Notice to Reader
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our
knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in
violation of any patent or in violation of any law or regulation. It is the user's responsibility to determine for himself the suitability of any
material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained
in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of
any material supplied by us.
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