MSDS No: UW200E8
Issue Date: 16 Dec 2008
Page: 1 of 5
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: UNI-WELD CPVC MEDIUM ORANGE CEMENT
Product No.: 3266S, 3256S, 3246S, 3236S
Product Use: Cement for CPVC Plastic Pipe
Formula: CPVC Resin in Solvent Solution
Synonyms: CPVC Plastic Pipe Cement
Firm Name & UNITED ELCHEM IND. c/o OATEY CO. 4700 West 160th Street
Mailing Address: P.O. Box 35906 Cleveland, Ohio 44135, U.S.A.
http://www.elchem.com, http://www.oatey.comOatey Phone Number:
(216) 267-7100 or (800) 321-9532
Emergency Phone For Emergency First Aid call 1-877-740-5015. For
Numbers: chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the U.S. 1-703-527-3887.
Prepared By: Technical Department
Preparation Date: December 16, 2008
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER:
Methyl Ethyl Ketone 30 - 45% 78-93-3 200 ppm 200 ppm None
300 ppm STEL
Tetrahydrofuran 30 - 40% 109-99-9 50 ppm(skin) 200 ppm 25 ppm (Mfg)
100 ppm STEL
CPVC Resin 10 - 20% 68648-82-8 10 mg/m3 None None
(Non-hazardous) Established
Cyclohexanone 5 - 10% 108-94-1 20 ppm(skin) 50 ppm None
50 ppm STEL
Amorphous Fumed Silica 1 - 5% 112945-52-5 10 mg/m3 None None
(Non-hazardous) Established
OSHA Hazard Classification: Flammable, irritant, organ effects
SECTION 3 HAZARDS IDENTIFICATION
Emergency Overview:
Orange liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors
may cause flash fire. May cause eye and skin irritation. Inhalation of vapors or
mist may cause respiratory irritation and central nervous system effects. Swallowing
may cause irritation, nausea, vomiting, diarrhea and kidney or liver disorders.
Aspiration hazard. May be fatal if swallowed. Symptoms may be delayed.
SECTION 4 FIRST AID MEASURERS
CALL 1-877-740-5015 or 1-303-623-5716 COLLECT
Skin: Remove contaminated clothing immediately. Wash all exposed areas with
soap and water. Get medical attention if irritation develops. Remove
dried cement with Oatey Plumber's Hand Cleaner or baby oil.
Eyes: If material gets into eyes or if fumes cause irritation, immediately
flush eyes with plenty of water until chemical is removed. If
irritation persists, get medical attention immediately.
Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing
becomes difficult, administer oxygen. Administer artificial
respiration if breathing has stopped. Seek immediate medical
attention.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything
by mouth to a person who is unconscious or drowsy. Get immediate
medical attention by calling a Poison Control Center, or hospital
emergency room. If medical advice cannot be obtained, then take the
person and product to the nearest medical emergency treatment center
or hospital.
MSDS No: UW200E8
Issue Date: 16 Dec 2008
Page: 2 of 5
SECTION 5 FIRE FIGHTING MEASURES
Flashpoint / Method: 14 - 23 Degrees F. (-10 to -5 Degrees C) / CCCFP
Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume
Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media: exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire Firefighters should wear positive pressure self-contained
Fighting breathing apparatus and full protective clothing for fires in
Procedure: areas where chemicals are used or stored
Unusual Fire and Extremely flammable liquid. Keep away from heat and all
Explosion sources of ignition including sparks, flames, lighted
Hazards: cigarettes and pilot lights. Containers may rupture or
explode in the heat of a fire. Vapors are heavier than air
and may travel to a remote ignition source and flash back.
This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.
Hazardous Combustion will produce toxic and irritating vapors including
Decomposition carbon monoxide, carbon dioxide and hydrogen chloride.
Products:
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Remove all sources of ignition and ventilate area. Stop leak if it
Leak can be done without risk. Personnel cleaning up the spill should
Procedures: wear appropriate personal protective equipment, including respirators
if vapor concentrations are high. Soak up spill with an inert
absorbent such as sand, earth or other non-combusting material. Put
absorbent material in covered, labeled metal containers. Prevent
liquid from entering watercourses, sewers and natural waterways.
Report releases to authorities as required. See Section 13 for
disposal information.
SECTION 7 HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors
or mists. Use with adequate ventilation (equivalent to outdoors).
Wash thoroughly after handling. Do not eat, drink or smoke in the
work area. Keep product away from heat, sparks, flames and all other
sources of ignition. No smoking in storage or use areas. Keep
containers closed when not in use.
Storage: Store in a cool, dry, well-ventilated area away from incompatible
materials. Keep containers closed when not in use.
Other: "Empty" containers retain product residue and can be hazardous.
Follow all MSDS precautions in handling empty containers. Do not cut
or weld on or near empty or full containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Open doors & windows. Provide ventilation capable of maintaining
emissions at the point of use below recommended exposure limits. If
used in enclosed area, use exhaust fans. Exhaust fans should be
explosion-proof or set up in a way that flammable concentrations of
solvent vapors are not exposed to electrical fixtures or hot
surfaces.
Respiratory For operations where the exposure limit may be exceeded, a NIOSH
Protection: approved organic vapor respirator or supplied air respirator is
recommended. Equipment selection depends on contaminant type and
concentration, select in accordance with 29 CFR 1910.134 and good
industrial hygiene practice. For firefighting, use self-contained
breathing apparatus.
Skin Rubber gloves are suitable for normal use of the product. For long
Protection: exposures chemical resistant gloves may be required such as
MSDS No: UW200E8
Issue Date: 16 Dec 2008
Page: 3 of 5
4H(tm) or Silver Shield(tm) to avoid prolonged skin contact.
Eye Safety glasses with side shields or safety goggles.
Protection:
Other: Eye wash and safety shower should be available.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 151 Degrees F / 66 Degrees C
Melting Point: Not applicable
Vapor Pressure: 145 mmHg @ 20 Degrees C
Vapor Density: (Air = 1) 2.5
Volatile Components: 78-82%
Solubility In Water: Negligible
pH: Not applicable
Specific Gravity: 0.95 +/- 0.02 @ 20 Degrees C
Evaporation Rate: (BUAC = 1) = 5.5 - 8.0
Appearance: Orange Liquid
Odor: Ether-Like
Will Dissolve In: Tetrahydrofuran
Material Is: Liquid
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition.
Hazardous Combustion will produce toxic and irritating vapors
Decomposition including carbon monoxide, carbon dioxide and hydrogen
Products: chloride.
Incompatibility/ Oxidizing agents, alkalis, amines, ammonia, acids, chlorine
Materials To Avoid: compounds, chlorinated inorganics (potassium, calcium and
sodium hypochlorite) and hydrogen peroxides. May attack
plastic, resins and rubber.
Hazardous Will not occur.
Polymerization:
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Vapors or mists may cause mucous membrane and respiratory
irritation, coughing, headache, dizziness, dullness, nausea,
shortness of breath and vomiting. High concentrations may cause
central nervous system depression, narcosis and unconsciousness.
May cause kidney, liver and lung damage.
Skin: May cause irritation with redness, itching and pain. Methyl
ethyl ketone and cyclohexanone may be absorbed through the skin
causing effects similar to those listed under inhalation.
Eye: Vapors may cause irritation. Direct contact may cause irritation
with redness, stinging and tearing of the eyes. May cause eye
damage.
Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and
diarrhea. Aspiration during swallowing or vomiting can cause
chemical pneumonia and lung damage. May cause kidney and liver
damage.
Chronic Prolonged or repeated overexposure cause dermatitis and damage
Toxicity: to the kidney, liver, lungs and central nervous system.
Toxicity Data: Cyclohexanone: Oral rat LD50: 1,620 mg/kg
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit LD50: 1 mL/kg
Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg
Inhalation rat LC50: 21,000 ppm/3 hours
Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit LD50: 6,480 mg/kg
Sensitization: None of the components are known to cause sensitization.
MSDS No: UW200E8
Issue Date: 16 Dec 2008
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Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA. The National Toxicology Program
has reported that exposure of mice and rats to Tetrahydrofuran
(THF) vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their
lifetime caused an increased incidence of kidney tumors in male
rats and liver tumors in female mice. The significance of these
findings for human health is unclear at this time, and may be
related to "species specific" effects. Elevated incidences of
tumors in humans have not been reported for THF. ACGIH has
classified cyclohexanone (CYH) and tetrahydrofuran as "A3,"
confirmed Animal Carcinogens with Unknown Relevance to Humans.
Mutagenicity: Cyclohexanone has been positive in bacterial and mammalian
assays. Methyl ethyl ketone and tetrahydrofuran are
generally thought not to be mutagenic.
Reproductive Methyl ethyl ketone and cyclohexanone have been shown to cause
Toxicity: embryofetal toxicity and birth defects in laboratory animals.
Tetrahydrofuran has been found to cause adverse
developmental effects only when exposure levels cause other
toxic effects to the mother.
Medical Persons with pre-existing skin, lung, kidney or liver disorders
Conditions may be at increased risk from exposure to this product.
Aggravated By
Exposure:
SECTION 12 ECOLOGICAL INFORMATION
This product is not expected to be toxic to aquatic organisms.
Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.
Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L.
Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.
VOC This product emits VOC's (volatile organic compounds) in its use.
Information: Make sure that use of this product complies with local VOC emission
regulations, where they exist.
VOC Level: Maximum 490 g/L per SCAQMD Test Method 316A.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number: U057, U159, U213
EPA Hazardous Waste ID Number: D001, D035, F003, F005
EPA Hazard Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
SECTION 14 TRANSPORT INFORMATION
DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
UN/NA Number: None UN1133
Proper Shipping Name: Consumer Commodity Adhesives
Hazard Class: ORM-D 3
Packing Group: None PGII
Hazard Labels: None Flammable Liquid
IMDG
UN Number: UN1133 UN1133
Proper Shipping Name: Adhesives Adhesives
Hazard Class: 3 3
Packing Group: II II
Label: None (Limited Quantities Class 3 (Flammable
are excepted Liquid)
from labeling)
Flashpoint (deg C) -10 to -5 Degrees C -10 to -5 Degrees C
2008 North American Emergency Response Guidebook Number: 127
MSDS No: UW200E8
Issue Date: 16 Dec 2008
Page: 5 of 5
SECTION 15 REGULATORY INFORMATION
Hazard Category for Section Acute Health, Chronic Health, Flammable
311/312:
Section 302 Extremely This product does not contain chemicals regulated
Hazardous Substances (TPQ): under SARA Section 302.
Section 313 Toxic Chemicals: This product does not contain chemicals subject to
SARA Title III Section 313 Reporting requirements.
CERCLA 103 Reportable Spills of this product over the RQ (reportable
Quantity: quantity) must be reported to the National Response
Center. The RQ for the product, based on the RQ for
Tetrahydrofuran (40% maximum) of 1,000 lbs, is 2,500
lbs. Many states have more stringent release
reporting requirements. Report spills required under
federal, state and local regulations.
California Proposition 65: This product contains trace amounts of chemicals
known to the State of California to cause cancer.
Under normal use conditions, exposure to these
chemicals at levels above the State of California "No
Significant Risk Level" (NSRL) are unlikely. Oatey
Strongly encourages the use of proper personal
protective equipment (PPE) and ventilation guidelines
noted in Section 8 to minimize exposure to these
chemicals.
TSCA Inventory: All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification: Class B, Division 2; Class D, Division 2,
Subdivision B; Class D, Division 2, Subdivision A.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16 OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None
HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G
Disclaimer:
The information herein has been compiled from sources believed to be reliable, up-
to-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
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