MATERIAL SAFETY DATA SHEET
MSDS Number: 3402E
Section 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: PURPLE or CLEAR PRIMER
Product Nos.: purple - 018255, 018256, 018267, 019002, 018003, 019038, 019041, 019044,
019045, 019046, 019048, 019049, 019050, 019051, 019052, 019053, 019054,
019055, 019056, 019057, 019060, 019062, 019063, 019064, 019065, 019066,
019067, 019068, 019069, 019070, 019071, 019072, 019073, 019074, 019075,
019076, 019077, 019078, 019079, 019080, 019081, 019082, 019083, 019084,
019085, 019086, 019087, 019089, 019090, 019091, 019092, 019093, 019094,
019095, 019097, 019098, 019099, 019157, 019171, 019172, 019173, 019190,
019200, 019201, 019202, 019205, 019205, 019505, 019511, 019716, 019717,
405163, 458457, 458465, B15944, B15944A, B15944D, B15944F, MVP9912,
MVP9913, MVP9914, PV019038, PV019041, PV019205 clear - 019000, 019001,
019010, 019012, 019017, 019018, 019019, 019020, 019021, 019022, 019023,
019024, 019025, 019029, 019030, 019031, 019032, 019034, 019035, 019039,
019040, 019047, 019139, 019170, 019207
Product Use: Primer for PVC and CPVC Plastic Pipe
Formula: See section 2
Synonyms: Plastic Pipe Primer
Firm Name & William H. Harvey Company 4334 South 67th Street, Omaha, NE 68117
Address: www.wmharvey.com
Firm Phone No: (402) 331-1175
Emergency Phone For Emergency First Aid call 1-877-740-5015. For chemical transportation
Nos.: emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the U.S. 1-
703-527-3887.
Prepared by: Technical Department
Preparation Date: 11/01/2009
Section 2 HAZARDS IDENTIFICATION
Emergency Overview:
Purple or Clear
liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors may cause flash
fire. May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory
irritation and central nervous system effects. Swallowing may cause irritation, nausea,
vomiting, diarrhea and kidney or liver disorders. Aspiration hazard. May be fatal if
swallowed. Symptoms may be delayed.
Section 3 COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS: %wt/wt : CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA OTHER:
Tetrahydrofuran 15 ?30% 109-99-9 50 ppm(skin) 200 ppm 25 ppm (Mfg)
100 ppm STEL
Methyl Ethyl Ketone 25 ?40% 78-93-3 200 ppm 200 ppm None
300 ppm
Acetone 25 ?40% 67-64-1 500 ppm 1000 ppm None
750 ppm STEL
Cyclohexanone 15 ?30% 108-94-1 20 ppm(skin) 50 ppm None
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50 ppm STEL
OSHA Hazard Classification: Flammable, irritant, organ effects
Section 4 FIRST AID MEASURES
Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and
water. Get medical attention if irritation develops. Remove dried cement with
hand cleaner or baby oil.
Eyes: If material gets into eyes or if fumes cause irritation, immediately flush eyes
with plenty of water until chemical is removed. If irritation persists, get
medical attention immediately.
Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes
difficult, administer oxygen. Administer artificial respiration if breathing
has stopped. Seek immediate medical attention.
DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to
Ingestion:
a person who is unconscious or drowsy. Get immediate medical attention by
calling a Poison Control Center, or hospital emergency room. If medical advice
cannot be obtained, then take the person and product to the nearest medical
emergency treatment center or hospital.
Section 5 FIRE FIGHTING MEASURES
Flashpoint / 14 - 23 Degrees F. (-10 to -5 Degrees C) / CCCFP
Method:
Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume
Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container
Media: with water. Water may be ineffective as an extinguishing agent.
Special Fire Firefighters should wear positive pressure self-contained breathing apparatus
Fighting and full protective clothing for fires in areas where chemicals are used or
Procedure: stored
Unusual Fire Extremely flammable liquid. Keep away from heat and all sources of ignition
And Explosion including sparks, flames, lighted cigarettes and pilot lights. Containers may
Hazards: rupture or explode in the heat of a fire. Vapors are heavier than air and may
travel to a remote ignition source and flash back. This product contains
tetrahydrofuran that may form explosive organic peroxide when exposed to air or
light or with age.
Hazardous Combustion will produce toxic and irritating vapors including carbon monoxide,
Decomposition carbon dioxide and hydrogen chloride.
Products:
Section 6 ACCIDENTAL RELEASE MEASURES
Spill or Leak Remove all sources of ignition and ventilate area. Stop leak if it can be done
Procedures: without risk. Personnel cleaning up the spill should wear appropriate personal
protective equipment, including respirators if vapor concentrations are high.
Soak up spill with an inert absorbent such as sand, earth or other non-
combusting material. Put absorbent material in covered, labeled metal
containers. Prevent liquid from entering watercourses, sewers and natural
waterways. Report releases to authorities as required. See Section 13 for
disposal information.
Section 7 HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists.
Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after
handling. Do not eat, drink or smoke in the work area. Keep product away from
heat, sparks, flames and all other sources of ignition. No smoking in storage
or use areas. Keep containers closed when not in use.
Storage: Store in a cool, dry, well-ventilated area away from incompatible materials.
Keep containers closed when not in use.
Other: "Empty" containers retain product residue and can be hazardous. Follow all MSDS
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precautions in handling empty containers. Do not cut or weld on or near empty
or full containers.
Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at
the point of use below recommended exposure limits. If used in enclosed area,
use exhaust fans. Exhaust fans should be explosion-proof or set up in a way
that flammable concentrations of solvent vapors are not exposed to electrical
fixtures or hot surfaces.
Respiratory For operations where the exposure limit may be exceeded, a NIOSH approved
Protection: organic vapor respirator or supplied air respirator is recommended. Equipment
selection depends on contaminant type and concentration, select in accordance
with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting,
use self-contained breathing apparatus.
Skin Rubber gloves are suitable for normal use of the product. For long exposures
Protection: chemical resistant gloves may be required such as 4H(tm) or Silver Shield(tm)
to avoid prolonged skin contact.
Eye Safety glasses with side shields or safety goggles.
Protection:
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 151 Degrees F / 66 Degrees C
Melting Point: Not applicable
Vapor Pressure: 145 mmHg @ 20 Degrees C
Vapor Density: (Air = 1) 2.5
Volatile Components: 99.96%
Solubility In Water: Negligible
pH: Not applicable
Specific Gravity: 0.84 +/- 0.02 @ 20 Degrees C
Evaporation Rate: (BUAC = 1) = 5.5 - 8.0
Appearance: Purple or Clear Liquid
Odor: Ether-Like
Will Dissolve In: Tetrahydrofuran
Material Is: Liquid
Section 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid heat, sparks, flames and other sources of ignition.
Avoid:
Hazardous Combustion will produce toxic and irritating vapors including carbon
Decomposition monoxide, carbon dioxide and hydrogen chloride.
Products:
Incompatibility/ Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds,
Materials To chlorinated inorganics (potassium, calcium and sodium hypochlorite) and
Avoid: hydrogen peroxides. May attack plastic, resins and rubber.
Hazardous Will not occur.
Polymerization:
Section 11 TOXICOLOGICAL INFORMATION
Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation,
coughing, headache, dizziness, dullness, nausea, shortness of breath and
vomiting. High concentrations may cause central nervous system depression,
narcosis and unconsciousness. May cause kidney, liver and lung damage.
Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone and
cyclohexanone may be absorbed through the skin causing effects similar to
those listed under inhalation.
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Eye: Vapors may cause irritation. Direct contact may cause irritation with
redness, stinging and tearing of the eyes. May cause eye damage.
Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea.
Aspiration during swallowing or vomiting can cause chemical pneumonia and
lung damage. May cause kidney and liver damage.
Chronic Prolonged or repeated overexposure cause dermatitis and damage to the
Toxicity: kidney, liver, lungs and central nervous system.
Toxicity Data: Acetone: Oral rat LD50: 5,800 mg/kg
Inhalation rat LC50: 50,100 mg/m3/8 hours
Cyclohexanone: Oral rat LD50: 1,620 mg/kg
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit LD50: 1 mL/kg
Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg
Inhalation rat LC50: 21,000 ppm/3 hours
Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit LD50: 6,480 mg/kg
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by
NTP, IARC or OSHA. The National Toxicology Program has reported that
exposure of mice and rats to tetrahydrofuran (THF) vapor levels up to 1800
ppm 6 hr/day, 5 days/week for their lifetime caused an increased incidence
of kidney tumors in male rats and liver tumors in female mice. The
significance of these findings for human health is unclear at this time, and
may be related to "species specific" effects. Elevated incidences of tumors
in humans have not been reported for THF. ACGIH has classified
cyclohexanone (CYH) and tetrahydrofuran as "A3," Confirmed Animal
Carcinogens with Unknown Relevance to Humans.
Mutagenicity: Cyclohexanone has been positive in bacterial and mammalian assays. Acetone,
methyl ethyl ketone and tetrahydrofuran are generally thought not to be
mutagenic.
Reproductive Methyl ethyl ketone and cyclohexanone have been shown to cause embryofetal
Toxicity: toxicity and birth defects in laboratory animals. Acetone and
tetrahydrofuran has been found to cause adverse developmental effects only
when exposure levels cause other toxic effects to the mother.
Medical Persons with pre-existing skin, lung, kidney or liver disorders may be at
Conditions increased risk from exposure to this product.
Aggravated By
Exposure:
Section 12 ECOLOGICAL INFORMATION
This product is not expected to be toxic to aquatic organisms.
Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.
Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L.
Acetone: 96 hour LC50 for fish is greater than 100 mg/L.
Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.
VOC This product emits VOC's (volatile organic compounds) in its use. Make sure
Information: that use of this product complies with local VOC emission regulations, where
they exist.
VOC Level: Maximum 550 g/L per SCAQMD Test Method 316A.
Section 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste U002, U057, U159, U213
Number:
EPA Hazardous Waste D001, D035, F003, F0005
ID Number:
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EPA Hazard Waste Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
Number:
Section 14 TRANSPORT INFORMATION
DOT Less than 1 Liter (0.3 Greater than 1 Liter (0.3
gal) gal)
UN/NA Number: None UN1993
Proper Shipping Name: Consumer Commodity Flammable Liquid, NOS
(Methyl Ethyl Ketone,
Acetone)
Hazard Class: ORM-D 3
Packing Group: None PGII
Hazard Labels: None Flammable Liquid
IMDG
UN Number: UN1993 UN1993
Proper Shipping Name: Flammable Liquid, NOS Flammable Liquid, NOS
(Limited Quantity) (Methyl Ethyl Ketone,
Acetone)
Hazard Class: 3 3
Packing Group: II II
Label: None (Limited Quantities Class 3 (Flammable Liquid)
are expected from
labeling)
Flashpoint (deg C) -10 to -5 Degrees C -10 to -5 Degrees C
2008 North American Emercency Response Guidebook Number: 127
Section 15 REGULATORY INFORMATION
Hazard Category for Acute Health, Chronic Health, Flammable
Section 311/312:
Section 302 This product does not contain chemicals regulated under SARA Section 302.
Extremely Hazardous
Substances (TPQ):
Section 313 Toxic This product does not contain chemicals subject to SARA Title III Section
Chemicals: 313 Reporting requirements.
CERCLA 103 Spills of this product over the RQ (reportable quantity) must be reported
Reportable to the National Response Center. The RQ for the product, based on the RQ
Quantity: for Tetrahydrofuran (30% maximum) of 1,000 lbs, is 3,333 lbs.
Many states have more stringent release reporting requirements. Report
spills required under federal, state and local regulations.
California This product does not contain any chemicals subject to California
Proposition 65: Proposition 65 regulations.
TSCA Inventory All of the components of this product are listed on the TSCA inventory.
Canadian WHIMS Class B, Division 2; Class D, Division 2, Subdivision B; Class D,
Classification: Division 2, Subdivision A. This product has been classified in accordance
with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
Section 16 OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None
HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G
Disclaimer:
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The information herein has been compiled from sources believed to be reliable, up-to-date, and
is accurate to the best of our knowledge. However, we cannot give any guarantees regarding
information from other sources, and expressly do not make warranties, nor assume any liability
for its use.
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