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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 07/30/2008
1 Identification of substance
?Product details
?Trade name: TM/B
?Article number: TM/B
?Application of the substance / the preparation Printing inks
?Manufacturer/Supplier:
TAMPOMARK INC.
W 227 N937 Westmound Drive 1A
Waukesha, WI 53186
Phone (262) 544-4860
Fax (262) 544-4865
Email info@tampomark.us
www.tampomark.us
?Information department:
Mr. Michael Simon
simon@grulms.de
?Emergency information:
Phone Calls Domestic North America: 1-800-424-9300 (toll free - Chemtrec)
International calls: +1 703 527 3887
2 Composition/Data on components
?Chemical characterization
?Description: Mixture of the substances listed below with nonhazardous additions.
?Dangerous components:
108-94-1 cyclohexanone 10-25%
112-07-2 2-butoxyethyl acetate 10-25%
64742-95-6 Solvent naphtha (petroleum), light arom. 2.5-10%
108-65-6 2-methoxy-1-methylethyl acetate 2.5-10%
3 Hazards identification
?Hazard description:
Harmful
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation and in contact with skin.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Repeated exposure may cause skin dryness or cracking.
?Classification system:
The classification was made according to the latest editions of international substances lists, and
expanded upon from company and literature data.
?NFPA ratings (scale 0 - 4)
Health = 2
2 Fire = 2
2 0 Reactivity = 0
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 07/30/2008
Trade name: TM/B
(Contd. of page 1)
?HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 2
FIRE 2
Reactivity = 0
REACTIVITY 0
4 First aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire fighting measures
?Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Not required.
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires: No special measures required.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
108-94-1 cyclohexanone (10-25%)
PEL 200 mg/m? 50 ppm
REL 100 mg/m? 25 ppm
Skin
TLV 50 mg/m? 20 ppm
Skin
(Contd. on page 3)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 07/30/2008
Trade name: TM/B
(Contd. of page 2)
112-07-2 2-butoxyethyl acetate (10-25%)
REL 33 mg/m? 5 ppm
Skin
TLV 130 mg/m? 20 ppm
108-65-6 2-methoxy-1-methylethyl acetate (2.5-10%)
WEEL 50 ppm
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use respiratory protective device that is independent of circulating air.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to
be observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Pasty
Form:
According to product specification
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: > 150癈 (> 302癋)
?Flash point: > 55癈 (> 131癋) (Abel Pensky)
?Ignition temperature: 410癈 (770癋)
(Contd. on page 4)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 07/30/2008
Trade name: TM/B
(Contd. of page 3)
?Auto igniting: Product is not selfigniting.
?Danger of explosion: Product does not present an explosion hazard.
?Explosion limits:
0.8 Vol %
Lower:
12.7 Vol %
Upper:
?Vapor pressure at 20癈 (68癋): 3 hPa (2 mm Hg)
?Density at 20癈 (68癋): 1.3 g/cm?br>
?Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
?Viscosity:
9000 mPas
Dynamic at 20癈 (68癋):
5.0 %
VOC content:
520.0 g/l / 4.34 lb/gl
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
108-94-1 cyclohexanone
Oral LD50 1535 mg/kg (rat)
Dermal LD50 948 mg/kg (rabbit)
Inhalative LC50/4 h 8000 mg/l (rat)
112-07-2 2-butoxyethyl acetate
Oral LD50 2400 mg/kg (rat)
Dermal LD50 1580 mg/kg (rabbit)
64742-95-6 Solvent naphtha (petroleum), light arom.
Oral LD50 >6800 mg/kg (rat)
Dermal LD50 >3400 mg/kg (rab)
Inhalative LC50/4 h >10.2 mg/l (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Irritant
12 Ecological information
?Ecotoxical effects:
?Remark: Harmful to fish
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 07/30/2008
Trade name: TM/B
(Contd. of page 4)
?General notes:
Harmful to aquatic organisms
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?DOT regulations:
?Hazard class: -
?Land transport ADR/RID (cross-border):
?ADR/RID class: -
?Maritime transport IMDG:
?IMDG Class: -
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: -
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
?TSCA (Toxic Substances Control Act):
All ingredients are listed.
?Proposition 65
?Chemicals known to cause cancer:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
?Cancerogenity categories
?EPA (Environmental Protection Agency)
None of the ingredients is listed.
(Contd. on page 6)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 07/30/2008
Trade name: TM/B
(Contd. of page 5)
?IARC (International Agency for Research on Cancer)
108-94-1 cyclohexanone 3
?NTP (National Toxicology Program)
None of the ingredients is listed.
?TLV (Threshold Limit Value established by ACGIH)
108-94-1 cyclohexanone A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Harmful
?Risk phrases:
Harmful by inhalation and in contact with skin.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Repeated exposure may cause skin dryness or cracking.
?Safety phrases:
Keep container in a well-ventilated place.
Do not breathe fumes/aerosol.
Avoid contact with eyes.
Wear suitable protective clothing.
This material and its container must be disposed of as hazardous waste.
Avoid release to the environment. Refer to special instructions/safety data sheets.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
?Contact:
Mr. Michael Simon
simon@grulms.de
USA