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MATERIAL SAFETY DATA SHEET
FOR INDUSTRIAL USE ONLY
DESCRIPTION: Cascophen RS-240MDA
1. Chemical Product and Company Identification
DESCRIPTION: Cascophen RS-240MDA
PRODUCT CODE: 304463
PRODUCT TYPE: Liquid PRF Resin
APPLICATION: General Purpose Wood Gluing
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CASCOPHEN is a trademark of Borden Chemical Investments, Inc., registered in the USA.
Manufacturer/Supplier Information
MSDS prepared by:
Hexion Specialty Chemicals, Inc. For Emergency Medical Assistance
155 West A Street, Bldg. A-1 Call Health & Safety Information Services
Springfield, OR 1-866-303-6949
97477
For additional health and safety or regulatory information, call (541)744-3256.
2. Composition, Information on Ingredients
The ingredients listed below have been associated with one or more immediate and/or
delayed(*) health hazards. Risk of damage and effects depends upon duration and level of
exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ
AND UNDERSTAND THE MSDS.
% by weight
64-17-5 *Ethanol 5.0 - 10.0
108-46-3 Resorcinol 1.0 - 5.0
108-95-2 *Phenol 5.0 - 10.0
Any applicable Canadian trade secret numbers will be listed in Section 15.2.
3. Hazards Identification
3.1 Emergency Overview
Appearance Reddish-brown liquid
Odor Slight alcoholic
WARNING!
COMBUSTIBLE
Will polymerize at high temperatures with some evolution of heat.
Hazardous polymerization may occur.
Overexposure may cause central nervous system depression. May cause irritation of nose,
throat and lungs if allowed to become airborne.
Causes chemical burns to eyes.
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NORTH AMERICAN EMERGENCY RESPONSE GUIDE, 2000, NO: 127
HMIS Rating
HEALTH = 3 (serious)
FLAMMABILITY = 2 (moderate)
REACTIVITY = 1 (slight)
CHRONIC = *
3.2 Potential Health Effects
Immediate Hazards
INGESTION: Not expected to be harmful under normal conditions of use.
INHALATION: Not expected to be harmful under normal conditions of use. However,
overexposure may cause central nervous system effects. Also, if
allowed to become airborne, may cause irritation of nose, throat and
lungs.
SKIN: May cause irritation on prolonged or repeated contact.
EYES: Causes chemical burns.
64-17-5 Ethanol
Can cause central nervous system depression. Signs and symptoms may include headache,
dizziness, nausea, vomiting and drowsiness.
108-46-3 Resorcinol
This chemical is slightly to moderately toxic by ingestion, inhalation and skin absorption. Signs
of acute poisoning in rats include central nervous system stimulation, tremors and convulsions
followed by depression and death, or complete recovery within 8-24 hours. Animal studies
have further indicated that high acute doses have caused reversible damage to the thyroid as
well as damage to the blood, spleen, liver, kidney and lungs. Since it is rapidly absorbed and
rapidly eliminated from the body, there are no identified chronic or cumulative adverse effects.
108-95-2 Phenol
Can cause central nervous system effects. Signs and symptoms may include headache,
dizziness, nausea, vomiting, motor difficulties and unconsciousness.
Delayed Hazards
64-17-5 Ethanol
Ingestion may cause liver damage.
-- See Footnote
108-95-2 Phenol
Can cause liver and kidney damage. Signs and symptoms of chronic poisoning may include
vomiting, difficulty in swallowing, diarrhea, lack of appetite, jaundice, fatigue, bleeding or easy
bruising and sometimes pain and swelling in the upper right abdomen, changes in urine output
or dark urine, pain upon urination or in the lower back, or general edema. Can also cause
cardiac damage evidenced by shortness of breath and in severe cases cardiac arrest.
Preexisting medical conditions of the heart, kidney, liver, lung, eyes and skin may be
aggravated by exposure.
-- See Footnote
Footnote: As of the date of issuance of this document, this material has not been listed by
NTP, classified by IARC nor regulated by OSHA as a carcinogen.
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4. First Aid Measures
If accidentally swallowed, dilute by drinking large quantities of water. If
INGESTION:
the individual is drowsy or unconscious, do not give anything by mouth.
Immediately contact poison control center or hospital emergency room
for advice on whether to induce vomiting or for any other additional
treatment directions.
Remove to fresh air.
INHALATION:
In case of irritation, flush with water.
SKIN:
Immediately flush eyes with plenty of water for at least 15 minutes.
EYES:
Eyelids should be held apart during irrigation to ensure water contact
with entire surface of eyes and lids. Call a physician.
5. Fire Fighting Measures
Flash point 52 癈 (126 癋) Pensky-Martens Closed Cup
ASTM D 93
Lower explosion limit Not available
Upper explosion limit Not available
Autoignition temperature Not available
COMBUSTIBLE. Keep away from heat and flame.
In case of fire, use water spray, dry chemical, "alcohol" foam or CO2. Use water to keep fire-
exposed containers cool.
6. Accidental Release Measures
Eliminate all ignition sources. Contain and/or absorb spill with inert material (e.g. sand,
vermiculite), then place in a suitable container. For large spills, use water spray to disperse
vapors and flush spill area. Prevent runoff from entering waterways or sewers. Use
appropriate Personal Protective Equipment (PPE).
7. Handling and Storage
7.1 Handling
Handle in accordance with good industrial hygiene and safety practices. These practices
include avoiding unnecessary exposure and removal of the material from eyes, skin and
clothing. Wash thoroughly after handling. Always use appropriate Personal Protective
Equipment (PPE).
Avoid prolonged or repeated breathing of vapor.
INHALATION:
Avoid prolonged or repeated contact with skin and clothing.
SKIN:
Do not get in eyes.
EYES:
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7.2 Storage
Keep container closed.
Store in a cool, dry place.
Not harmed by freezing. If frozen, resin should be thawed slowly at room temperature and
agitated thoroughly before use.
8. Exposure Controls/Personal Protection
8.1 Exposure Controls
ENGINEERING CONTROLS: The following exposure control techniques may be used to
effectively minimize employee exposure: local exhaust ventilation, enclosed system design,
process isolation and remote control in combination with appropriate use of personal
protective equipment and prudent work practices. These techniques may not necessarily
address all issues pertaining to your operations. We, therefore, recommend that you consult
with experts of your choice to determine whether or not your programs are adequate.
If airborne contaminants are generated when the material is heated or handled, sufficient
ventilation in volume and air flow patterns should be provided to keep air contaminant
concentration levels below acceptable criteria.
8.2 Personal Protection
Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84)
approved respiratory protection equipment. Respirators should be selected based on the form
and concentration of contaminants in air in accordance with OSHA laws and regulations or
other applicable standards or guidelines, including ANSI standards regarding respiratory
protection. Use goggles if contact is likely. Wear impervious gloves as required to prevent skin
contact.
8.3 Exposure Guidelines
64-17-5 Ethanol
ACGIH TLV 8-hr TWA 1,000 ppm 1,880
mg/m3
OSHA PEL 1,000 ppm 1,900
mg/m3
108-46-3 Resorcinol
ACGIH TLV 8-hr TWA 10 ppm 45 mg/m3
STEL (15 min) 20 ppm 90 mg/m3
OSHA PEL None
Established
Remanded TWA 10 ppm 45 mg/m3 1989 PEL remanded, but in
effect in some states
Remanded 20 ppm 90 mg/m3
STEL
108-95-2 Phenol
ACGIH TLV 8-hr TWA 5 ppm 19 mg/m3 Skin
OSHA PEL 8-hr TWA 5 ppm 19 mg/m3 Skin
9. Physical and Chemical Properties
Appearance Reddish-brown liquid
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Odor Slight alcoholic
Odor threshold Not available
Specific gravity 1.14 - 1.15
pH 7.5 - 7.9
Viscosity 150 - 250 cPs Brookfield
Freezing point Less than 0 癈 (32 癋)
Solubility in water Slightly
Octanol/water partition coefficient Not available
Vapor pressure Approx. 50 mm Hg @25 癈 (77 癋)
Vapor density Not available
Evaporation rate Approx. 0.6 (Butyl Acetate = 1)
Boiling point, 760 mm Hg Approx. 102 癈 (216 癋)
10. Stability and Reactivity
Normally stable, but will polymerize at high temperatures with some evolution of heat.
Incompatibilities:
Oxidizers, acids
Decomposition products may include:
CO, CO2, aldehydes (including formaldehyde), particulate matter and other organic
compounds.
Hazardous polymerization:
May occur.
11. Toxicological Information
A similar product was found to have an LD50 >0.5 g/kg when tested as
INGESTION:
described in 16 CFR Part 1500.3 (c)(1) and (2).
A similar product was found to be non-toxic by inhalation when tested
INHALATION:
as described in 16 CFR Part 1500.3 (c)(1) and (2).
A similar product was found to be non-toxic dermally when tested as
SKIN
described in 16 CFR Part 1500.3 (c)(1) and (2).
ABSORPTION:
A similar product was not a primary irritant (primary skin irritation index
SKIN:
less than 5.0/8.0) when tested as described in 16 CFR Part 1500.41.
A similar product was severely irritating when tested as described in 16
EYES:
CFR Part 1500.42.
64-17-5 Ethanol
LC50: rat=20,000 mg/l/10 h (Sax)
LD50: Oral-rat= 7,060 mg/kg (Sax)
108-46-3 Resorcinol
LC50: Not available
LD50: Oral-rat= 301 mg/kg (Sax); Skin-rabbit= 3,360 mg/kg (Sax)
108-95-2 Phenol
LC50: rat=0.316 mg/l (RTECS)
LD50: Oral-rat= 414 mg/kg (Sax); Skin-rabbit= 850 mg/kg (Sax)
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12. Ecological Information
No data for ecotoxicity has been found. Effects are expected to be minimal. Phenol-
formaldehyde polymers have a very low rate of biodegradation. Bioaccumulation is expected
to be minimal. Product is initially a mobile liquid which will solidify on aging. Unreacted
monomer may be leached into ground water even after normal curing has occurred.
13. Disposal Considerations
Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and
federal requirements. Empty container: May contain explosive vapors. DO NOT cut, puncture
or weld on or nearby.
14. Transport Information
14.1 U.S. Department of Transportation (DOT)
The data provided in this section is for information only and may not be specific to your
package size. You will need to apply the appropriate regulations to properly classify your
shipment for transportation.
RESIN SOLUTION, flammable
Proper shipping name
1866
UN/NA number
3
Class
III
Packing group
3
Label
Phenol
RQ Ingredients
14.2 Canadian Transportation of Dangerous Goods (TDG)
RESIN SOLUTION, flammable
Proper shipping name
1866
UN number:
Class 3
Class
III
Packing group
3
Label
15. Regulatory Information (Selected Regulations)
15.1 U.S. Federal Regulations
OSHA Hazards Communication Standard 29CFR1910.1200
This material is a "health hazard" and/or a "physical hazard" as determined when reviewed
according to the requirements of the Occupational Safety and Health Administration 29 CFR
Part 1910.1200 "Hazard Communication" Standard.
SARA Title III: Section 311/312
Reactivity hazard
Immediate health hazard
Delayed health hazard
Fire hazard
SARA Title III: Section 313 and 40 CFR Part 372
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This product contains the following toxic chemical(s) subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and
Subpart C-Supplier Notification Requirement of 40 CFR Part 372.
Phenol 108-95-2 5.49%
TSCA Section 8(b) Inventory
All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications
of compliance from our suppliers for chemical substances not manufactured by us.
15.2 Canadian Regulations
Workplace Hazardous Materials Information System (WHMIS)
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulation (CPR) and the MSDS contains all the information required by the CPR.
Class B3
Class D2B
Canadian Environmental Protection Act (CEPA)
All reportable chemical substances are listed on the Domestic Substances List (DSL) or
otherwise comply with CEPA new substance notification requirements.
National Pollutant Release Inventory (NPRI)
This product contains the following chemical(s) subject to the reporting requirements of the
Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release
Inventory.
Phenol (and its salts) 108-95-2 5.49%
16. Other Information
User's Responsibility
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Hazardous Materials Information System (WHMIS) require that the information contained on
these sheets be made available to your workers. Educate and train your workers regarding
OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult
with appropriate experts to guard against hazards associated with use of this product and its
ingredients.
Disclaimer
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT
OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that
the product shall conform to contracted specifications, and that the product does not infringe
any valid United States or Canadian patent. No claim of any kind shall be greater in amount
than the purchase price of the quantity of product in respect of which damages are claimed. In
no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim
is based on contract, breach of warranty, negligence or otherwise.
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