MATERIAL SAFETY DATA SHEET
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HE571 - HENRY BLUESKIN ADHESIVE
1. Product And Company Identification
Manufacturer Manufacturer Emergency Contacts & Phone Number
HENRY COMPANY CHEMTREC: (800) 424-9300
909 N. Sepulveda Blvd., Suite 650 CHEMTREC: (703) 527-3887
El Segundo, CA 90245-2724 CANUTEC: (613) 996-6666
Company Contact: Technical Services
Telephone Number: (800) 486-1278
Web Site: www.henry.com www.bakor.com
Issue Date: 08/24/2009
Supersedes MSDS Dated: 03/19/2008
Product Name: HE571 - HENRY BLUESKIN ADHESIVE
Product Code: HE571
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
1,2,4-trimethylbenzene 95-63-6 0.1 - 1
1,3,5-trimethylbenzene 108-67-8 0.1 - 1
3-methylpentane 96-14-0 5 - 20
acetone 67-64-1 25 - 50
bentonite 1302-78-9 1-5
hexane 110-54-3 10 - 35
hydrocarbon resins Mixture 15 - 30
isohexane 107-83-5 1-5
methylcyclopentane 96-37-7 1-5
mineral oil 64742-52-5 1-5
stoddard solvent 8052-41-3 5 - 10
xylene 1330-20-7 0.1 - 1
inert ingredients
EMERGENCY OVERVIEW
WARNING! Flammable liquid and vapor. Vapor may cause light-headedness, headache, nausea, loss of
coordination and respiratory tract irritation. Causes skin irritation.
Appearance/Odor: Blue liquid with mild gasoline-like odor.
3. Hazards Identification
Primary Routes(s) Of Entry
Inhalation
Eye Hazards
May cause eye irritation (burning, tearing, redness or swelling).
Skin Hazards
May cause skin irritation and contact dermatitis upon prolonged contact.
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3. Hazards Identification - Continued
Ingestion Hazards
Ingestion may cause central nervous system depression.
Inhalation Hazards
Exposure to vapors may cause respiratory tract irritation. Inhalation of vapors or mists may cause central nervous
system depression, light-headedness, headache, nausea and loss of coordination.
Chronic/Carcinogenicity Effects
None of the ingredients of this product comprising over 0.1% are classified as carcinogenic according to OSHA,
National Toxicology Program (NTP), International Agency for Research on Cancer (IARC) or the American Conference
of Governmental Industrial Hygienists (ACGIH).
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention immediately if irritation develops and persists.
Skin
Remove contaminated clothing and shoes. Wash affected areas with soap and water.
Ingestion
Get medical attention immediately. DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious
victim.
Inhalation
Remove the person from the contaminated area to fresh air. If breathing is difficult, give oxygen. Get medical attention
immediately.
5. Fire Fighting Measures
Flash Point: -18.4 癋 -28 癈
Flash Point Method: closed cup
Autoignition Point: 433 癋 223 癈
Lower Explosive Limit: 1.0
Upper Explosive Limit: 13.0
Fire And Explosion Hazards
Thermal decomposition (burning) may release irritating, corrosive and/or toxic gases, vapors and fumes.
Extinguishing Media
Chemical foam, carbon dioxide (CO2), or dry chemical.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
6. Accidental Release Measures
Restrict access to area until oxygen level in the air can be determined and is at least 19.5%. Ensure monitoring is
conducted by trained personnel only. Wear adequate respiratory protection equipment. Ventilate area. Avoid open
flames, sparks or other ignition sources. Contain any liquids and absorb spill with inert material (e.g. sand, vermiculite).
Collect and dispose in accordance with applicable regulations.
MATERIAL SAFETY DATA SHEET
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HE571 - HENRY BLUESKIN ADHESIVE
7. Handling And Storage
Handling And Storage Precautions
Store in a cool, dry, well-ventilated area. Keep away from ignition sources. Keep containers tightly closed.
8. Exposure Controls/Personal Protection
Engineering Controls
Use with adequate general and local exhaust ventilation. When used outdoors, stay well away from building air intakes
or close and seal the intakes to prevent product from entering building.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Use with chemical-protective gloves made of nitrile or neoprene, protective sleeves and solvent-resistant apron to
prevent skin contact.
Respiratory Protection
The level of respiratory protection needed should be based on the evaluation of chemical exposures by a health or
safety professional. If required, use a NIOSH-approved air purifying respirator with organic vapor cartridge and
particulate filter or supplied air respirator.
Occupational Exposure Limits for individual ingredients (if available) are listed below.
Ingredient(s) - Exposure Limits
1,2,4-trimethylbenzene
ACGIH TLV-TWA 25 ppm
1,3,5-trimethylbenzene
ACGIH TLV-TWA 25 ppm
acetone
ACGIH TLV-STEL 750 ppm
ACGIH TLV-TWA 500 ppm
OSHA PEL-TWA 1000 ppm
bentonite
ACGIH TLV-TWA 10 mg/m3 (total dust)
ACGIH TLV-TWA 3 mg/m3 (respirable dust)
OSHA PEL-TWA 15 mg/m3 (total dust)
OSHA PEL-TWA 5 mg/m3 (respirable dust)
hexane
ACGIH TLV-STEL 1000 ppm
ACGIH TLV-TWA 50 ppm (Skin)
ACGIH TLV-TWA 500 ppm
OSHA PEL-TWA 500 ppm
isohexane
ACGIH TLV-STEL 1000 ppm
ACGIH TLV-TWA 500 ppm
mineral oil
ACGIH (TLV-TWA): 5 mg/m3 (mist)
OSHA (PEL-TWA): 5 mg/m3 (mist)
stoddard solvent
ACGIH TLV-TWA 100 ppm
OSHA PEL-TWA 500 ppm
xylene
ACGIH TLV-STEL 150 ppm
MATERIAL SAFETY DATA SHEET
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8. Exposure Controls/Personal Protection - Continued
Ingredient(s) - Exposure Limits - Continued
ACGIH TLV-TWA 100 ppm
OSHA PEL-TWA 100 ppm
9. Physical And Chemical Properties
Appearance
Blue liquid
Odor
Mild gasoline-like odor
Chemical Type: Mixture
Physical State: Liquid
Boiling Point: 132.8 癋 56 癈
Specific Gravity: 0.80 for liquid portion
Percent Volatiles: 70-75 <500g/L
Vapor Pressure: 200-300 mm Hg at 30 篊
Vapor Density: 2.0-2.8 for liquid portion @77篎
pH Factor: not applicable
Solubility: slight
Evaporation Rate: 7-9 (butyl acetate = 1)
10. Stability And Reactivity
Stability: stable
Hazardous Polymerization: not expected to occur
Conditions To Avoid (Stability)
Avoid extreme temperatures. Keep away from ignition sources, heat and flames.
Incompatible Materials
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products
Toxic and irritating gases, vapors or fumes of carbon monoxide (CO), carbon dioxide (CO2).
11. Toxicological Information
Miscellaneous Toxicological Information
Toxicological testing has not been conducted for this product overall. Available toxicological data for individual
ingredients are summarized below.
Ingredient(s) - Toxicological Data
1,2,4-trimethylbenzene
LD50 (oral, rat): 5000 mg/kg
LC50 (rat): 18 g/m3 (4-hour exposure)
1,3,5-trimethylbenzene
Lethal dose (oral, rat): 23 g/kg lethal to 7 of 10 test animals
LC50 (rat): 24 g/m3 (4-hour exposure)
acetone
LD50 (oral, female rat): 5800 mg/kg
LD50 (dermal, rabbit): >16000 mg/kg
LC50 (male rat): 30000 ppm (4-hour exposure)
hexane
LD50 (oral, 14-day old rat): 15840 mg/kg
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11. Toxicological Information - Continued
Ingredient(s) - Toxicological Data - Continued
LC50 (male rat): 38500 ppm (4-hour exposure)
methylcyclopentane
LD50 (oral, rat): 5-15 g/kg
Lethal concentration (mouse): 95000-120000 mg/m3
mineral oil
LD50 (oral, rat): >5000 mg/kg
LD50 (dermal, rabbit): >5000 mg/kg
stoddard solvent
oral-rat LD50: >5000 mg/kg
dermal-rabbit LD50: >3000 mg/kg
inhal-rat LC50: >5500 mg/m3 (880 ppm)
inhal-rat LC50: >1300 ppm
xylene
LD50 (oral, rat): 5400 mg/kg
LD50 (dermal, rabbit): 12180 mg/kg
LC50 (rat): 6350 ppm (4-hour exposure)
12. Ecological Information
None identified.
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Ground UN1133, Adhesives, 3, II
IMDG UN1133, Adhesives, 3, II
IATA UN1133, Adhesives, 3, II
DOT (Pictograms)
15. Regulatory Information
SARA Hazard Classes
Acute Health Hazard
Fire Hazard
Ingredient(s) - U.S. Regulatory Information
1,2,4-trimethylbenzene
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
hexane
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
xylene
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
MATERIAL SAFETY DATA SHEET
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HE571 - HENRY BLUESKIN ADHESIVE
15. Regulatory Information - Continued
Ingredient(s) - State Regulations
1,2,4-trimethylbenzene
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
1,3,5-trimethylbenzene
New Jersey - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
3-methylpentane
New Jersey - Workplace Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
acetone
New Jersey - Workplace Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
hexane
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
isohexane
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
methylcyclopentane
New Jersey - Workplace Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
mineral oil
New Jersey - Workplace Hazard
stoddard solvent
New Jersey - Workplace Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
xylene
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
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15. Regulatory Information - Continued
Canadian Regulatory Information
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR. WHMIS Classification: Class B2 - Flammable Materials, D2B - Toxic Materials.
Ingredient(s) - Canadian Regulatory Information
1,2,4-trimethylbenzene
WHMIS - Ingredient Disclosure List
1,3,5-trimethylbenzene
WHMIS - Ingredient Disclosure List
acetone
WHMIS - Ingredient Disclosure List
hexane
WHMIS - Ingredient Disclosure List
isohexane
WHMIS - Ingredient Disclosure List
stoddard solvent
WHMIS - Ingredient Disclosure List
WHMIS - Canada (Pictograms)
NFPA HMIS
HEALTH 2
3
FLAMMABILITY 3
2 0
REACTIVITY 0
PERSONAL PROTECTION
16. Other Information
Revision/Preparer Information
This MSDS Supersedes A Previous MSDS Dated: 03/19/2008
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties and
make no representations as to the accuracy or completeness of the information contained therein, and assume
no responsibility regarding the suitablility of this information for the user's intended purposes or for the
consequences of its use. Each individual should make a determination as to the suitability of the information
for their particular purposes(s).
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