MATERIAL SAFETY DATA SHEET
MANUFACTURER Varian Instruments ?Middelburg
ADDRESS Herculesweg 8
4338 PL Middelburg, Netherlands
PHONE 31.118.67100 MSDS Number: 1002-741032 Rev. 1
EMERGENCY PHONE 1.800.424.9300 ?CHEMTREC USA Date: September 20, 2007
FAX 31.118.633118 Prepared by: Corporate EH&S
SECTION 1: MATERIAL IDENTIFICATION
Product Name: ASTM D3710 Quantitative Calibration Mix - Testmix CP741032
Synonyms: None
SECTION 2: HAZARD IDENTIFICATION
Emergency Overview: Extremely flammable. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. Possible risk of impaired fertility. Possible risk of harm to the unborn child. Harmful: may cause lung damage if
swallowed. Harmful by inhalation. Irritating to skin. Harmful: danger of serious damage to health by prolonged exposure through
inhalation in contact with skin, and if swallowed.
Potential Health Effects
Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
Skin Contact: Causes skin irritation. Harmful if absorbed through skin.
Eye Contact: May cause eye irritation.
Target Organ Information: Nerves. Kidneys. Liver. Heart. Bladder. Brain. Lungs. Eyes. Ears. Testes.
SECTION 3: COMPOSITION
An ampoule/vial containing the following:
Concentration NTP IARC
Component CAS Number (Weight %) Carcinogen Status Carcinogen Status
not listed not listed
Propane 74-98-6 3 - 6%
not listed not listed
Butane 106-97-8 4 - 7%
not listed not listed
2-Methylpropane 75-28-5 1 - 3%
not listed not listed
n-Propylbenzene 103-65-1 3 - 6%
not listed not listed
n-Pentane 109-66-0 5 - 10%
not listed not listed
Heptane 142-82-5 6 - 12%
not listed not listed
n-Octane 111-65-9 3 - 6%
not listed not listed
Decane 124-18-5 2 - 4%
not listed not listed
Dodecane 112-40-3 2 - 4%
not listed not listed
n-Tridecane 629-50-5 1 - 3%
not listed not listed
n-Tetradecane 629-59-4 1 - 3%
not listed not listed
n-Pentadecane 629-62-9 1 - 3%
not listed not listed
p-Xylene 106-42-3 12 - 18%
not listed not listed
Butylbenzene 104-51-8 3 - 6%
not listed not listed
2,4-Dimethylpentane 108-08-7 3 - 6%
not listed not listed
2-Methylpentane 107-83-5 3 - 6%
not listed not listed
2-Methylbutane 78-78-4 5 - 10%
not listed not listed
Toluene 108-88-3 10 - 15%
not listed not listed
n-Hexane 110-54-3 3 - 6%
WARNING: This product contains Toluene [CAS# 108-88-3], a chemical known to the State of California to cause birth defects or
other reproductive harm.
MSDS# 1002-741032 Revision 1 Effective Date 09/20/07 Page 1 of 4
SECTION 4: FIRST AID INFORMATION
Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Can cause rapid suffocation. Harmful if
inhaled.
Ingestion: If swallowed, wash out mouth with water provided person is conscious. Call a physician.
Skin Contact: In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing
and shoes. Call a physician.
Eye Contact: In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing
by separating the eyelids with fingers. Call a physician.
SECTION 5: FIRE-FIGHTING INFORMATION
Fire: Flash point (closed cup): <-73篊
Autoignition temperature: Not available
Flammable limits in air % by volume: 1% to 83%
NFPA Rating: health-2; flammability-4; reactivity-0
Explosion: Above flash point, vapor-air mixtures are explosive. Vapors can flow along surfaces to distant ignition source and
flash back. Sealed containers may rupture when heated. Contact with strong oxidizers may cause fire. Sensitive to static
discharge.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water may be ineffective. Water spray may be used to keep fire
exposed containers cool, dilute spills to nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Use proper personal protective equipment as indicated in Section 8. Ventilate area of leak or spill. Remove all sources of ignition.
Absorb spill with inert material (e.g. vermiculite, sand or earth), scoop up with a nonsparking tool, then place into a suitable
container for disposal. Do not flush to sewer!
SECTION 7: HANDLING AND STORAGE
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated
area. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Avoid ingestion and
inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8: EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment
Eye Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166. Maintain eye wash fountain and quick-drench facilities in
work area.
Skin Protection: Wear impervious gloves, apron, and/or clothing.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its
source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A
Manual of Recommended Practices", most recent edition, for details.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear to yellow liquid Boiling Point: Not available
Odor: Characteristic Melting Point: Not available
Solubility: Negligible. Vapor Density: Not available
Specific Gravity: Not available Vapor Pressure (mm Hg): Not available
pH: Not applicable. Evaporation Rate: Not available
Molecular Formula: Mixture ?Not applicable % Volatiles by Volume: 100
Molecular Weight: Mixture ?Not applicable
MSDS# 1002-741032 Revision 1 Effective Date 09/20/07 Page 2 of 4
SECTION 10: STABILITY AND REACTIVITY DATA
Stability: Stable at room temperature in sealed containers.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers, heat, and sources of ignition.
Conditions to Avoid: Incompatibles.
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicity: Note : the toxicological properties of this mixture have not been thoroughly investigated.
Signs and Symptoms of Exposure: Exposure can cause: Narcotic effect. Lung irritation, chest pain, and edema which may be
fatal. CNS depression. Gastrointestinal disturbances. Damage to the liver. Damage to the kidneys. Blood effects. Inhalation studies
on toluene have demonstrated the development of inflammatory and ulcerous lesions of the penis, prepuce, and scrotum in
animals.
SECTION 12: ECOLOGICAL INFORMATION
Environmental Fate: Not available
Environmental Toxicity: Not available
SECTION 13: DISPOSAL GUIDELINES
Dispose in compliance with federal, state, and local regulations. Chemical waste generators must determine whether a discarded
chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts
261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate
classification.
USEPA RCRA waste number D001.
The information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with other
materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal
method.
SECTION 14: TRANSPORT INFORMATION
Ship in accordance with all applicable local, State, Federal, and International transportation regulations.
The following is a summary only. Check regulations for complete information:
United States (Land, D.O.T.) International (Air, I.C.A.O.)
Proper Shipping Name: Petrol Proper Shipping Name: Petrol
Hazard Class: 3 Hazard Class: 3
UN/NA: UN1203 UN/NA: UN1203
Packing Group: II Packing Group: II
MSDS# 1002-741032 Revision 1 Effective Date 09/20/07 Page 3 of 4
SECTION 15: REGULATORY INFORMATION
US Federal
TSCA: All components are listed on the TSCA inventory.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: No
US State
California Proposition 65: WARNING: This product contains Toluene [CAS# 108-88-3], a chemical known to the State of California
to cause birth defects or other reproductive harm.
Other Regulations
Classification and Labeling according to EU Directives
Indication of Danger Annex I Index Number 601-022-00-9
F+ Extremely Flammable
Xn Harmful
N Dangerous for the environment
R-Phrases
12 Extremely flammable.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
62 Possible risk of impaired fertility.
63 Possible risk of harm to the unborn child.
65 Harmful: may cause lung damage if swallowed.
20 Harmful by inhalation.
38 Irritating to skin.
48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation in contact with skin,
and if swallowed.
S-Phrases
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - no smoking.
36/37 Wear suitable protective clothing and gloves.
60 This material and its container must be disposed of as hazardous waste.
61 Avoid release to the environment. Refer to special instructions/safety data sheets.
62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
SECTION 16: OTHER INFORMATION
This MSDS was prepared in accordance with ANSI Z400.1-2003 and EC No 1907/2006 recommended formats.
The information contained herein is believed to be accurate, but does not purport to be all-inclusive and shall be used only as a
guide. Varian, Inc., does not guarantee said information is accurate or complete, nor shall any of this information constitute a
warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the goods, or the fitness of the goods
for a particular purpose. It is the user's responsibility to determine the suitability of this information and to assure the adoption of
necessary precautions. Varian, Inc. shall not be held liable for any damage resulting from handling or from contact with the above
product, nor for the results obtained, or for incidental or consequential damage arising from the use of these data. No freedom from
infringement of any patent, copyright or trademark is to be inferred.
MSDS# 1002-741032 Revision 1 Effective Date 09/20/07 Page 4 of 4
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