MATERIAL SAFETY DATA SHEET
conforming to EC-directive 91/155/EC
Surfynol?61
78010
Edition: 09.01.2007
_____________________________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product Information:
Surfynol?61
Product Name:
Article no.: 78010
Application: Artists' and Restauration Material
Company: Kremer Pigmente GmbH & Co. KG
Hauptstrasse 41-47, D - 88317 Aichstetten
Tel. +49 7565 91120 Fax. +49 7565 1606
www.kremer-pigmente.de, kremer-pigmente@t-online.de
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Characterization:
Component CAS No. EINECS No. Conc. Hazard Symbol
3,5-Dimethylhex-1-in-3-ol 107-54-0 203-500-9 100 % Xn, R10, 22,
36/38
Acetylenic alcohol.
3. HAZARDS IDENTIFICATION
Xn Harmful
R 10: Flammable
R 22: Harmful if swallowed.
R 36/38: Irritating to eyes and skin.
Potential Health Effects:
Inhalation: May cause nose, throat, and lung irritation. Inhalation of vapors
and/or aerosols in high concentration may cause irritation of
respiratory system.
Eye contact: Severe eye irritation.
Skin contact: Mild skin irritation.
Ingestion: Harmful if swallowed.
Chronic health hazard: This product contains no listed carcinogens according to Directive
67/548/EEC, IARC, ACGIH and/or NTP in concentrations of 0.1%
or greater.
Aggravated medical condition: Eye disease, asthma.
Target organs: Eyes.
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MATERIAL SAFETY DATA SHEET
conforming to EC-directive 91/155/EC
Surfynol?61
78010
Edition: 09.01.2007
_____________________________________________________________________________________________
Symptoms: Repeated and/or prolonged exposure to low concentrations of
vapors and/or aerosols may cause: sore throat.
4. FIRST AID MEASURES
General advice: Seek medical advice. If breathing has stopped or is labored, give
assisted respirations. Supplemental oxygen may be indicated. If the
heart has stopped, trained personnel should begin cardiopulmonary
resuscitation immediately.
After eye contact: Rinse immediately with plenty of water also under the eyelids for
at least 20 min. Remove contact lenses.
After skin contact: Wash off with soap and plenty of water. Remove contaminated
clothing.
After inhalation: Move to fresh air. If breathing has stopped or is labored, give
assisted respirations. Supplemental oxygen may be indicated. If the
heart has stopped, trained personnel should begin cardiopulmonary
resuscitation immediately.
After ingestion: Never give anything by mouth to an unconscious person. If a
person vomits when lying on his back, place him in the recovery
position. Prevent aspiration of vomit. Turn victim磗 head to the
side.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: Alcohol resistant foam, carbon dioxide (CO2), dry chemical, dry
sand, limestone powder.
Specific hazards: Incomplete combustion may form carbon monoxide. Fire or
intense heat may cause violent rupture of packages. May form
explosive mixtures in air. Downwind personnel must be evacuated.
Burning produces obnoxious and toxic fumes. In the event of fire,
cool tanks with water spray.
Special protective equipment: Use personal protective equipment. Wear self-contained breathing
apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use self-contained breathing apparatus and chemically protective
clothing. Wear suitable protective clothing, gloves and eye/face
protection. Remove all sources of ignition. Evacuate personnel to
safe areas.
Environmental precautions: Shut off or remove all ignition sources. Construct a dike to prevent
spreading.
Methods for cleaning up: Approach suspected leak areas with caution. Absorb with inert
materials such as: dry sand, vermiculite, activated charcoal. Place
in appropriate chemical waste container.
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MATERIAL SAFETY DATA SHEET
conforming to EC-directive 91/155/EC
Surfynol?61
78010
Edition: 09.01.2007
_____________________________________________________________________________________________
Additional advice: Open enclosed spaces to outside atmosphere. If possible, stop flow
of product.
7. HANDLING AND STORAGE
Handling: Emergency showers and eye wash stations should be readily
accessible. Adhere to work practice rules established by
governmental regulations. Avoid breathing vapors and/or aerosols.
Avoid contact with eyes. Use only in well-ventilated areas. Use
personal protective equipment. When using, do not eat, drink or
smoke.
Storage: Keep containers tightly closed in a dry, cool and well-ventilated
place. To avoid ignition of vapors by static electricity discharge, all
metal parts of the equipment must be grounded. Keep away from
heat and sources of ignition. Keep in a dry, cool place. Keep away
from children.
Storage class (VCI): 3A
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposition limits: ---
Engineering measures: Use explosion proof equipment. Provide readily accessible eye
wash stations and safety showers. Provide neutral or explosion-
proof ventilation adequate to ensure concentrations are kept below
exposure limits.
Personal protective equipment:
General protective measures: Avoid breathing vapors and/or aerosols. Avoid contact with skin,
eyes and clothing.
Hygiene measures: Keep away from food, drink and animal feeding stuffs. Wash
hands before breaks and immediately after handling the product.
Respiratory protection: Wear appropriate respirator when ventilation is inadequate.
Hand protection: Neoprene gloves. The breakthrough time of the selected glove(s)
must be greater than the intended use period.
Eye protection: Chemically resistant goggles.
Skin and body protection: Long sleeve shirts and trousers without cuffs.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: aqueous liquid
Color: light yellow
Odor: organic
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MATERIAL SAFETY DATA SHEET
conforming to EC-directive 91/155/EC
Surfynol?61
78010
Edition: 09.01.2007
_____________________________________________________________________________________________
pH-Value: 7
Boiling temperature: 160癈 (320癋)
Melting temperature: not applicable
Flash point: 49癈 (120癋) Method: Pensky-Martin
Inflammability (solid, gas): not applicable
Autoignition: no data
Explosion limits: no data
53.064 lb/ft3 (0.85 g/cm3) at 21癈 (70癈)
Density:
Vapor pressure: 4.5 mmHg (21癈)
Vapor density: (Air = 1 ) 4.34
10. STABILITY AND REACTIVITY
Stability: Stabile under normal conditions.
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Reactive metals (e.g. sodium, calcium, zinc, etc.). Materials react
with hydroxyl compounds. Dehydrating agents. Oxidizing agents.
Hazardous decomposition
products: Heating above 65癈 in the presence of strong bases can liberate
acetylene and methyl isobutyl ketone. Carbon monoxide, carbon
dioxide, aldehydes. Flammable hydrocarbon fragments (e.g.
acetylene).
11. TOXICOLOGICAL INFORMATION
Acute Toxicity:
LD50, oral, rat): > 200 mg/kg
LC50, inhalation (1h; rat): > 20 mg/l
LD50, dermal: no data available
Primary effect:
Irritant effect on eye: Severe eye irritation.
Irritant effect on skin: Mild skin irritation.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects:
Aquatic toxicity: No data is available on the product ifself.
Toxicity for other organisms: No data available.
Persistency and degradability:
Biodegradability: According to the results of tests of biodegradability this product is
considered as being readily biodegradable.
Mobility: No data available.
Bioaccumulation: No data available.
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MATERIAL SAFETY DATA SHEET
conforming to EC-directive 91/155/EC
Surfynol?61
78010
Edition: 09.01.2007
_____________________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Product: Product may not be disposed of with regular waste nor enter waste
water. Must be disposed of in accordance with local official
regulations.
Uncleaned packaging: Empty container completely and thoroughly and recycle.
14. TRANSPORT INFORMATION
Land transportation:
ADR/RID-GGV/E-Class: 3 UN No.: 1993
Packaging group: III Label: 3
Hazard no.: 33 Classification No.: F1
Tunnel code: D/E
Correct technical name: FLAMMABLE LIQUID, N.O.S. (3,5-Dimethyl-1-hexyn-3-ol)
Sea transportation:
IMDG/GGVSea-Class: 3 UN No.: 1993
Packaging group: III Label: 3
EmS.: F-E,S-D Marine pollutant: --
Correct technical name: FLAMMABLE LIQUID, N.O.S. (3,5-Dimethyl-1-hexyn-3-ol)
Air transportation:
ICAO/IATA-Class: 3 UN No.: 1993
Packaging group: III Label: 3
Correct technical name: FLAMMABLE LIQUID, N.O.S. (3,5-Dimethyl-1-hexyn-3-ol)
15. REGULATORY INFORMATION
Designation according to EC guidelines: The material is subject to classification according to
EC lists.
Hazard Designation:
Xn Harmful
Risk Phrases:
R 10: Flammable
R 22: Harmful if swallowed.
R 36/38: Irritating to eyes and skin.
Safety Phrase:
S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
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MATERIAL SAFETY DATA SHEET
conforming to EC-directive 91/155/EC
Surfynol?61
78010
Edition: 09.01.2007
_____________________________________________________________________________________________
USA (TSCA): Included on Inventory.
EU (EINECS): Included on EINECS inventory or polymer substance, monomers
included on EINECS inventory or no longer polymer.
Canada (DSL): Included on Inventory.
Australia (AICS): Included on Inventory.
Japan (ENCS): Included on Inventory.
South Korea (ECL): Included on Inventory.
China (SEPA): Included on Inventory.
Philippines (PICCS): Included on Inventory.
16. FURTHER INFORMATION
This product should be stored, handled and used in accordance with good hygiene practices and in
conformity with any legal regulations. This information contained herein is based on the present
state of knowledge and is intended to describe our product from the point of view of safety
requirements. It should therefore not be construed as guaranteeing specific properties.
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