Material Safety Data Sheet
RAMUC TYPE DS - WHITE 1 GAL. 26514
Version 1 Print Date 10/24/2005
REVISION DATE: 10/20/2005
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : RAMUC TYPE DS - WHITE 1 GAL. 26514
Product code :
COMPANY : Republic Powdered Metals
2628 Pearl Road
Medina, OH 44256
Telephone : (800) 551-7081
Emergency Phone: : 1-800-551-7081
After Hours: Chemtrec 1-800-424-9300
Product use : Coating
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
White. Liquid. No serious effects anticipated under normal conditions of use. Leave area to breathe fresh air.
Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation No serious effects anticipated under normal conditions of use.
:
Eyes Direct contact may cause mild irritation.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause mild irritation.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient
evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the
TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis
may result from breathing free silica. Diacetone alcohol caused liver damage in experimental animals. Can
cause narcosis at high concentrations. In animal studies, prolonged or repeated exposure to ethylene glycol (or
its components) has been suggested as a cause of reproductive effects and kidney and liver damage. It has
caused birth defect in animal studies at high oral doses. Prolonged and repeated to ethylene glycol (or its
components) has been suggested as a cause of kidney and liver damage in humans. Ethylene glycol is not
expected to cause cancer in humans, since it did not cause cancer in laboratory animals and is not listed as a
carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program
(NTP), or the Occupational Safety and Health Administration (OSHA). Fillers are encapsulated and not
expected to be released from product under normal conditions of use.
SECTION 3 - PRODUCT COMPOSITION
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Material Safety Data Sheet
RAMUC TYPE DS - WHITE 1 GAL. 26514
Version 1 Print Date 10/24/2005
REVISION DATE: 10/20/2005
Chemical Name CAS-No. Weight %
Water 7732-18-5 30.0 - 60.0
Methyl Methacrylate, Copolymer With
25852-37-3 15.0 - 40.0
Butyl Acrylate, POLYMER (BA/MMA)
IN sap1167
Titanium dioxide 13463-67-7 10.0 - 30.0
Barium sulfate 7727-43-7 10.0 - 30.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 7.0 - 13.0
Ethylene glycol 107-21-1 1.0 - 5.0
Diacetone alcohol 123-42-2 1.0 - 5.0
Amorphous silica 7631-86-9 1.0 - 5.0
2-Butoxyethanol (Glycol ether) 111-76-2 1.0 - 5.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Get medical attention. Do not induce vomiting.
Notes to physician : Not applicable.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Tag Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : This product is not expected to burn under normal conditions of use.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : This product not expected to ignite under normal conditions of use.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Transfer to appropriate container for disposal. Stop flow. Contain spill. Keep out of water courses. Absorb
spill in sand, earth or other suitable material. Transfer to appropriate container for disposal. Use appropriate
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Material Safety Data Sheet
RAMUC TYPE DS - WHITE 1 GAL. 26514
Version 1 Print Date 10/24/2005
REVISION DATE: 10/20/2005
protective equipment. Avoid contact with material.
SECTION 7 - HANDLING AND STORAGE
Handle in compliance with common hygienic practices. Clean hands thoroughly after handling. Keep from
freezing. Do not use in confined or poorly ventilated areas. Prevent inhalation of vapor, ingestion, and contact
with skin eyes and clothing. Keep container closed when not in use. Precautions also apply to emptied
containers. Store in sealed containers in a dry, ventilated warehouse location above freezing.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Not required under normal conditions of use.Wear appropriate, NIOSH/MSHA
approved respirator with combination particulate filter and vapor/gas
removing cartridge when the ventilation is not adequate or if it is necessary to
abrade or grind surfaces coated with this product.
Hand protection : Use suitable impervious rubber or vinyl gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Other equipment not normally required.Use professional judgment in the
selection, care, and use.
Engineering measures : Not required under normal conditions of use.Use local exhaust when the
general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Barium sulfate 7727-43-7 ACGIH TWA: 10 mg/m3
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
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Material Safety Data Sheet
RAMUC TYPE DS - WHITE 1 GAL. 26514
Version 1 Print Date 10/24/2005
REVISION DATE: 10/20/2005
Chemical Name CAS Number Regulation Limit Form
Crystalline Silica 14808-60-7 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
(Quartz)/ Silica Sand OSHA TWA: 0.1 mg/m3 Respirable.
OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
Diacetone alcohol 123-42-2 ACGIH TWA: 50 ppm
OSHA PEL: 240 mg/m3
Amorphous silica 7631-86-9 ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 0.8 mg/m3
2-Butoxyethanol (Glycol 111-76-2 ACGIH TWA: 20 ppm
ether) OSHA PEL: 240 mg/m3
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : White
Odor : Mild
pH : 9.5
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : 212.5 ?101 ?br>
F, C
Water solubility : Soluble
Specific Gravity : 1.39
% Volatile Weight : 45 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Strong acids.Strong bases.
Stability : Stable
Hazardous polymerization : Will not occur.
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Material Safety Data Sheet
RAMUC TYPE DS - WHITE 1 GAL. 26514
Version 1 Print Date 10/24/2005
REVISION DATE: 10/20/2005
SECTION 11 - TOXICOLOGICAL INFORMATION
Ethylene glycol, CAS-No.: 107-21-1
Acute oral toxicity (LD-50 oral) 6,140 mg/kg ( Rat )
Diacetone alcohol, CAS-No.: 123-42-2
Acute oral toxicity (LD-50 oral) 4,000 mg/kg ( Rat )
Amorphous silica, CAS-No.: 7631-86-9
Acute oral toxicity (LD-50 oral) 22,500 mg/kg ( Rat )
2-Butoxyethanol (Glycol ether), CAS-No.: 111-76-2
Acute oral toxicity (LD-50 oral) 1,480 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 400 mg/kg ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
RCRA Class : D005: Reportable Quantity = 1000 lbs. Barium
This classification applies only to the material as it was originally produced.
Disposal Method : Waste not regulated under RCRA. Incinerate at EPA approved facility or dispose of
waste in compliance with state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Ethylene glycol 107-21-1
2-Butoxyethanol (Glycol ether) 111-76-2
SARA 311/312 Hazards : Acute Health Hazard
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Material Safety Data Sheet
RAMUC TYPE DS - WHITE 1 GAL. 26514
Version 1 Print Date 10/24/2005
REVISION DATE: 10/20/2005
OSHA Hazardous Components :
Titanium dioxide 13463-67-7
Barium sulfate 7727-43-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Ethylene glycol 107-21-1
Diacetone alcohol 123-42-2
Amorphous silica 7631-86-9
2-Butoxyethanol (Glycol ether) 111-76-2
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 191 g/l
exempt solvent)
VOC Method 310 : 6%
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Titanium dioxide 13463-67-7
Barium sulfate 7727-43-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Ethylene glycol 107-21-1
Diacetone alcohol 123-42-2
Amorphous silica 7631-86-9
2-Butoxyethanol (Glycol ether) 111-76-2
Penn RTK Components : Water 7732-18-5
Methyl Methacrylate, Copolymer With 25852-37-3
Butyl Acrylate, POLYMER (BA/MMA)
IN sap1167
Titanium dioxide 13463-67-7
Barium sulfate 7727-43-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Ethylene glycol 107-21-1
Diacetone alcohol 123-42-2
Amorphous silica 7631-86-9
2-Butoxyethanol (Glycol ether) 111-76-2
NJ RTK Components : Water 7732-18-5
Methyl Methacrylate, Copolymer With 25852-37-3
Butyl Acrylate, POLYMER (BA/MMA)
IN sap1167
Titanium dioxide 13463-67-7
Barium sulfate 7727-43-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
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Material Safety Data Sheet
RAMUC TYPE DS - WHITE 1 GAL. 26514
Version 1 Print Date 10/24/2005
REVISION DATE: 10/20/2005
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
1333-86-4 Carbon Black
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 1 0 = Minimum
1 = Slight
Flammability 0
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
NTP - National Toxicology Program RCRA - Resource Conservation and Recovery Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
CERCLA - Comprehensive Environmental Response, Compensation, and WHMIS - Workplace Hazardous Materials Information
Liability Act System
OSHA - Occupational Safety and Health Administration
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