Ciba Specialty Chemicals Corporation
2301 Wilroy Road
PO Box 820
Suffolk, VA 23434
24-Hour Health/Environmental Emergency Phone: 1-800-873-1138
Material Safety Data Sheet
LODYNE S-103A
Value beyond chemistry
MSDS No: 44 Date Printed: 1/29/2003 Effective Date: 1/28/03
Health 2
1. PRODUCT IDENTIFICATION 1
Flammability 1
2 0
Reactivity 0
Chemical Family: Fluoroalkyl Sodium Sulfate
Protective Equipment C
Intended Use: Additive for Fire Extinguishing Compound
HMIS RATING
NFPA RATING
2. COMPOSITION / INFORMATION ON INGREDIENTS
ACGIH/PPM OSHA/PPM
CAS No. Common Name: TWA STEL PEL % by Wt.
Confidential Fluorochemical anionic surfactant None None None 43 - 47
Dermal: Not evaluated
Inhalation: Not evaluated
Ingestion: Not evaluated
107-41-5 Hexylene glycol None 25 None 15
Dermal: (Rabbit) LD50 > 10,000 mg/kg
Inhalation: (Rat) ALC (saturated vapor) >
18,000 ppm (8 hr)
Ingestion: (Rat) LD50 = 4,470 mg/kg
3. HAZARDS IDENTIFICATION
Route(s) of Entry: Dermal and inhalation.
Potential Health Effects: May cause eye and skin irritation.
Carcinogenicity (NTP): Not listed.
Carcinogenicity (IARC): Not listed.
Carcinogenicity (OSHA): Not listed.
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4. FIRST AID MEASURES
Ingestion: If conscious, give plenty of water to drink. Get medical attention. If unconscious, do not give anything to drink. Get
immediate medical attention.
Skin: Wash with mild soap and water. If irritation occurs, get medical attention. If clothing is contaminated, remove and wash
before reuse.
Inhalation: Remove to fresh air. Get medical attention.
Eyes: Flush eyes with water for at least 15 minutes. Get medical attention.
5. FIRE FIGHTING MEASURES
203癋 (95 癈)
Flash Point:
Not evaluated
Flammable Limits in Air (Lower - % by volume):
Not evaluated
Flammable Limits in Air (Upper - % by volume):
Not evaluated
Auto-Ignition Temperature:
Not regulated
TDG Flammability Class (Canada):
General Hazards: None known.
Fire Fighting Equipment: Use self contained breathing apparatus
Fire Fighting Extinguishing Media: Foam.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
Hazardous Combustion Products: Burning may produce oxides of carbon, nitrogen or sulfur.
Explosive Data-Sensitivity to Mechanical Impact: Not evaluated.
Explosive Data-Static Discharge: Not evaluated.
Emergency Response Guidebook Information: None
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Absorb onto sand or other absorbent material. Shovel into closable container for disposal. Wear
protective equipment specified (Section 8). Do not use water, as large volumes of foam develop and slippery conditions may
result.
7. HANDLING AND STORAGE
CAUTION! May cause eye and skin irritation. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. For
industrial use only. Keep from freezing.
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Effective Date: 1/28/03 LODYNE S-103A Ciba Specialty Chemicals Corporation
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal Protective Equipment: Wear appropriate equipment to prevent probability of exposure and personal contact. Deluge
safety shower and eye wash should be located near work area.
Eye Protection: Wear side-shield safety glasses.
Skin Protection: Wear impervious gloves as a standard handling procedure.
Respiratory Protection: Use NIOSH approved respirator where there is likelihood of inhalation of the product mist.
Engineering Controls: Local exhaust recommended, mechanical exhaust acceptable.
Emergency Response Protection: No additional specialized equipment should be required.
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Physical Form:
Pale yellow
Color:
Slight
Odor:
Not evaluated
Odor Threshold:
Soluble
Solubility in Water:
Not evaluated
Vapor Pressure:
1.2 (H20 = 1)
Specific Gravity:
100癈 (212 癋)
Boiling Point:
8?C (46 ?F)
Melting Point:
Not evaluated
Freezing Point:
Not evaluated
Decomposition Temperature:
Not evaluated
Evaporation Rate:
Not evaluated
Bulk Density:
Not evaluated
Vapor Density:
< 15 % For component
VOC:
6.5 - 8
pH:
~ 2.2 log Pow
Coefficient of water/oil:
Volatile(s): 40%
10. STABILITY AND REACTIVITY
Stability: Stable
Incompatibility: None known.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
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Effective Date: 1/28/03 LODYNE S-103A Ciba Specialty Chemicals Corporation
Eye Irritation: (Rabbits) mild irritant
Skin Irritation: (Rabbits) minimal irritant
Inhalation Toxicity: Not evaluated.
Sensitization: Sensitization (Guinea Pig) - Not a sensitizer
Chronic/Carcinogenicity: Not evaluated.
Teratology: Not evaluated.
Reproduction: Not evaluated.
Mutagenicity: Ames Test - negative
Acute Oral Effects: (Rats) LD50 > 10,000 mg/kg
Acute Dermal Toxicity: Not evaluated.
Additional Information: None
12. ECOLOGICAL INFORMATION
Biodegradability: Not evaluated
Ecotoxicity: (Fathead Minnow) LC50 = 707 mg/l (96 HR)
Daphnia Toxicity: EC50 = 470 mg/l (48 HR)
Biological Oxygen Demand (BOD5): 12 mg O2/g
Chemical Oxygen Demand (COD): 636 mg O2/g
Activated Sludge Respiration Inhibition Test: EC50 > 1,000 mg/l
Additional Information: None
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method: Bury or incinerate in approved site or facility in accordance with local, state (provincial) and federal
regulations.
Container Disposal Information: Emptied container may contain product residue and should not be reused.
RCRA Hazard Class: Refer to Section 15: Regulatory Information for RCRA status.
14. TRANSPORT INFORMATION
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Effective Date: 1/28/03 LODYNE S-103A Ciba Specialty Chemicals Corporation
DOT:
Not Regulated
Proper Shipping Name:
IATA:
Not Regulated
Proper Shipping Name:
IMDG:
Not Regulated
Proper Shipping Name:
TDG:
Not Regulated
Proper Shipping Name:
Additional Information: None
15. REGULATORY INFORMATION
US Federal Regulations:
Chemical Weapons Convention (CWC): This product does not contain any chemicals listed under the Chemical Weapons
Convention Schedule of Chemicals.
Clean Air Act -Hazardous Air Pollutants (HAP): This product does not contain any hazardous air pollutants (HAP), as defined
by the U.S. Clean Air Act Section 12 (40 CFR 61).
Clean Air Act - Ozone Depleting Substances (ODS): This product neither contains, nor was manufactured with, a Class I or
Class II ozone depleting substance (ODS), as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App. A+B).
Clean Water Act - Priority Pollutants (PP): This product does not contain any priority pollutants listed under the U.S. Clean
Water Act Section 307 (2)(1) Priority Pollutant List (40 CFR 401.15).
Occupational Safety and Health Act (OSHA): This product is hazardous under the criteria of the Federal OSHA Hazard
Communication Standard 29 CFR 1910.1200.
Resource Conservation and Recovery Act (RCRA): This product is not considered to be hazardous waste under RCRA (40
CFR 261).
SARA Title III: Section 302 - Extremely Hazardous Substances (EHS): This product does not contain any chemicals regulated
under Section 302 (40 CFR 355) as extremely hazardous substances.
SARA Title III: Section 304 - CERCLA: This product does not contain any chemicals regulated under Section 304 (40 CFR
302) as hazardous chemicals for emergency release notification ("CERCLA" List).
SARA Title III: Section 311/312 - Hazard Communication Standard (HCS): Immediate
SARA Title III: Section 313 Toxic Chemical List (TCL): This product does not contain any chemicals for routine annual toxic
chemical release reporting under Section 313 (40 CFR 372).
TSCA Section 5(e) - Consent Order / SNUR: This product is not subject to a Section 5(e) Consent Order or Significant New
Use Rule (SNUR).
TSCA Section 8(b) - Inventory Status: All chemical(s) comprising this product are either exempt or listed on the TSCA
inventory.
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Effective Date: 1/28/03 LODYNE S-103A Ciba Specialty Chemicals Corporation
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.
International Regulations:
Canadian Inventory Status: This product contains only chemicals that are currently listed on the Canadian Domestic Substance
List.
Canadian WHMIS: This product contains the following chemicals listed on the Canadian WHMIS Ingredient Disclosure List.
Chemical Name: 2,4-Pentanediol, 2-methyl-
Common Name: Hexylene glycol
CASRN: 107-41-5
Percent in Composition: 15 % by wt
Controlled product, Class D2B
State Regulations:
California Proposition 65: This product does not contain any chemicals currently on the California list of Known Carcinogens
and Reproductive Toxins.
Massachusetts Right-to-Know: The following is required composition information:
Chemical Name: 2,4-Pentanediol, 2-methyl-
Common Name: Hexylene glycol
CASRN: 107-41-5
Percent in Composition: 15 % by wt
New Jersey Right-to-Know: The following is required composition information:
Chemical Name: Fluorochemical anionic surfactant
NJ Registry #: 29943300001-6626P
Chemical Name: Water
CASRN: 7732-18-5
Chemical Name: 2,4-Pentanediol, 2-methyl-
CASRN: 107-41-5
Chemical Name: Sulfuric acid magnesium salt (1:1)
CASRN: 7487-88-9
Chemical Name: 1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propenyl)amino]-, monosodium salt
CASRN: 5165-97-9
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: Fluorochemical anionic surfactant
CASRN: Confidential
Comment: Not on Pennsylvania Hazardous Substance List
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Effective Date: 1/28/03 LODYNE S-103A Ciba Specialty Chemicals Corporation
Chemical Name: Water
CASRN: 7732-18-5
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2,4-Pentanediol, 2-methyl-
CASRN: 107-41-5
Comment: Hazardous Substance
16. OTHER INFORMATION
44
MSDS No:
Frances E. Knight
Approved By:
Director, Product Stewardship &
Title:
Regulatory Affairs, W&PT
01/28/03
Approved Date:
04/30/02
Supersedes Date:
Revision Summary: Changes in Section(s): 1 & 16.
Disclaimer: For further information, please contact: Phone: (757) 538-5126
Product Stewardship Team: Fax: (757) 538-8341
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or
warranty of any kind expressed or implied is made with respect to the information contained herein. This material safety data
sheet was prepared to comply with the OSHA Hazard Communication Standard (29 CFR 1910.1200) and with the Workplace
Hazardous Materials Information System (WHMIS).
This supersedes any previous information.
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