HMIS
H =1
MATERIAL SAFETY DATA SHEET F =0
R=0
PPE = See Section 8
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Lightweight Concrete Decks
Insulcel?PB Liquid Concentrate
Trade Name:
Chemical Names Hydrolysated Polypeptide Condensate
and Family:
Product Use: Protein Based Concentrate for Cellular-Concrete Foam
CAS # (Chemical
Abstract Service): Proprietary
Transportation Hazard Classification
United States DOT
Proper Shipping Name: Not applicable
Hazard Class: Nonhazardous
Identification #: Not applicable
Label(s) Required: None
Surface Freight Classification: Cellular concrete foam concentrate
Section II - Ingredients
EXPOSURE LIMITS
INGREDIENT OSHA PEL ACGIH TLV
121 mg/m3 - Ceiling Value
Hexylene glycol Not available
CAS # 107-41-5 25 ppm - Ceiling Value
Peptide condensate Not available Not available
CAS # Proprietary
INGREDIENT: % TOXICITY DATA: LD50 & LC50
(Chemical Name, CAS #, & Common Name) BY WT.
Polypeptide - alkylene polyol condensate 90-100 No toxicity data available
CAS # Proprietary
Hexylene glycol (2-Methyl-2, 4-pentanediol) 10% Max Oral Rat. LD50 = 3,700 mg/kg
CAS # 107-41-5 Oral Rbt. LD50 = 8,760 mg/kg
Trade Name: Insulcel?PB Liquid Concentrate
Page Two
Section III - Physical Data Section VI - Reactivity Data
Boiling Point: > 100癈 (212癋) Stability: Stable X Unstable ______
Evaporation Rate (Butyl Acetate = 1): < 1 Conditions to Avoid: None known
% Volatile by Volume: Unknown Hazardous Decomposition or Byproducts: Carbon
Vapor Pressure (mm Hg.): < 0.05 dioxide, carbon monoxide, alkenes and alkanes.
Vapor Density (AIR =1): Unknown Hazardous Polymerization: May occur Will not
Solubility in Water: Complete occur X
Bulk Density (lb./cu. ft): 75 Conditions to Avoid: Not applicable
Appearance and Odor: Dark brown liquid with
pungent odor. Section VII - Spill & Disposal Information -
Odor Threshold: Not determined U.S. Only
pH: 6 - 7.5
Specific Gravity (H2O=1): Approx. 1.2 If spilled, absorb with an inert, noncombustible
material such as sand, vermiculite or soil and remove
Section IV - Fire and Explosion Data to containers for disposal.
Flash Point: Not applicable Prevent liquid from entering sewers, waterways or
Method Used: Not applicable low areas by diking flow of spill. Product is
Flammable Limits: LEL: Not applicable biodegradable but will cause foaming in water.
UEL: Not applicable
N.F.P.A. Rating: H-1, F-0, R-0 Product is not considered a hazardous waste by the
Extinguishing Media: Product is noncombustible. U.S. EPA. Check with local and state agencies to
However, in case of fire, keep containers cool by determine if their regulations differ. Dispose of all
spraying or flooding with water. waste in accordance with applicable regulations.
Special Procedures: None
Unusual Hazards: None Section VIII - Special Protection Information
Section V - Health Hazard Data Warning Statements:
CAUTION! MAY CAUSE SLIGHT IRRITATION
Routes of Exposure:
INHALATION: This product is not expected to generate Liquid contact with eye or skin may cause slight
vapors due to its low vapor pressure. Exposure by irritation.
inhalation is therefore not expected to be a concern. Contains Hydrolysated peptide condensate
SKIN AND EYES: Eye contact with liquid may cause (CAS # Proprietary) with hexylene glycol (CAS #
slight reversible irritation. Skin contact with liquid 107-41-5).
may result in mild to moderate irritation. Repeated Precautionary Measures:
skin contact may cause drying of skin. Avoid contact with eyes, skin and clothing.
INGESTION: May be slightly toxic if swallowed causing Do not consume food, drink or tobacco in areas
nausea and vomiting. Hexylene glycol present at where they may become contaminated with this
10% by weight or less is a known anesthetic and may product.
cause signs of excitement followed by profound Wash thoroughly after handling.
depression if ingested. No long-term (chronic) effects Keep container tightly closed.
are known to occur from accidental ingestion of this Respiratory Protection:
product. Not generally required.
Carcinogenicity According to NTP, IARC and OSHA:
Not applicable
Trade Name: Insulcel?PB Liquid Concentrate
Page Three
Ventilation: If skin contact occurs, promptly flush exposed
SKIN:
Local Exhaust: Not generally required. area with plenty of water. Wash thoroughly with soap
Mechanical: If used indoors, adequate building and water after handling. If irritation occurs and
ventilation should be provided. persists, consult a physician.
Special: Not applicable SWALLOWED: Give two glasses of water to drink and
Other: Not applicable induce vomiting by sticking finger down throat. Call a
Skin Protection: Impervious rubber or synthetic physician. Never give anything by mouth to an
rubber gloves are recommended when handling this unconscious person.
product to prevent skin contact with liquid.
Eye Protection: Safety glasses with side shields are Section X - Government Reporting
recommended to avoid eye contact. If gloves come Information - U.S. Only
into contact with liquid, avoid hand-to-eye movement
to prevent secondary eye contact. SARA Title III Reporting Information:
Other Protective Clothing or Equipment: Appropriate Tier I & II Hazard Categories: Not applicable
work clothes and boots. Contains Extremely Hazardous - SARA III Section
Work/Hygienic Practices: 302 Ingredient: No
Use good personal hygiene and perform regular Contains Toxic Chemical Release - SARA III Section
housekeeping at jobsite. 313 Ingredient: No
Other Government Reporting Requirements: None
Section IX - Emergency and First Aid required.
Procedures Non-hazardous Ingredient Disclosure: Not
applicable.
EYES: In case of eye contact, flush eyes with plenty
of fresh, running water holding eyelids apart. If
irritation persists, consult a physician.
The data included herein are presented according to Siplast's practices current at the time of preparation hereof, are made available solely for
the consideration, investigation and verification of the original recipients hereof and do not constitute a representation or warranty for which
Siplast assumes legal responsibility. It is the responsibility of a recipient of this data to remain currently informed on chemical hazard
information, to design and update its own program and to comply with all national, federal, state and local laws and regulations applicable to
safety, occupational health, right-to-know and environmental protection.
Rev 10/07
HMIS
H =1
MATERIAL SAFETY DATA SHEET F =0
R=0
PPE = See Section 8
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Lightweight Concrete Decks
NVS?Concrete Aggregate & ZIC
Trade Name:
Chemical Names Expanded Vermiculite and Quartz (Sand)
and Family: Expanded Vermiculite Magnesium-Alumino-silicate Mineral
Product Use: Concrete Aggregate
Formula: Blend of Vermiculite and Sand
CAS # (Chemical NVS Concrete Aggregate - Mixture-Not applicable
Abstract Service): ZIC - 01318-00-9
Transportation Hazard Classification
United States DOT
Proper Shipping Name: Not applicable
UN/NA Number Not applicable
Domestic Hazard Class: Nonhazardous
Label/Placard Required: Not applicable
Surface Freight Classification: Vermiculite, other thin vermiculite
Section II - Ingredients
EXPOSURE LIMITS
INGREDIENT PERCENT (MAX) OSHA PEL ACGIH TLV
Quartz 1-60 TWA: TWA:
0.1 mg/m3 0.05 mg/m3
CAS # 14808-60-7
respirable dust (respirable fraction)
Vermiculite 50 - 100 Not Available Not Available
CAS # 001318-00-9
NOTE: See additional information in Work Hygienic Practices Section of the MSDS for additional information
concerning Quartz.
In addition to the exposure limits referenced above, the following non-specific limits for dust apply to this product:
OSHA, 15 mg/m3-TWA or Total Dust and 5 mg/mg3 as Respirable Dust, ACGIH, 10 mg/m3-TWA as Total dust and
3 mg/m3-TWA as Respirable Dust.
Section III - Physical Data
Appearance and Odor: Brown or gray free flowing
aggregate.
Boiling Point: Not applicable
Odor Threshold: None determined
Evaporation Rate (Butyl Acetate = 1): Not applicable
pH: Not applicable
% Volatiles (gr/L): (70癋) (21癈) Not available
Specific Gravity (H2O=1): Not applicable
Vapor Pressure (mm Hg.): Unknown
Physical State: Solid
Vapor Density (AIR =1): Unknown
Viscosity: Not Applicable
Solubility in Water: Negligible
Bulk Density (lb./cu. ft): 4-10 PCF
Trade Name: NVS?Concrete Aggregate & ZIC
Page Two
Section IV - Fire and Explosion Data Section VI - Reactivity Data
Flash Point: Not applicable Stability: Stable X Unstable ______
Flash Point Method: Not applicable Conditions to Avoid: Vermiculite is often used as a
Flammable Limits: LEL: Not available chemical absorbent. When contact with highly
UEL: Not available reactive chemicals or chemicals that can off-gas at
Auto-Ignition Temperature: Not available temperatures above room temperature (such as
Extinguishing Media: Not applicable. Product will not Hydrogen peroxide solutions), care should be taken
burn. to neutralize or make these materials inert prior to
Special Procedures: None absorption. If possible, consult the MSDS or supplier
Unusual Hazards: None known of the material being absorbed.
Hazardous Decomposition or Byproducts: None
Known
Section V - Health Hazard Data
Hazardous Polymerization: May occur Will not
occur X
Emergency Overview: Caution!
Causes eye irritation.
Caused respiratory tract irritation. Section VII - Spill & Disposal Information -
Avoid contact with eyes. U.S. Only
Potential Health Effects: Spills/Leaks:
INHALATION: Causes respiratory tract irritation. Carefully shovel or sweep up material and place in
Effects include: Coughing, shortness of breath, suitable container for recycle or disposal. Dampen
wheezing and reduced pulmonary function from with water spray or use other methods to clean spill,
pneumoconiosis (dusty lungs). which avoid creating dust. Dampen empty packaging
promptly. Avoid excessive handling of empty
Eye contact causes physical irritation.
EYE CONTACT: packaging, which may result in unnecessary release
Prolonged eye contact can result in redness and of airborne particulates. Use proper personal
itching. protective equipment.
SKIN CONTACT: Skin contact is not expected to cause
any harmful effects. Handling & Storage:
SKIN ABSORPTION: Not expected to be harmful if Precautionary Measures
absorbed through the skin. Avoid contact with eyes, skin, and clothing.
Ingestion is expected to be harmful.
INGESTION: Avoid creating and inhaling airborne dust or
Effects include: No other effects expected unless particulates.
listed below. Use only with adequate ventilation.
Wash clothing before reuse.
Carcinogenicity: Equip mixers with dust covers.
Quartz: NTP: Known: Yes Suspect: Yes Provide respiratory protection if needed.
IARC: Group 1 - Yes Group 2A & 2B - No FOR PROFESSIONAL USE ONLY. KEEP OUT OF
OSHA: Yes CHILDREN'S REACH.
Vermiculite: NTP: No Waste Disposal Procedures: Consult all regulations
IARC: No (federal, state, provincial, local) or a qualified waste
OSHA: No disposal firm when characterizing waste for disposal.
According to EPA (40 CRF ?261), waste of this
Prolonged exposure to respirable crystalline silica product is not defined as hazardous. Dispose of
(Quartz) has been associated with a lung cancer waste in accordance with all applicable regulations.
health risk in humans. See information in work According to US EPA (40 CFR ?261.3) waste of this
hygienic practices section concerning quartz. product is not defined as hazardous.
Mutagencity: Not applicable
Teratoenicity: Not applicable
Repoductive Toxicity: Not applicable
Trade Name: NVS?Concrete Aggregate & ZIC
Page Three
Section IX - Emergency and First Aid
Section VIII - Special Protection Information
Procedures
Personal Protective Equipment:
EYES: Flush eyes with water for at least 15 minutes
Respiratory Protection: Respiratory protection may
while holding eyelids open. If discomfort persists,
be desirable if dust is created in handling and is
consult a physician.
required at or above the Permissible Exposure Limit
Wash with soap and water. If
(PEL) for nuisance particulates. SKIN CONTACT:
discomfort or irritation persists, consult a physician.
Skin Protection: Gloves are recommended.
Remove contaminated clothing and wash before
Eye Protection: Safety glasses or goggles should be
reuse.
worn.
INGESTION: Adverse health effects are not expected if
Work/Hygienic Practices: Use good personal
swallowed.
hygiene practices.
INHALATION: If symptoms develop, get fresh air. If
Grace has not been able to detect respirable sized
symptoms persist, consult a physician. If breathing
quartz in vermiculite above the current Permissible
has stopped, give artificial respiration then oxygen if
Exposure Limit (PEL) during industrial hygiene
needed.
sampling of workers at Grace production facilities.
We believe that the highest potential for exposure
Section X - Government Reporting
exists at our production facilities due to the high
volume of product produced and handled. In Information - U.S. Only
addition, a wet sieving analysis combined with x-ray
diffractometry has been conducted on vermiculite.
Results indicate that respirable quartz is not present Regulatory Chemical Lists:
above 0.1% by weight limit established by the CERCLA (Comprehensive Response Compensation
Occupational Safety and Health Administration and Liability Act): None present unless listed below)
(OSHA) for carcinogens. OSHA states that if the SARA Title III (Superfund Amendments and
hazardous substance is contained in the product Reauthorization Act):
below 0.1% by weight and exposures do not exceed SARA Section 312/Tier I & II Hazard Categories.
permissible exposure limits, then the hazards do not Health Immediate (acute) No
Health Delayed (chronic) No
apply.
Flammable No
Reactive No
Quartz (Crystalline silica) is a naturally-occurring
Pressure No
mineral that is commonly contained in materials that
are mined from the earth's surface such as sand,
302 Reportable Ingredients (Identification Threshold
limestone, clay, and gypsum (Calcium sulfate). Total
1%): None
quartz is a value usually representing the combined
313 Reportable Ingredients (Chemicals present
fractions of large, non-respirable sized particles and
bellow report threshold are exempt): None
of respirable sized particles (less than ten microns in
National Volatile Organic Compound Emission
aerodynamic diameter). It is only the respirable
Standards for Architectural Coatings: Volatile
fraction of total quartz that is recognized as
Organic Content: (gr/L) Not Applicable
hazardous by professionals in the field of
WHMIS Classification(s): D - 2B
Occupational Health and by most regulatory
This product has been classified in accordance with
agencies. This product contains compounds subject
the hazard criteria of the Controlled Products
to exposure guidelines and/or identified as Regulations (CPR). This MSDS contains all the
carcinogens. However, due to the physical nature of information required by the CPR.
this product, these compounds are unlikely to reach
exposure limits.
Engineering Controls: General ventilation may be
desirable and should be used where appropriate.
Trade Name: NVS?Concrete Aggregate & ZIC
Page Four
State Regulatory Information:
California Proposition 65: WARNING! This product
contains substances known to the state of California
to cause cancer, birth defects, or other reproductive
harm.
New Jersey Hazardous List (Identification threshold
(0.1%): None
Pennsylvania Hazardous Substance List
(Identification threshold 0.01%): None
Massachusetts Hazardous Substance List
(identification threshold 0.001% (1 ppm):
Chemical Name Cas # Wt %
Quartz 014808-60-7 1
Chemical Inventory Status:
All chemicals in this product are listed or exempt from
listing in the following countries:
US CANADA
TSCA DSL NDSL
Yes Yes Yes
The data included herein are presented according to Siplast's practices current at the time of preparation hereof, are made available solely for
the consideration, investigation and verification of the original recipients hereof and do not constitute a representation or warranty for which
Siplast assumes legal responsibility. It is the responsibility of a recipient of this data to remain currently informed on chemical hazard
information, to design and update its own program and to comply with all national, federal, state, and local laws and regulations applicable to
safety, occupational health, right-to-know and environmental protection.
Rev 10/07
HMIS
H =1
MATERIAL SAFETY DATA SHEET F =0
R=0
PPE = See Section 8
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Lightweight Concrete Decks
NVS?Concrete Aggregate & ZIC
Trade Name:
Chemical Names Expanded Vermiculite and Quartz (Sand)
and Family: Expanded Vermiculite Magnesium-Alumino-silicate Mineral
Product Use: Concrete Aggregate
Formula: Blend of Vermiculite and Sand
CAS # (Chemical NVS Concrete Aggregate - Mixture-Not applicable
Abstract Service): ZIC - 01318-00-9
Transportation Hazard Classification
United States DOT
Proper Shipping Name: Not applicable
UN/NA Number Not applicable
Domestic Hazard Class: Nonhazardous
Label/Placard Required: Not applicable
Surface Freight Classification: Vermiculite, other thin vermiculite
Section II - Ingredients
EXPOSURE LIMITS
INGREDIENT PERCENT (MAX) OSHA PEL ACGIH TLV
Quartz 1-60 TWA: TWA:
0.1 mg/m3 0.05 mg/m3
CAS # 14808-60-7
respirable dust (respirable fraction)
Vermiculite 50 - 100 Not Available Not Available
CAS # 001318-00-9
NOTE: See additional information in Work Hygienic Practices Section of the MSDS for additional information
concerning Quartz.
In addition to the exposure limits referenced above, the following non-specific limits for dust apply to this product:
OSHA, 15 mg/m3-TWA or Total Dust and 5 mg/mg3 as Respirable Dust, ACGIH, 10 mg/m3-TWA as Total dust and
3 mg/m3-TWA as Respirable Dust.
Section III - Physical Data
Appearance and Odor: Brown or gray free flowing
aggregate.
Boiling Point: Not applicable
Odor Threshold: None determined
Evaporation Rate (Butyl Acetate = 1): Not applicable
pH: Not applicable
% Volatiles (gr/L): (70癋) (21癈) Not available
Specific Gravity (H2O=1): Not applicable
Vapor Pressure (mm Hg.): Unknown
Physical State: Solid
Vapor Density (AIR =1): Unknown
Viscosity: Not Applicable
Solubility in Water: Negligible
Bulk Density (lb./cu. ft): 4-10 PCF
Trade Name: NVS?Concrete Aggregate & ZIC
Page Two
Section IV - Fire and Explosion Data Section VI - Reactivity Data
Flash Point: Not applicable Stability: Stable X Unstable ______
Flash Point Method: Not applicable Conditions to Avoid: Vermiculite is often used as a
Flammable Limits: LEL: Not available chemical absorbent. When contact with highly
UEL: Not available reactive chemicals or chemicals that can off-gas at
Auto-Ignition Temperature: Not available temperatures above room temperature (such as
Extinguishing Media: Not applicable. Product will not Hydrogen peroxide solutions), care should be taken
burn. to neutralize or make these materials inert prior to
Special Procedures: None absorption. If possible, consult the MSDS or supplier
Unusual Hazards: None known of the material being absorbed.
Hazardous Decomposition or Byproducts: None
Known
Section V - Health Hazard Data
Hazardous Polymerization: May occur Will not
occur X
Emergency Overview: Caution!
Causes eye irritation.
Caused respiratory tract irritation. Section VII - Spill & Disposal Information -
Avoid contact with eyes. U.S. Only
Potential Health Effects: Spills/Leaks:
INHALATION: Causes respiratory tract irritation. Carefully shovel or sweep up material and place in
Effects include: Coughing, shortness of breath, suitable container for recycle or disposal. Dampen
wheezing and reduced pulmonary function from with water spray or use other methods to clean spill,
pneumoconiosis (dusty lungs). which avoid creating dust. Dampen empty packaging
promptly. Avoid excessive handling of empty
Eye contact causes physical irritation.
EYE CONTACT: packaging, which may result in unnecessary release
Prolonged eye contact can result in redness and of airborne particulates. Use proper personal
itching. protective equipment.
SKIN CONTACT: Skin contact is not expected to cause
any harmful effects. Handling & Storage:
SKIN ABSORPTION: Not expected to be harmful if Precautionary Measures
absorbed through the skin. Avoid contact with eyes, skin, and clothing.
Ingestion is expected to be harmful.
INGESTION: Avoid creating and inhaling airborne dust or
Effects include: No other effects expected unless particulates.
listed below. Use only with adequate ventilation.
Wash clothing before reuse.
Carcinogenicity: Equip mixers with dust covers.
Quartz: NTP: Known: Yes Suspect: Yes Provide respiratory protection if needed.
IARC: Group 1 - Yes Group 2A & 2B - No FOR PROFESSIONAL USE ONLY. KEEP OUT OF
OSHA: Yes CHILDREN'S REACH.
Vermiculite: NTP: No Waste Disposal Procedures: Consult all regulations
IARC: No (federal, state, provincial, local) or a qualified waste
OSHA: No disposal firm when characterizing waste for disposal.
According to EPA (40 CRF ?261), waste of this
Prolonged exposure to respirable crystalline silica product is not defined as hazardous. Dispose of
(Quartz) has been associated with a lung cancer waste in accordance with all applicable regulations.
health risk in humans. See information in work According to US EPA (40 CFR ?261.3) waste of this
hygienic practices section concerning quartz. product is not defined as hazardous.
Mutagencity: Not applicable
Teratoenicity: Not applicable
Repoductive Toxicity: Not applicable
Trade Name: NVS?Concrete Aggregate & ZIC
Page Three
Section IX - Emergency and First Aid
Section VIII - Special Protection Information
Procedures
Personal Protective Equipment:
EYES: Flush eyes with water for at least 15 minutes
Respiratory Protection: Respiratory protection may
while holding eyelids open. If discomfort persists,
be desirable if dust is created in handling and is
consult a physician.
required at or above the Permissible Exposure Limit
Wash with soap and water. If
(PEL) for nuisance particulates. SKIN CONTACT:
discomfort or irritation persists, consult a physician.
Skin Protection: Gloves are recommended.
Remove contaminated clothing and wash before
Eye Protection: Safety glasses or goggles should be
reuse.
worn.
INGESTION: Adverse health effects are not expected if
Work/Hygienic Practices: Use good personal
swallowed.
hygiene practices.
INHALATION: If symptoms develop, get fresh air. If
Grace has not been able to detect respirable sized
symptoms persist, consult a physician. If breathing
quartz in vermiculite above the current Permissible
has stopped, give artificial respiration then oxygen if
Exposure Limit (PEL) during industrial hygiene
needed.
sampling of workers at Grace production facilities.
We believe that the highest potential for exposure
Section X - Government Reporting
exists at our production facilities due to the high
volume of product produced and handled. In Information - U.S. Only
addition, a wet sieving analysis combined with x-ray
diffractometry has been conducted on vermiculite.
Results indicate that respirable quartz is not present Regulatory Chemical Lists:
above 0.1% by weight limit established by the CERCLA (Comprehensive Response Compensation
Occupational Safety and Health Administration and Liability Act): None present unless listed below)
(OSHA) for carcinogens. OSHA states that if the SARA Title III (Superfund Amendments and
hazardous substance is contained in the product Reauthorization Act):
below 0.1% by weight and exposures do not exceed SARA Section 312/Tier I & II Hazard Categories.
permissible exposure limits, then the hazards do not Health Immediate (acute) No
Health Delayed (chronic) No
apply.
Flammable No
Reactive No
Quartz (Crystalline silica) is a naturally-occurring
Pressure No
mineral that is commonly contained in materials that
are mined from the earth's surface such as sand,
302 Reportable Ingredients (Identification Threshold
limestone, clay, and gypsum (Calcium sulfate). Total
1%): None
quartz is a value usually representing the combined
313 Reportable Ingredients (Chemicals present
fractions of large, non-respirable sized particles and
bellow report threshold are exempt): None
of respirable sized particles (less than ten microns in
National Volatile Organic Compound Emission
aerodynamic diameter). It is only the respirable
Standards for Architectural Coatings: Volatile
fraction of total quartz that is recognized as
Organic Content: (gr/L) Not Applicable
hazardous by professionals in the field of
WHMIS Classification(s): D - 2B
Occupational Health and by most regulatory
This product has been classified in accordance with
agencies. This product contains compounds subject
the hazard criteria of the Controlled Products
to exposure guidelines and/or identified as Regulations (CPR). This MSDS contains all the
carcinogens. However, due to the physical nature of information required by the CPR.
this product, these compounds are unlikely to reach
exposure limits.
Engineering Controls: General ventilation may be
desirable and should be used where appropriate.
Trade Name: NVS?Concrete Aggregate & ZIC
Page Four
State Regulatory Information:
California Proposition 65: WARNING! This product
contains substances known to the state of California
to cause cancer, birth defects, or other reproductive
harm.
New Jersey Hazardous List (Identification threshold
(0.1%): None
Pennsylvania Hazardous Substance List
(Identification threshold 0.01%): None
Massachusetts Hazardous Substance List
(identification threshold 0.001% (1 ppm):
Chemical Name Cas # Wt %
Quartz 014808-60-7 1
Chemical Inventory Status:
All chemicals in this product are listed or exempt from
listing in the following countries:
US CANADA
TSCA DSL NDSL
Yes Yes Yes
The data included herein are presented according to Siplast's practices current at the time of preparation hereof, are made available solely for
the consideration, investigation and verification of the original recipients hereof and do not constitute a representation or warranty for which
Siplast assumes legal responsibility. It is the responsibility of a recipient of this data to remain currently informed on chemical hazard
information, to design and update its own program and to comply with all national, federal, state, and local laws and regulations applicable to
safety, occupational health, right-to-know and environmental protection.
Rev 10/07
HMIS
H =1
MATERIAL SAFETY DATA SHEET F =3
R=0
PPE = See Section 8
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Expanded Polystyrene Products
Insulperm?Insulation Board
Trade Name:
Chemical Names
and Family: Expanded Polystyrene Board and Custom Molded Polystyrene Inserts
Product Use: Insulation Board
Formula: (C8H8)n
CAS # (Chemical
Abstract Service): 09003-53-6
Transportation Hazard Classification
United States DOT
Proper Shipping Name: Nonhazardous
Hazard Class: Nonhazardous
Identification #: Nonhazardous
Label(s) Required: Nonhazardous
Surface Freight Classification: Plastic articles, blocks or panels
Section II - Ingredients
EXPOSURE LIMITS
INGREDIENT OSHA PEL ACGIH TLV NIOSH REL
Pentane, residual 600 ppm-TWA 600 ppm-TWA 120 ppm for 10 hr-TWA
CAS # 00109-66-0 750 ppm-STEL 750 ppm-STEL
5000 ppm-IDLH
INGREDIENT: % TOXICITY DATA: LD50 & LC50
(Chemical Name, CAS #, & Common Name) BY WT.
筆entane, residual 0-3.0% No data available
(CAS # 109-66-0)
笴ontained as a blowing agent.
Section III - Physical Data
Bulk Density (lb./cu. ft): Approx. 1.0
Appearance and Odor: White to yellow lightweight
Boiling Point: Not applicable
board and molded parts with characteristic odor.
Evaporation Rate (Butyl Acetate = 1): Not applicable
Odor Threshold: Approx. 400 ppm (for pentane)
% Volatile by Volume: 0-3.0% as pentane
pH: Not applicable
Vapor Pressure (mm Hg.): 445 mmHg @ 70癋 (for
Specific Gravity (H2O=1): Not applicable
pentane)
Vapor Density (AIR =1): >1 for pentane
Solubility in Water: Negligible
Trade Name: Insulperm?Insulation Board
Page Two
Section VI - Reactivity Data
Section IV - Fire and Explosion Data
Stability: Stable X Unstable ______
Flash Point: 49癈 (for pentane)
Conditions to Avoid: Excessive heat, sparks and
Method Used: (C.C.)
flame.
Flammable Limits: LEL: 1.5% UEL: 7.8%
Hazardous Decomposition or Byproducts: Carbon
N.F.P.A. Rating: H-1, F-4, R-0 (for pentane)
dioxide, carbon monoxide.
Extinguishing Media: In case of fire, use dry
Hazardous Polymerization: May occur Will not
chemical, carbon dioxide, or alcohol foam. When
occur X
heated near melting point, EPS will drip and burn.
Conditions to Avoid: None known
Water may spread liquid and be ineffective.
Special Procedures: Because EPS produces
Section VII - Spill & Disposal Information -
copious amounts of thick black smoke when it burns,
U.S. Only
a NIOSH-approved positive-pressure self-contained
breathing apparatus should be worn.
Unusual Hazards: Until much of the residual pentane Observe all precautionary measures (Section 8).
dissipates, fresh EPS may be able to supply enough Pick up or shovel into dry containers and recycle or
vapor to form a flammable mixture with air. The remove for disposal.
mixture is explosive only when confined. If
unconfined suddenly, and ignited, its rate of flame of Waste of this product is not defined as hazardous
propagation is high, and the flame appears to move according to the US EPA (40 CFR 261.3). Consult
in a flash, but without explosion. state and local regulations to determine if their
hazardous waste definitions differ from the US EPA.
Dispose of waste in accordance with all applicable
Section V - Health Hazard Data
regulations.
Routes of Exposure:
Section VIII - Special Protection Information
Inhalation is not expected to be a
INHALATION:
problem in most situations. However, fresh
Warning Statements: CAUTION!
polystyrene contains residual pentane and if large
Styrene Foam CAS # 9003-53-6 is an organic cellular
amounts of EPS materials are stored in a confined,
plastic foam and therefore combustible.
unventilated area such as a semi-trailer truck,
Fresh EPS may contain residual pentane (CAS #
pentane may off-gas and create measurable airborne
109-61-0) which is extremely flammable. However,
concentrations. Effects of inhaling pentane include
pentane content dissipates upon aging.
dizziness, drowsiness, eye and nose irritation,
Inhalation of pentane which may build up in confined
dermatitis and loss of coordination.
spaces such as delivery trucks may cause dizziness,
SKIN AND EYES: Dust or scrap of product may irritate
drowsiness, and loss of coordination.
eyes if contact occurs. Repeated skin contact may
Direct contact with styrene foam products or dust
cause slight physical irritation.
may cause slight physical irritation to eyes and skin.
INGESTION: Not likely to occur in an industrial setting.
Precautionary Measures:
Not generally considered to be toxic if swallowed.
Do not expose to open flames, sparks or excessive
Carcinogenicity According to NTP, IARC and OSHA:
heat. Local building codes may require the use of a
IARC (Vol. 19, 251, 1979) reported polystyrene as a
thermal or fire barrier.
positive animal carcinogen based upon animal
Store fresh material in well-ventilated areas.
studies where subcutaneous implantation of
Gloves and glasses or goggles are recommended if
polystyrene discs, rods and spheres induced local
direct contact leading to physical irritation is likely.
sarcomas in rats. No human data or epidemiology
Respiratory Protection:
studies on the carcinogenicity of polystyrene in
Not generally required. In nonroutine situations
humans are known to IARC.
where pentane vapor build-up occurs, use of a
NIOSH-approved organic vapor respirator (Type
TC-23C-XXX) is recommended.
Trade Name: Insulperm?Insulation Board
Page Three
Ventilation: Section X - Government Reporting
Local Exhaust: No Information - U.S. Only
Mechanical: Yes
Special: Not applicable SARA Title III Reporting Information:
Tier I & II Hazard Categories: Fire
Other: Natural ventilation, i.e., winds, building cross-
Contains Extremely Hazardous - SARA III Section
currents, etc., should be sufficient to adequately
302 Ingredient: No
disperse residual pentane vapors released from fresh
Contains Toxic Chemical Release - SARA III Section
material.
313 Ingredient: No
Skin Protection: Gloves are recommended when
Other Government Reporting Requirements: Not
handling EPS products to minimize repeated skin
applicable.
contact.
Non-hazardous Ingredient Disclosure: Not
Eye Protection: Safety glasses are recommended
applicable.
when specific use of EPS products creates a
significant amount of dust and/or scrap.
Other Protective Clothing or Equipment: Not
applicable.
Work/Hygienic Practices:
Observe above precautions and practice good
housekeeping.
Section IX - Emergency and First Aid
Procedures
EYES: In case of eye contact, flush eyes with plenty
of running water, lifting eyelids frequently. If irritation
persists, consult a physician.
SKIN: If repeated skin contact results in persistent
irritation, consult a physician to clear up condition and
take precautionary measures to prevent its
reoccurrence.
INHALATION: If vapor is inhaled, get fresh air
immediately. Inform a supervisor. Consult a
physician if symptoms persist.
INGESTION: If swallowed, consult a physician. Never
give anything by mouth to an unconscious person.
The data included herein are presented according to Siplast's practices current at the time of preparation hereof, are made available solely for
the consideration, investigation and verification of the original recipients hereof and do not constitute a representation or warranty for which
Siplast assumes legal responsibility. It is the responsibility of a recipient of this data to remain currently informed on chemical hazard
information, to design and update its own program and to comply with all national, federal, state and local laws and regulations applicable to
safety, occupational health, right-to-know and environmental protection.
Rev 10/07
HMIS
H =1
MATERIAL SAFETY DATA SHEET F =0
R=0
PPE = See Section 8
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Lightweight Concrete Decks
Trade Name: Zono-PatchTM
Chemical Names
and Family: Calcium Aluminate, Gypsum, Expanded Perlite, & Expanded Vermiculite
Product Use: Preformulated Mixture for Lightweight Concrete Decks
Formula: Blend of Calcium Aluminate, Gypsum, & Expanded Mineral Aggregates
CAS # (Chemical
Abstract Service): Mixture-Not applicable
Transportation Hazard Classification
United States DOT
Proper Shipping Name: Not applicable
Hazard Class: Nonhazardous
Identification #: Not applicable
Label(s) Required: Not applicable
Surface Freight Classification: Vermiculite other than crude
Section II - Ingredients
EXPOSURE LIMITS
INGREDIENT OSHA ACGIH
PEL TLV
Calcium Aluminate mixture
Up to 57% by weight
5 mg/m3 10 mg/m3
Total dust exposure
Calcium Aluminate CAS #12042-68-1
Calcium Dialuminate CAS #12004-08-9
Tetracalcium Aluminoferrite CAS #12068-35-8
Dicalcium Aluminosilicate CAS #12068-46-1
Calcium Aluminosulfate CAS #12004-11-4
Gypsum (calcium sulfate) CAS #7778-18-9
Up to 26% by weight
5 mg/m3
Respirable dust
15 mg/m3 10 mg/m3
Total dust
Perlite Volcanic Glass CAS #73763-70-3
10 mg/m3
Total dust N/A
Vermiculite
Up to 10% by weight
Altered Mica Material CAS #1318-00-9 N/A N/A
Aluminum Magnesium Sulfate N/A N/A
Trade Name: Zono-PatchTM
Page Two
EXPOSURE LIMITS
INGREDIENT OSHA ACGIH
PEL TLV
Crystalline silica
CAS #14808-60-7
0.1 mg/m3 0.1 mg/m3
Respirable dust
Trace Elements
Due to the use of substances mined from the earth's crust, trace amounts of naturally occurring, potentially harmful
constituents may be detected during chemical analysis. Calcium aluminate cement may contain up to 0.75%
insoluble residue. A small amount of this residue includes free crystalline and heavy metals.
Section III - Physical Data Potential Health Effects
Relevant Routes of Exposure:
Eye contact, skin contact, inhalation, and ingestion.
Boiling Point: Not applicable
EYE CONTACT: Exposure to airborne dust may cause
Evaporation Rate (Butyl Acetate = 1): Not applicable
immediate or delayed irritation or inflammation. Eye
% Volatile by Volume: Not applicable
contact by larger amounts of dry powder or splashes
Vapor Pressure (mm Hg.): Not applicable
of wet product slurry may cause effects ranging from
Vapor Density (AIR =1): Not applicable
moderate eye irritation to chemical burns and
Solubility in Water: Negligible
blindness. Such exposures require immediate first
Bulk Density (lb./cu. ft): 8-12
aid and medical attention to prevent significant
Appearance and Odor: Gray free flowing aggregate.
damage to the eye.
Earthy odor.
SKIN CONTACT: Discomfort or pain cannot be relied
Odor Threshold: None established
upon to alert a person to a hazardous skin exposure.
pH: In water 10-11
Consequently, the only effective means of avoiding
Specific Gravity (H2O=1): 3.15
skin injury or illness involves minimizing skin contact,
particularly contact with wet product slurry. Exposed
Section IV - Fire and Explosion Data
persons may not feel discomfort until hours after the
exposure has ended and significant injury has
Flash Point: None
occurred.
Method Used: Not applicable
Exposure to dry product may cause drying of the skin
Flammable Limits: LEL: Not applicable
with consequent mild irritation or more significant
UEL: Not applicable
effects attributable to aggravation of other conditions.
N.F.P.A. Rating: Not applicable
Dry product contacting wet skin or exposure to moist
Extinguishing Media: Not applicable
product or wet slurry may cause more severe skin
Special Procedures: None
effects including thickening, cracking or fissuring of
Unusual Hazards: None known
the skin. Prolonged exposure can cause severe skin
damage in the form of (caustic) chemical burns.
Section V - Health Hazard Data
Some individuals may exhibit an allergic response
upon exposure to this product, possibly due to trace
Emergency Overview
amounts of chromium. The response may appear in
This product is a light gray powder that poses little
a variety of forms ranging from mild rash to severe
immediate hazard. A single short-term exposure to
skin ulcers. Persons already sensitized may react to
the dry powder is not likely to cause serious harm.
their first contact with the product. Other persons
However, exposure of sufficient duration to the
may first experience this effect after years of contact
material mixed with water can cause serious,
with this product.
potentially irreversible tissue (skin or eye) destruction
in the form of chemical (caustic) burns, including third
degree burns. The same type of tissue destruction
can occur if wet or moist areas of the body are
exposed for sufficient duration to the dry product.
Trade Name: Zono-PatchTM
Page Three
This product may contain trace amounts Discard empty packaging promptly. Avoid excessive
INHALATION:
of free crystalline silica. Prolonged exposure to handling of empty packaging, which may result in
respirable free crystalline silica may aggravate other unnecessary release of airborne particulates.
lung conditions. It also may cause delayed lung
Do not wash Zono-Patch down drains.
injury including silicosis, a disabling and potentially
fatal lung disease, and/or other diseases. (Also,
Allow materials to "dry" before disposal.
"Carcinogenic potential" below.)
Exposure to this product may cause irritation to the
moist membranes of the nose, throat, and upper
Section VIII - Special Protection Information
respiratory system. It may also leave unpleasant
deposits in the nose.
INGESTION: Although small quantities of dust are not Warning Statements:
known to be harmful, ill effects are possible if larger CAUTION! MAY CAUSE SLIGHT IRRITATION.
quantities are consumed. This product should not be
eaten. This product will harden on contact with Product contains vermiculite (CAS # 1318-00-9) and
water. See physician immediately if symptoms occur. quartz (crystalline silica (CAS # 14808-60-7).
This product is not listed as a carcinogen by NTP, Eye contact may cause minor physical irritation.
OSHA, or IARC. It may, however, contain trace Inhalation of dust may cause upper respiratory
amounts of substances listed as carcinogens by irritation with coughing and sneezing.
these organizations. Long-term exposure to airborne respirable quartz
Crystalline silica, a potential trace level contaminant (crystalline silica) dust can decrease lung function
in this product, is not listed as a carcinogen by the and create risk of silicosis, pneumoconiosis, lung
Occupational Safety and Health Administration cancer and other lung disease.
(OSHA). IARC has designated crystalline silica as Precautionary Measures:
carcinogenic to humans (Group 1). The NTP Avoid contact with eyes.
indicates that crystalline silica is reasonably Avoid creating and inhaling dust.
anticipated to be a carcinogen (Group 2). Provide adequate ventilation and respiratory
Medical conditions which may be aggravated by protection.
inhalation or dermal exposure: Equip mixers with dust covers.
Pre-existing upper respiratory and lung diseases. Respiratory Protection:
Wear a NIOSH approved (Type TC-21C-XXX) dust
Section VI - Reactivity Data respirator to prevent exposures above the limits
specified in Section II.
Ventilation: Use in well-ventilated area.
Stability: Stable X Unstable ______
Local Exhaust: Not generally required, but should be
Conditions to Avoid: Unintentional contact with
used where available.
water.
Mechanical: Not generally required, but should be
Hazardous Decomposition or Byproducts: See
used where available.
Section 10
Special: None
Hazardous Polymerization: May occur Will not
Other: None
occur X
Skin Protection: Gloves recommended.
Eye Protection: Goggles recommended where
Section VII - Spill & Disposal Information - exposure to excessive dust is likely.
Other Protective Clothing or Equipment: Normal work
U.S. Only
clothes.
Work/Hygienic Practices:
Observing the above precautions, sweep up or
Use bag opening and disposal which minimizes dust
shovel spilled material and place in suitable
release. Equip mixers with dust covers.
containers for recycle or disposal. Dampen with
water spray or use other methods to clean spill which
avoid creating dust.
Trade Name: Zono-PatchTM
Page Four
Section IX - Emergency and First Aid 40 CRF 117
STATUS UNDER CERCLA/SUPERFUND, AND
302 ?Not listed.
Procedures
(TITLE III), SECTION 311
HAZARD CATEGORY UNDER SARA
312 ?Calcium aluminate cement qualifies as
AND
EYES: In case of eye contact, do not rub eyes. Flush
"hazardous substance" with delayed health effects.
eyes with plenty of water while holding eyelids apart.
STATUS UNDER SARA (TITLE III), SECTION 313
If irritation, blinking or tearing occur and persist,
Not subject to reporting requirements under Section
consult a physician.
313.
SWALLOWED: Although small quantities of dust are not
STATUS UNDER TSCA (AS OF MAY 1997)
known to be harmful, ill effects are possible if larger
Calcium aluminate cement is on the TSCA inventory
quantities are consumed. This product should not be
list.
eaten. This product will harden on contact with
STATUS UNDER THE FEDERAL HAZARDOUS SUBSTANCES
water. See physician immediately if symptoms occur.
ACT ?Calcium aluminate cement is a "hazardous
INHALATION: If inhaled, get fresh air. If symptoms
substance" subject to statues promulgated under the
persist, consult a physician.
subject act.
STATUS UNDER CALIFORNIA PROPOSITION 65
Section X - Government Reporting
This product contains chemicals (trace metals)
Information - U.S. Only
known to the State of California to cause cancer, birth
defects or other reproductive harm. California law
SARA Title III Reporting Information:
requires the manufacturer to give the above warning
Tier I & II Hazard Categories: Delayed - chronic,
in the absence of definitive testing to prove that the
Immediate - acute
defined risks do not exist.
Contains Extremely Hazardous - SARA III Section
STATUS UNDER CANADIAN ENVIRONMENTAL PROTECTION
302 Ingredient: No
ACT ? Not listed.
Contains Toxic Chemical Release - SARA III Section
STATUS WHMIS
313 Ingredient: No
Calcium aluminate cement is considered to be a
California Proposition 65: Product sold in the state of
hazardous material under the Hazardous Products
California is labeled to comply with Proposition 65.
Act as defined by the Controlled Products
Non-hazardous Ingredient Disclosure: Water
Regulations (Class D2A.E ?Corrosive Material) and
STATUS UNDER USDOL-OSHA HAZARD COMMUNICATION
is therefore subject to the labeling and MSDS
RULE, 29 CFR 1910.1200
requirements of the Workplace Hazardous Materials
Calcium aluminate cement is considered a
Information System (WHMIS).
"hazardous chemical" under this regulation, and
should be part of any hazard communication
program.
The data included herein are presented according to Siplast's practices current at the time of preparation hereof, are made available solely for
the consideration, investigation and verification of the original recipients hereof and do not constitute a representation or warranty for which
Siplast assumes legal responsibility. It is the responsibility of a recipient of this data to remain currently informed on chemical hazard
information, to design and update its own program and to comply with all national, federal, state and local laws and regulations applicable to
safety, occupational health, right-to-know and environmental protection.
Rev 10/07
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