Material Safety Data Sheet
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PHOS-CHEK?WD881 FIRE SUPPRESSANT FOAM CONCENTRATE
Reference Number: AST10045
Date: March 15, 2004
Company/Undertaking Identification:
Worldwide Hqts Europe Hqts
ASTARIS LLC ASTARIS S.r.l.
622 Emerson Road - Suite 500 Via Brescia 26
St. Louis, Missouri 63141 20063 Cernusco Sul Naviglio MI
Milan, Italy
Emergency telephone
In Europe call +39 (0)3 568 5123
In USA call CHEMTREC: 1 800 424 9300
In Canada call CANUTEC: 1 613 996 6666
Outside North America call CHEMTREC: 1 703 527 3887
General Information: + 39 (0)3 568 5123 (Europe)
1 800 244 6169 (Worldwide)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS No. % by weight
Alpha-olefin Sulfonate Solution ---- 60 - 100
2,4-pentanediol, 2-methyl- 107-41-5 10 - 30
1-dodecanol 112-53-8 1-5
d-limonene 5989-27-5 1-5
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Appearance and Odor: Golden brown liquid with an odor similar to orange blossoms
WARNING STATEMENTS
WARNING!
CAUSES EYE IRRITATION
MAY CAUSE SKIN & RESPIRATORY TRACT IRRITATION
POTENTIAL HEALTH EFFECTS
Likely Routes of Exposure: Skin contact and inhalation
EYE CONTACT: This product causes severe eye irritation based on toxicity studies.
SKIN CONTACT: This product may cause skin irritation based on toxicity studies.
INHALATION: This product may cause irritation to the nose and upper respiratory system based
on component supplier information.
Astaris Material Safety Data Sheet
Material: Material: Phos-Chek?WD-881 Fire Suppressant Foam Concentrate Page 2 of 5
Reference No.: AST10045 March 15, 2004
INGESTION: This product is no more than slightly toxic. Significant adverse health effects are
not expected to develop if only small amounts (less than a mouthful) are
swallowed.
Refer to Section 11 for toxicological information.
4. FIRST AID MEASURES
IF IN EYES, immediately flush with plenty of water for at least 15 minutes. If easy to do, remove
any contact lenses. Get medical attention. Remove material from skin, eyes and clothing.
IF ON SKIN, immediately flush with plenty of water. Remove contaminated clothing. Get medical
attention if irritation persists. Wash clothing before reuse.
IF INHALED, remove to fresh air. Immediate first aid is not likely to be required, if breathing. If
breathing is difficult give oxygen. If not breathing, give artificial respiration. Get medical attention.
IF SWALLOWED, immediate first aid is not likely to be required. A physician or Poison Control
Center can be contacted for advice.
5. FIRE FIGHTING MEASURES
FLASH POINT: Not combustible
EXTINGUISHING MEDIA: Not applicable
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known
SPECIAL FIRE FIGHTING PROCEDURES IN ENCLOSED AREAS:
Phos-Chek?WD-881 Solutions: There are no special hazards associated with dilute foam
solutions as used for fire fighting.
Phos-Chek?WD-881 Concentrate: If the concentrate becomes involved in a fire, fire fighters and
others exposed to products of combustion should wear self-contained breathing apparatus and
protective clothing. Equipment should be thoroughly cleaned after use.
6. ACCIDENTAL RELEASE MEASURES
Contain large spills with dikes and transfer the material to appropriate containers for reclamation
or disposal. Absorb remaining material or small spills with an inert material and then place in a
chemical waste container. Flush residual spill area with water.
Refer to Section 13 for disposal information and Sections 14 and 15 for reportable quantity
information.
7. HANDLING AND STORAGE
HANDLING
Avoid contact with eyes, skin and clothing.
Avoid breathing vapor or mist.
Keep container closed.
Use with adequate ventilation.
Wash thoroughly after handling.
STORAGE: Emptied container retains vapor and product residue. Observe all labeled safeguards
until container is cleaned, reconditioned or destroyed. The reuse of this material's container for
non-industrial purposes is prohibited and any reuse must be in consideration of the data provided
in the MSDS.
Astaris Material Safety Data Sheet
Material: Material: Phos-Chek?WD-881 Fire Suppressant Foam Concentrate Page 3 of 5
Reference No.: AST10045 March 15, 2004
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION: Where there is significant potential for eye contact, wear chemical goggles
and have eye flushing equipment available.
SKIN PROTECTION: Wear appropriate protective clothing and chemical resistant gloves to
prevent skin contact. Consult glove manufacturer to determine appropriate type glove for given
application. Wear face shield and chemical resistant clothing such as a rubber apron when
splashing is likely. Wash contaminated skin promptly. Launder contaminated clothing and clean
protective equipment before reuse. Wash thoroughly after handling.
RESPIRATORY PROTECTION: Avoid breathing vapor or mist. Use NIOSH/MSHA approved
respiratory protection equipment (full facepiece recommended) when airborne exposure limits are
exceeded (see below). Consult respirator manufacturer to determine appropriate type equipment
for given application. Observe respirator use limitations specified by NIOSH/MSHA or the
manufacturer. Respiratory protection programs must comply with 29 CFR 1910.134.
VENTILATION: Provide natural or mechanical ventilation to control exposure levels below airborne
exposure limits (see below). If practical, use local mechanical exhaust ventilation at sources of air
contamination such as open process equipment. Consult NFPA Standard 91 for design of exhaust
systems.
AIRBORNE EXPOSURE LIMITS:
Product/Component OSHA PEL ACGIH TLV
Phos-Chek WD881 None established None established
2,4-pentanediol, 2-methyl- 25 ppm ceiling 25 ppm ceiling
Components referred to herein may be regulated by specific Canadian provincial legislation.
Please refer to exposure limits legislated for the province in which the substance will be used.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Golden brown liquid
Odor: Similar to orange blossoms
Solubility in Water: Forms foam
NOTE: These physical data are typical values based on material tested but may vary from
sample to sample. Typical values should not be construed as a guaranteed analysis of any
specific lot or as specifications for the product.
10. STABILITY AND REACTIVITY
STABILITY: Product is stable under normal conditions of storage and handling.
MATERIALS TO AVOID: None known
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, partially oxidized
hydrocarbons, smoke and soot.
HAZARDOUS POLYMERIZATION: Will not occur
11. TOXICOLOGICAL INFORMATION
Data from Astaris single-dose (acute) animal studies with this material are given below:
Phos-Chek WD881 Fire Suppressant Foam Concentrate
Oral - Practically Nontoxic (Rat LD50, Greater than 5,000 mg/kg)
Skin - No More Than Slightly Toxic (Rabbit LD50, Greater than 2,000 mg/kg)
Astaris Material Safety Data Sheet
Material: Material: Phos-Chek?WD-881 Fire Suppressant Foam Concentrate Page 4 of 5
Reference No.: AST10045 March 15, 2004
Eye Irritation - Severely Irritating (Rabbit 24-hr 58.0/110.0)
Skin Irritation - Moderately Irritating (Rabbit 24-hr 4.8/8.0)
Phos-Chek WD881 Fire Suppressant Foam Solution (1% solution in water)
Oral - Practically Nontoxic (Rat LD50, Greater than 5,000 mg/kg)
Skin - No More Than Slightly Toxic (Rabbit LD50, Greater than 2,000 mg/kg)
Eye Irritation - Practically Non-irritating (Rabbit 24-hr 2.0/110.0)
Skin Irritation - Moderately Irritating (Rabbit 4-hr 0.3/8.0)
COMPONENTS
Data from Astaris studies and/or the available scientific literature on the components of this
material which have been identified as hazardous chemicals under the criteria of the OSHA
Hazard Communication Standard (29 CFR 1910.1200) are discussed below:
2,4-pentanediol, 2-methyl-
2,4-pentanediol, 2-methyl- is an eye irritant; contact with liquid or mists may cause damage to the
eyes which are reported to heal slowly. If ingested and absorbed, central nervous system (CNS)
depression may occur as evidenced by giddiness, headache, and dizziness progressing to
unconsciousness and death. Organ weight changes and effects on liver and kidney tissues have
been reported in rodents in repeat dosing studies. No effects were seen on fertility of male rats
following repeat oral dosing.
12. ECOLOGICAL INFORMATION
The following data have been classified using the criteria adopted by the European Economic
Community (EEC) for aquatic organism toxicity.
96-hr LC50 Rainbow Trout, 22 mg/l Harmful
Data from a similar product:
48-hr LC50 Daphnia Magna, 7.8 mg/l Toxic
96-hr EC50 selenastrum capricornutum (algae), 7.6 mg/l Toxic
13. DISPOSAL CONSIDERATIONS
This material when discarded is not a hazardous waste as that term is defined by the Resource,
Conservation and Recovery Act (RCRA), 40 CFR 261. Dispose of by incineration or recycle in
accordance with local, state and federal regulations. Consult your attorney or appropriate
regulatory officials for information on such disposal.
14. TRANSPORT INFORMATION
The data provided in this section is for information only. Please apply the appropriate regulations
to properly classify your shipment for transportation.
IMDG/UN not hazardous for transportation
ICAO/IATA not hazardous for transportation
RID/ADR not hazardous for transportation
Canadian TDG not hazardous for transportation
US DOT not hazardous for transportation
15. REGULATORY INFORMATION
TSCA Inventory: Listed
DSL Inventory: Listed
WHMIS Classification: D2(B) - Materials Causing Other Toxic Effects
SARA Hazard Notification
Hazard Categories Under Title III Rules (40 CFR 370): Immediate
Astaris Material Safety Data Sheet
Material: Material: Phos-Chek?WD-881 Fire Suppressant Foam Concentrate Page 5 of 5
Reference No.: AST10045 March 15, 2004
Section 302 Extremely Hazardous Substances: Not Applicable
Section 313 Toxic Chemical(s): Not Applicable
CERCLA Reportable Quantity: Not applicable
California Proposition 65: Not applicable
This product has been classified in accordance with the hazard criteria of the Canadian
Controlled Products Regulation and the MSDS contains all the information required by the
Canadian Controlled Products Regulation.
Refer to Section 11 for OSHA/HPA Hazardous Chemical(s) and Section 13 for RCRA
classification.
16. OTHER INFORMATION
Health Fire Reactivity Additional Information
Suggested NFPA Rating 2 0 0
Suggested HMIS Rating 2 0 0 G
G = Safety glasses, gloves,
dust & vapor respirator
Reason for revision: Updated transport information. Supersedes MSDS dated: January 8, 2003
Product Use: Fire Suppressant
PHOS-CHEK?is a registered trademark of Astaris LLC.
Astaris?is a trademark of Astaris LLC
Although the information and recommendations set forth herein (hereinafter "Information") are
presented in good faith and believed to be correct as of the date hereof, Astaris LLC makes no
representations as to the completeness or accuracy thereof. Information is supplied upon the
condition that the persons receiving same will make their own determination as to its suitability for
their purposes prior to use. In no event will Astaris LLC be responsible for damages of any
nature whatsoever resulting from the use of or reliance upon information. NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER
NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT
TO WHICH INFORMATION REFERS
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