HENKEL LOCTITE CORPORATION Date of Preparation: 01/16/01
MATERIAL SAFETY DATA SHEET Page 01 of 05
|-------------------------------------------------------|
| MATERIAL SAFETY DATA SHEET |
|-------------------------------------------------------|
|=========================================================================|
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
|=========================================================================|
PRODUCT NAME : FIXMASTER FLEX RUBBER PRIMER
IDENTIFICATION NUMBER: 98468
PRODUCT USE/CLASS : Primer
MANUFACTURER:
Loctite Corporation
1001 Trout Brook Crossing
Rocky Hill, Connecticut 06067
EMERGENCY TELEPHONE: 860-571-5100 24 hrs
PREPARER: Safety Health & Regulatory Affairs PREPARE DATE: 10/15/98
|=========================================================================|
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
|=========================================================================|
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT %
---------------------------------------------------------------------------
01 Methyl ethyl ketone 78-93-3 40-70 %
02 Toluene 108-88-3 20-40 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA U. K.
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-STEL TLV-TWA SKIN
---------------------------------------------------------------------------
01 200 ppm 300 ppm 200 ppm 300 ppm 200 ppm NO
02 100 ppm 150 ppm 100 ppm 150 ppm 100 ppm NO
(See Section 16 for abbreviation legend)
|=========================================================================|
| SECTION 3 - HAZARDS IDENTIFICATION |
|=========================================================================|
*** EMERGENCY OVERVIEW ***: Harmful if inhaled. Harmful if swallowed.
Contains substances which are thought to cause organ damage based upon
animal tests. Refer to health effects section. Can cause eye burns. Can
cause skin irritation. Inhalation of vapors may cause respiratory
irritation and intoxication. Flammable liquid and vapor.
ACUTE EFFECTS - EYE CONTACT: Severe irritant. Prolonged contact may cause
permanent corneal injury.
ACUTE EFFECTS - SKIN CONTACT: Mild irritant. Prolonged contact may cause
defatting and redness.
ACUTE EFFECTS - INHALATION: Inhalation of vapors may cause respiratory
irritation or intoxication, with headache, dizziness, and nausea. Liquid
aspirated into lungs may cause severe injury or death.
ACUTE EFFECTS - INGESTION: May cause irritation of mouth, throat and
stomach, with nausea and vomiting.
CHRONIC OVEREXPOSURE EFFECTS -: *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components. Studies
suggest that solvent chronic overexposure effects are targeted at the liver
and central nervous system. Deliberate and repeated inhalation of
concentrated solvent vapors may cause permanent neural injury.
HENKEL LOCTITE CORPORATION Date of Preparation: 01/16/01
MATERIAL SAFETY DATA SHEET Page 02 of 05
Item No.: 98468
Embryotoxic/fetotoxic effects have been observed in laboratory rats exposed
to methyl ethyl ketone by inhalation at levels greater than 1000 ppm for
most of the gestation period. Methyl ethyl ketone may shorten the time of
onset of peripheral polyneuropathy caused by methyl n-butyl ketone or
n-hexane. Methyl ethyl ketone by itself has not been shown to cause
peripheral polyneuropathy. Animal Studies suggest that repeated or
prolonged overexposure may cause injury to the kidneys, liver, or central
nervous system.
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT SKIN CONTACT INHALATION
===========================================================================
|=========================================================================|
| SECTION 4 - FIRST AID MEASURES |
|=========================================================================|
FIRST AID - EYE CONTACT: Immediately flush eyes with clean water at least
15 minutes. Obtain IMMEDIATE medical attention.
FIRST AID - SKIN CONTACT: Remove contamination and flush with water.
Follow with thorough soap and water wash. Remove and wash contaminated
clothing. Seek medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If breathing is difficult,
give oxygen. Administer artificial respiration if not breathing. Obtain
medical attention
FIRST AID - INGESTION: If swallowed, DO NOT induce vomiting. Give water
or milk if victim is conscious and not drowsy. Obtain immediate medical
attention.
|=========================================================================|
| SECTION 5 - FIRE FIGHTING MEASURES |
|=========================================================================|
FLASH POINT: 22 F LOWER EXPLOSIVE LIMIT: 1.3 %
(TAGLIABUE CLOSED CUP) UPPER EXPLOSIVE LIMIT: 11.5 %
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA: ALCOHOL FOAM FOAM DRY CHEMICAL CO2
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture or
explode (due to pressure build-up) when exposed to extreme heat. Vapors
are heavier than air, and may travel along the ground to be reignited at
locations distant from the source; flashback of flame may occur. "Empty"
containers may retain dangerous product residues or explosive vapors. DO
NOT pressurize, cut, weld, braze, solder, drill or grind on or near empty
containers. Store full and empty containers away from heat, sparks, flame,
and other sources of ignition. Observe all labeled precautions until
containers are cleaned and/or reconditioned. Irritating and/or toxic gases
or fumes may be generated by thermal decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained
breathing apparatus and full protective clothing. Use water to cool
exposed containers. Water stream directed into fire may cause frothing
with subsequent spread of flame.
HENKEL LOCTITE CORPORATION Date of Preparation: 01/16/01
MATERIAL SAFETY DATA SHEET Page 03 of 05
Item No.: 98468
|=========================================================================|
| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
|=========================================================================|
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove sources
of ignition. Wear appropriate protective equipment during cleanup. Absorb
with inert material, such as clay. Sweep or shovel into loosely-covered
waste container and remove to appropriate waste area. Dispose of in
accordance with federal, state, and local regulations. Wash spill area
with soap and water.
|=========================================================================|
| SECTION 7 - HANDLING AND STORAGE |
|=========================================================================|
HANDLING: Avoid contact with skin and eyes. Avoid inhaling vapors. DO
NOT take internally. FOR INDUSTRIAL USE ONLY
STORAGE: Store full and empty containers away from heat, sparks, open
flames, and sources of ignition. Keep containers closed when not in use.
KEEP OUT OF THE REACH OF CHILDREN Use proper grounding procedures.
|=========================================================================|
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
|=========================================================================|
ENGINEERING CONTROLS: Local exhaust as needed to control vapor or dust
levels to below lowest component TLV.
===========================================================================
|=========================================================================|
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
|=========================================================================|
RESPIRATORY PROTECTION: If TLV/PEL is exceeded, if use is performed in a
poorly-ventilated space, or if inhalation effects occur, use NIOSH-approved
vapor cartridge respirator in accordance with applicable health and safety
regulations and manufacturer's recommendations.
SKIN PROTECTION: Clean clothing to cover skin. Butyl rubber gloves.
Teflon gloves. Viton gloves. Supported PVA gloves.
EYE PROTECTION: Chemical splash goggles.
OTHER PROTECTIVE EQUIPMENT: No Information.
HYGIENIC PRACTICES: Follow general industrial safety practices during use.
Do not smoke or eat during use. Use only with adequate ventilation. DO
NOT reuse empty containers without commercial clean or recondition. Follow
all MSDS/label precautions even after container is emptied.
|=========================================================================|
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
|=========================================================================|
BOILING RANGE : 175 - 233 F VAPOR DENSITY : Is heavier than air
ODOR : Strong solvent ODOR THRESHOLD : Appr. 1 ppm
APPEARANCE : Clear EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Negligible Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 0.7800
VAPOR PRESSURE : No data pH @ 0.0 % : N/A
PHYSICAL STATE : Liquid VISCOSITY : Low
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
HENKEL LOCTITE CORPORATION Date of Preparation: 01/16/01
MATERIAL SAFETY DATA SHEET Page 04 of 05
Item No.: 98468
|=========================================================================|
| SECTION 10 - STABILITY AND REACTIVITY |
|=========================================================================|
CONDITIONS TO AVOID: Prolonged exposure to heat.
INCOMPATIBILITY: Strong bases or oxidants.
PRODUCTS OF DECOMPOSITION OR COMBUSTION -: Acrid fumes. Oxides of carbon.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|=========================================================================|
| SECTION 11 - TOXICOLOGICAL PROPERTIES |
|=========================================================================|
No product or component toxicological information is available.
|=========================================================================|
| SECTION 12 - ECOLOGICAL INFORMATION |
|=========================================================================|
ECOLOGICAL INFORMATION: No Information.
|=========================================================================|
| SECTION 13 - DISPOSAL CONSIDERATIONS |
|=========================================================================|
DISPOSAL METHOD: Review all current federal, state, and local regulations
regarding health and disposal for appropriate disposal procedures.
|=========================================================================|
| SECTION 14 - TRANSPORTATION INFORMATION |
|=========================================================================|
DOT PROPER SHIPPING NAME: Adhesive
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: 3 HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: UN1133 PACKING GROUP: II RESP. GUIDE PAGE: 26
IMDG INFORMATION: Adhesive, Class 3.2, UN1133, Pkg Grp II, Page 3174, EmS
3-05, MFAG 330
AIR/IATA INFORMATION: Adhesive, Class 3, UN1133, Pkg Grp II, Packing
===========================================================================
|=========================================================================|
| SECTION 15 - REGULATORY INFORMATION |
|=========================================================================|
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY: This product has been reviewed and is
considered, under applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER MAX. WT/WT % IS
Methyl ethyl ketone 78-93-3 65.0 %
Toluene 108-88-3 35.0 %
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
HENKEL LOCTITE CORPORATION Date of Preparation: 01/16/01
MATERIAL SAFETY DATA SHEET Page 05 of 05
Item No.: 98468
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Laminating adhesive UNKNOWN
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Laminating adhesive UNKNOWN
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the State of California to cause cancer, birth defects or other
reproductive harm: Toluene
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2B, B1
RCRA HAZARDOUS WASTE CLASS: Ignitable Toxic
RCRA HAZARDOUS WASTE CODES: D001 U159 D035 U220
CERCLA REPORTABLE QUANTITY (RQ): 100
|=========================================================================|
| OTHER INFORMATION |
|=========================================================================|
HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 07/08/93 REASON FOR REVISION: periodic updt
REISSUE: Y
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
LEGEND CONT: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Safety and Health Administration; UK =
United Kingdom; GER = Germany; TLV-TWA = Threshold Limit Value-Time
Weighted Average (8 hrs); STEL = Short-Term Exposure Limit (15 min); C =
Ceiling Value; PEL = Permissible Exposure Limit
|