March 2010 Page 1 of 5
Material Safety Data Sheet
SUPER ETCH PRIMER
HiChem Paint Technologies Pty.Ltd.
A.B.N. 95 064 139 653
73 Hallam South Road, HALLAM, VICTORIA 3803.
Telephone : {03} 9796 3400 Facsimile : {03} 9796 4500
Email:msdsinfo@hichem.com.au www:hichem.com.au
IDENTIFICATION of the SUBSTANCE(S) and COMPOSITION
SUPER ETCH PRIMER Code SEP
Product Name
Use as an adhesion primer applied by spray on metal surfaces.
Product Use
Ingredients Name CAS Number Proportion w/w
Methyl Ethyl Ketone 78 ?93 ?3 10 ?<30 %
Ethyl Alcohol 64 ?17 ?5 30 ?60 %
Coloured Pigments/Extenders (non環azardous) Mixture 1.0 ?<10 %
Polymeric Synthetic Resins (non-hazardous) Mixture 1.0 ?<10 %
Additives (non環azardous) Mixture 1.0 ?<10 %
HAZARD IDENTIFICATION
The product is classified both as Dangerous Goods and Hazardous Substance in accordance to ASCC
Risk Phrases R
11 Highly Flammable Liquid
20/21/22 Harmful by inhalation, in contact with the skin and if swallowed.
36/37/38 Irritating to the eyes, respiratory tract and skin.
51/53 Toxic to aquatic organisms and may cause long term adverse effects in the aquatic
environment.
63 Causes foetotoxicity in animals at doses which are maternally toxic.
65/66/67 Harmful. May cause lung damage if swallowed. Repeated or prolonged exposure may
cause skin dryness and cracking. Vapours may cause headaches, drowsiness and dizziness.
Safety Phrases S
2 Keep out of reach of children.
7/9 Keep containers tightly closed when not in use and also in a well ventilated area.
15 Keep away from heat.
16/33 Keep away from sources of ignition. Take precautionary measures against static electricity.
20/21 When using, do not eat, drink or smoke.
23.5 Do not breathe vapours or spray mists
24/25 Avoid skin contact and with the eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
27 Take off immediately all contaminated clothing.
28.1 In contact with the skin, wash immediately soap and plenty of water.
36/37/38/39 The wearing of an Organic Vapour ?Particulate Respirator, Safety Glasses fitted with
side ?shields, Viton or PVC gloves, enclosed footwear, high temperature and anti ?static
clothing and hearing protection.
45 In case of accident, or if you feel unwell, seek medical advice immediately. Show the label
where possible.
62 If swallowed, do not induce vomiting: seek medical advice immediately. Show the label
where possible.
PAINT, immiscible in water, UN 1263, Class 3, HAZCHEM 3[YE, Packing
ADG Classification
Group II.
Classified as a Schedule S 5 poison.
SUSDP
March 2010 Page 2 of 5
Material Safety Data Sheet
SUPER ETCH PRIMER
FIRST AID MEASURES
If the applicator feels drowsy, dizzy, tired or experiencing
Inhalation
headaches, remove the victim to the fresh air. Keep the victim
warm and quiet until all symptoms subside.
If swallow, and only if the person is conscious, give clean
Ingestion
water to drink. If any symptoms occur, DO NOT induce
vomiting; seek URGENT medical attention if frothing from the
mouth occurs.
If splashed into eyes, hold eyes open, irrigate copiously with
Eyes
clean water for at least 15 minutes. Seek immediate medical
attention if any irritation occurs.
If skin contact occurs, remove contaminated clothing, and wash
Skin
thoroughly with soap and plenty of water. Seek medical
attention if any irritation occurs.
Clean Water Supply, soap or skin cleaner, barrier cream,
First Aid
emergency showers and eye wash stations.
Facilities
If poisoning occurs, consult with the Poisons Information
Advice to Doctor
Centre {Telephone 13 11 26}. Have a copy of this material
safety data sheet or label available. Treat symptomatically as
systems may be delayed for several hours after exposure.
FIRE FIGHTING MEASURES
Carbon Dioxide {CO2}, alcohol resistant foam, dry chemical
Extinguishing
or water spray. DO NOT use water jets. Bund area with sand
Media and
to prevent run ?off entering waterways and drains.
Requirements
Fire ?fighters must wear Chemical Splash Suit with attached
Fire Fighting
Self ?Contained Breathing Apparatus and gloves. Evacuate all
Procedures &
non fire璮ighting personnel away from the area. Turn off all
Precautions
electricity and power supplies. Keep containers cool with
water spray or water to prevent rupture or burning. Move away
all containers and equipment from the direction of the fire, if
safe to do so. Keep upwind.
Highly Flammable Liquid. Flash Point = - 4 o C
Flammability
On heating, containers may rupture and explode: contents may
Hazardous
burn rapidly forming toxic gases including carbon monoxide.
Decomposition
Products
ACCIDENTAL RELEASE MEASURES
Contain all spills and leaks. Avoid contamination with spilt
Spills and Leaks
material on surfaces. Remove all sources of ignition and NO
SMOKING. Wear the recommended full body impervious
clothing, gloves and breathing apparatus as per AS?NZ
1715/16. Keep upwind. Absorb all spilt contents onto sand or
earth.
Collect all residues into labelled and sealed containers for
Disposal
disposal via special waste collection services as per local
Statutory Authority requirements.
Avoid contaminating waterways, drains, water courses and
Other
sewage.
Precautions
March 2010 Page 3 of 5
Material Safety Data Sheet
SUPER ETCH PRIMER
HANDLING and STORAGE
Keep out of reach of children. Avoid unnecessary contact with the material. After use
Handling
before eating, drinking or smoking wash all exposed skin with soap and water.
Containers must be clearly labelled, rigid and strong. Store upright in a cool, dry,
Storage
well ventilated area from heat, ignition sources and direct sunlight e.g. Flammable
Goods Store as per AS 1940 requirements.
EXPOSURE CONTROLS
Ethyl Alcohol = 960 mg/m3. Methyl Ethyl Ketone = 600 mg/m3.
Exposure
Standards
No data available.
Exposure
Standards STEL
The use of local exhaust ventilation equipment is required. All ventilation equipment
Engineering
must be fitted with flame and explosion proof electrical fittings.
Controls
PERSONAL PROTECTION
The wearing of an Organic Vapour ?Particulate Respirator
Inhalation
must be worn during the application period.
AS 璑ZS
1715/16
The wearing of safety glasses fitted with side shields must
Eye
be worn at all times during the application period. Do not
AS 璑ZS 1337
wear contact lenses.
The wearing of Viton or PVC elbow length gloves must be
Gloves
worn at all times during the application period..
AS 璑ZS 2161
The wearing of enclosed footwear must be worn during
Footwear
the application period.
AS 璑ZS 2210
The wearing of anti璼tatic clothing made on natural or
Clothing
synthetic high temperature fibre must be worn during the
AS 璑ZS 2919
application period.
When applied by conventional spray, the wearing of
Hearing
hearing protection during the spray application period
AS 璑ZS 1270
must be worn.
Avoid contact with eyes and skin. Avoid inhaling vapours
Other
and spray mistsat all times.
Requirements
PHYSICAL ?CHEMICAL PROPERTIES
A coloured liquid with mild odour.
Appearance
Not required.
pH
Greater than 1.0
Vapour Pressure
(Butyl Acetate = 1)
78 ?117 o C {literature value}
Boiling Point oC
0.90 {calculated value}
Density
Immiscible
Solubility in water
- 4 o C {literature value}
Flash Point oC
Lower Explosive Limit = 1.2 % Upper Explosive Limit = 15.0 %
Flammability
Limits
340 o C
Auto Ignition oC
Organic Solvents
Volatile
Components
March 2010 Page 4 of 5
Material Safety Data Sheet
SUPER ETCH PRIMER
STABILITY and REACTIVITY
Stable under normal conditions of use.
Chemical Stability
Avoid contact with heat and all ignition sources.
Conditions to avoid
On heating, containers may rupture and explode: contents may burn rapidly
Hazardous
forming toxic gases including carbon monoxide.
decomposition
products
Incompatible with strong oxidizing agents
Incompatible
materials
Will not polymerize.
Hazardous Reactions
TOXICOLOGICAL INFORMATION
Health Effects Risk Phrase Ethyl Alcohol Methyl Ethyl Ketone
Inhalation LC50 rat 20 > 20 mgm/L > 20 mgm/L
Dermal LD50 rabbit 21 > 2000 mgm/kgm > 2000 mgm/kgm
Oral LD50 rat 22 > 2000 mgm/kgm > 2000 mgm/kgm
Note
Risk phrases R20/21/22 has been assigned by the EEC Council Directive 67/548/EEC.
Risk Phrases R20/21/22 ?Harmful by inhalation, skin contact or if swallowed.
Acute Oral Toxicity Low toxicity. Aspiration into lungs when swallowed or vomited may cause
rat chemical pneumonitis which can be fatal.
Acute Dermal Low toxicity
Toxicity rabbit
Acute Inhalation Low toxicity. High concentrations may cause central nervous system depression
Toxicity rat resulting in headaches, dizziness, nausea, loss of co-ordination and impaired
judgement: continued inhalation may result in unconsciousness and/or death.
OTHER TOXICOLOGICAL INFORMATION
Health Effects
Inhalation Other symptoms may cause dizziness, nausea, coughing, lack of co ?ordination
and impair judgement.
Ingestion Large quantities may cause nausea and vomiting.
Eyes Irritating to the eyes, including burning sensation, redness, swelling and/or
blurred vision.
Skin Will have degreasing effect on the skin may result in contact dermatitis.
Carcinogenicity Limited evidence of a carcinogenic effect.
Mutagenicity Not mutagenic in animal studies
Reproductive Does not impair fertility. Causes foetotoxicity in animals at doses which are
Toxicity maternally toxic.
ECOLOGICAL INFORMATION
Toxic to aquatic organisms (R51).
Environment
May cause long ?term adverse effects in the aquatic environment (R53).
March 2010 Page 5 of 5
Material Safety Data Sheet
SUPER ETCH PRIMER
DISPOSAL CONSIDERATIONS
Collect all residues and placed into labelled and sealed containers. Do not
incinerate empty containers after use. Dampen all unwanted cloths and rags in
water prior to disposal. Do not recycle contents or spent containers. Crush all
small empty containers. Larger containers and drums may be sent to an approved
drum recycler. Ensure all contents do not pollute waterways, drains and other
water courses.
TRANSPORT INFORMATION
1263
UN number
PAINT, immiscible in water.
Proper Shipping
Name
3 Not Required
Class Subsidiary Risk
II
Packing Group
3300 14
Emergency Initial Emergency
Procedures Response Guide
3[Y]E
HAZCHEM
Not Known
IMDG
REGULATORY INFORMATION
Classified as a Schedule S 5 poison.
SUSDP
OTHER INFORMATION
Emergency Poisons Information Centre 13 11 26 HiChem Paint Technologies
Contact (03) 9796 3400
Data provided is to best of HiChem Paint Technologies Proprietary Limited knowledge and
Disclaimer
believe to be accurate and reliable as of the date of issued. However no expressed or implied
warranties are given. HiChem Paint Technologies Proprietary Limited cannot anticipate or
control the conditions under which this information may be used. Therefore, it is user's
responsibility to satisfy themselves as to the suitability and completeness of such information for
their particular use. It is the responsibility of the user to ensure that the issue is current. This
information given is a non-controlled document
Version 2 ?Revised (7383)
20/02/2010
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