3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 09/19/2007
Supercedes Date: 11/27/2001
Document Group: 10-2684-8
Product Use:
Intended Use: Adhesive
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
Acetone 67-64-1 40 - 50
Toluene 108-88-3 10 - 20
Methyl Ethyl Ketone 78-93-3 10 - 20
Acrylonitrile-Butadiene Polymer 9003-18-3 10 - 20
Phenolic Resin 25085-50-1 3- 7
Glycerol Esters of Rosin Acids 8050-31-5 3- 7
Salicylic Acid 69-72-7 1- 5
Zinc Oxide 1314-13-2 0.5 - 1.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Brown, strong ketone odor.
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
flash back. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
May be absorbed through skin and cause target organ effects.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and
decreased ability to concentrate.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
404 篊 [Details: MEK]
Autoignition temperature
-4 篎 [Test Method: Closed Cup] [Details: Acetone]
Flash Point
1.3 % volume
Flammable Limits - LEL
12.8 % volume
Flammable Limits - UEL
Class IB Flammable Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build
dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film
forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or
commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an
absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible
using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the
area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing
solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected
material as soon as possible.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under
pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers
securely when transferring contents. Wear low static or properly grounded shoes. Avoid breathing of vapors, mists or spray. Avoid
static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Vapors may ignite explosively.
May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended
exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from
heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. For industrial or professional use only. Avoid contact
with oxidizing agents.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container
tightly closed. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Provide local exhaust ventilation at transfer points. Provide appropriate local exhaust
ventilation on open containers. If exhaust ventilation is not available, use appropriate respiratory protection.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber, Polyethylene/Ethylene Vinyl Alcohol.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
Acetone ACGIH TWA 500 ppm Table A4
Acetone ACGIH STEL 750 ppm Table A4
Acetone OSHA TWA, Vacated 750 ppm
Acetone OSHA TWA 1000 ppm Table Z-1
Acetone OSHA STEL, Vacated 1000 ppm
Methyl Ethyl Ketone ACGIH TWA 200 ppm
Methyl Ethyl Ketone ACGIH STEL 300 ppm
Methyl Ethyl Ketone OSHA TWA 200 ppm Table Z-1A
Methyl Ethyl Ketone OSHA STEL 300 ppm Table Z-1A
Toluene ACGIH TWA 20 ppm Table A4
Toluene CMRG STEL 75 ppm Skin Notation*
Toluene OSHA TWA, Vacated 100 ppm
Toluene OSHA STEL, Vacated 150 ppm
Toluene OSHA TWA 200 ppm Table Z-2
Toluene OSHA CEIL 300 ppm Table Z-2
Zinc Oxide ACGIH TWA, respirable 2 mg/m3
Zinc Oxide ACGIH STEL 10 mg/m3
Zinc Oxide OSHA TWA, as fume 5 mg/m3 Table Z-1
Zinc Oxide OSHA TWA, respirable 5 mg/m3 Table Z-1
Zinc Oxide OSHA STEL, Vacated, as 10 mg/m3
fume
Zinc Oxide OSHA TWA, Vacated, as 10 mg/m3
dust
Zinc Oxide OSHA TWA, as total dust 15 mg/m3 Table Z-1
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Brown, strong ketone odor.
Odor, Color, Grade:
Liquid
General Physical Form:
404 篊 [Details: MEK]
Autoignition temperature
-4 篎 [Test Method: Closed Cup] [Details: Acetone]
Flash Point
1.3 % volume
Flammable Limits - LEL
12.8 % volume
Flammable Limits - UEL
>=56 篊
Boiling point
0.88 g/ml
Density
2.0 [Ref Std: AIR=1]
Vapor Density
<=185 mmHg [@ 68 篎]
Vapor Pressure
.88 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
Not Applicable
Melting point
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
Slight (less than 10%)
Solubility in Water
1.9 [Ref Std: ETHER=1]
Evaporation rate
10 - 12 % weight
Hazardous Air Pollutants
223 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
70 - 80 % weight
Percent volatile
416 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
175 - 350 centipoise [@ 73.4 篎]
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Sparks and/or flames; Heat
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D035 (Methyl ethyl ketone)
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-1022-5530-4, 62-1022-6530-3, 62-1022-6535-2, 62-1022-7535-1, 62-1022-8535-0, 62-1022-9535-9, 62-1022-9537-5
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Toluene 108-88-3 10 - 20
Methyl Ethyl Ketone 78-93-3 10 - 20
Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 0.5 - 1.5
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
Acetone 67-64-1 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
Toluene 108-88-3 *Developmental Toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Nitrile High Performance Rubber and Gasket Adhesive 847L
09/19/2007
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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