Page 1/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
* 1 Identification of substance:
?Product details:
?Trade name: PRIMER BLACK PRB 83661
?Article number: 83661
?Application of the substance / the preparation Priming
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
Monday - Thursday 8.30am - 5.30pm, Friday 9.00am - 3.00pm
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation:
@@
??
GC Xn Harmful
F Highly flammable
?Information pertaining to particular dangers for man and environment
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 36 Irritating to eyes.
R 42/43 May cause sensitisation by inhalation and skin contact.
Contains isocyanates. See information supplied by the manufacturer
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
~
Danger
H225 - Highly flammable liquid and vapour.
~
Danger
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
~ Warning
H332 - Harmful if inhaled.
H336 - May cause drowsiness or dizziness.
Warning
H319 - Causes serious eye irritation.
H317 - May cause an allergic skin reaction.
Contains isocyanates. May produce an allergic reaction.
?Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
(Contd. on page 2)
GB
Page 2/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: PRIMER BLACK PRB 83661
(Contd. of page 1)
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
@
? Xi, ? F; R 11-36-66-67
G @
C
CAS: 78-93-3 butanone 25-50%
Danger: ~ 2.6/2
EINECS: 201-159-0
Warning: ~ 3.3/2, 3.8/3
G
@
? Xn, ? Xi; R 42/43
@
G
CAS: 63368-95-6 Polyurethane polymer 20-40%
Danger: ~ 3.4.R/1
Warning: 3.4.S/1
CAS: 123-86-4 n-butyl acetate R 10-66-67 5-10%
Warning: ~ 2.6/3; ~ 3.8/3
EINECS: 204-658-1
Danger: ~ 2.11/1
CAS: 1333-86-4 Carbon black 1-5%
EINECS: 215-609-9
? Xi; R 38-41-43
@
G
CAS: 1760-24-3 N-(3-(trimethoxysilyl)propyl)ethylenediamine <2%
Danger: ~ 3.3/1
EINECS: 217-164-6
Warning: ~ 3.4.S/1; 3.2/2
@
F
? T+, ? Xi; R 26-36/37/38-40-42/43-52/53
@
G
CAS: 26471-62-5 m-tolylidene diisocyanate <0.15%
Danger: ~ 3.1.I/2; ~ 3.4.R/1, 3.6/2
EINECS: 247-722-4
Warning: 3.2/2, 3.3/2, 3.4.S/1, 3.8/3, 4.1.C/3
@
? T, ? Xi; R 23-36/37/38-42/43
F @
G
CAS: 822-06-0 hexamethylene diisocyanate <0.15%
Danger: ~ 3.1.I/3; ~ 3.4.R/1
EINECS: 212-485-8
Warning: 3.2/2, 3.3/2, 3.4.S/1, 3.8/3
* 4 First aid measures
?General information
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
?After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
?After skin contact Instantly wash with water and soap and rinse thoroughly.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing Do not induce vomiting; instantly call for medical help.
* 5 Fire fighting measures
?Suitable extinguishing agents
Alcohol-resistant foam
Water haze
Fire-extinguishing powder
Carbon dioxide
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
?Protective equipment: Wear self-contained breathing apparatus.
* 6 Accidental release measures
?Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
(Contd. on page 3)
GB
Page 3/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: PRIMER BLACK PRB 83661
(Contd. of page 2)
Ensure adequate ventilation
Keep away from ignition sources
?Measures for environmental protection:
Inform respective authorities in case product reaches water or sewage system.
Do not allow to enter drainage system, surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable containers.
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
* 7 Handling and storage
?Handling
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Keep away from heat and direct sunlight.
Store in cool, dry place in tightly closed containers.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Fumes can combine with air to form an explosive mixture.
?Storage
?Requirements to be met by storerooms and containers:
Store in cool location.
Store only in the original container.
?Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials.
Do not store together with alkalis (caustic solutions).
Store away from water.
?Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
butanone
WEL Short-term value: 899 mg/m? 300 ppm
Long-term value: 600 mg/m? 200 ppm
Sk
n-butyl acetate
WEL Short-term value: 966 mg/m? 200 ppm
Long-term value: 724 mg/m? 150 ppm
Carbon black
WEL Short-term value: 7 mg/m?br>
Long-term value: 3.5 mg/m?br>
m-tolylidene diisocyanate
WEL Short-term value: 0.07 mg/m?br>
Long-term value: 0.02 mg/m?br>
Sen; as -NCO
hexamethylene diisocyanate
WEL Short-term value: 0.07 mg/m?br>
Long-term value: 0.02 mg/m?br>
Sen; as -NCO
?Additional information: The lists that were valid during the compilation were used as basis.
(Contd. on page 4)
GB
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: PRIMER BLACK PRB 83661
(Contd. of page 3)
?Personal protective equipment
?General protective and hygienic measures
Take off immediately all contaminated clothing
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing
apparatus that is independent of circulating air.
Filter AX/P2.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Rubber gloves
PVC gloves
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Tightly sealed safety glasses.
?Body protection: Protective work clothing.
* 9 Physical and chemical properties:
?General Information
Form: Liquid
Colour: Black
Odour: Solvent-like
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: 79癈
?Flash point: -5癈
?Ignition temperature: 310.0癈
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive. However, formation of explosive air/steam mixtures is possible.
?Critical values for explosion:
Lower: 1.0 Vol %
Upper: 10.6 Vol %
?Vapour pressure at 20癈: 101 mbar
?Density at 25癈 0.9 g/ml
?Solubility in / Miscibility with
Water: Unsoluble
?Viscosity:
kinematic at 20癈: 16 s (DIN 53211/4)
?Solvent content:
Organic solvents: 645g/l VOC
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.
(Contd. on page 5)
GB
Page 5/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: PRIMER BLACK PRB 83661
(Contd. of page 4)
No decomposition if used and stored according to specifications.
?Materials to be avoided:
?Dangerous reactions
Reacts with water
Reacts with amines
Reacts with alcohols
?Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Formation of harmful gases is possible during heating or in case of fire.
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
butanone
Oral LD50 3300 mg/kg (rat)
Dermal LD50 5000 mg/kg (rabbit)
n-butyl acetate
Oral LD50 14000 mg/kg (rat)
Inhalative LC50/4 h >21.0 mg/l (rat)
Carbon black
Oral LD50 10000 mg/kg (rat)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritant effect.
?Sensitization:
Sensitization possible by skin contact.
Sensitization possible by inhalation.
?Additional toxicological information:
Harmful
Irritant
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
?Sensitisation May cause sensitisation by inhalation and skin contact.
* 12 Ecological information:
?Additional ecological information:
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
* 13 Disposal considerations
?Product:
?Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
GB
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: PRIMER BLACK PRB 83661
(Contd. of page 5)
* 14 Transport information
?Land transport ADR/RID (cross-border)
g
c
d
x
?ADR/RID-GGVS/E Class: 3 (F1)
?UN-Number: 1993
?Packaging group: II
?Label 3
?Designation of goods: 1993 FLAMMABLE LIQUID, N.O.S. (vapor pressure at 50癈 at most 110 kPa) (ETHYL METHYL
KETONE (METHYL ETHYL KETONE))
?Maritime transport IMDG:
x
g
c
d
?IMDG Class: 3
?UN Number: 1993
?Label 3
?Packaging group: II
?EMS Number: F-E,S-E
?Marine pollutant: No
?Correct technical name: FLAMMABLE LIQUID, N.O.S. (ETHYL METHYL KETONE (METHYL ETHYL KETONE))
?Air transport ICAO-TI and IATA-DGR:
g
x
c
d
?ICAO/IATA Class: 3
?UN/ID Number: 1993
?Label 3
?Packaging group: II
?Correct technical name: FLAMMABLE LIQUID, N.O.S. (ETHYL METHYL KETONE (METHYL ETHYL KETONE))
?UN "Model Regulation": UN1993, FLAMMABLE LIQUID, N.O.S., 3, II
* 15 Regulatory information
?Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
?Code letter and hazard designation of product:
@@
GC
?? Xn Harmful
F Highly flammable
?Hazard-determining components of labelling:
Polyurethane polymer
m-tolylidene diisocyanate
?Risk phrases:
11 Highly flammable.
20 Harmful by inhalation.
36 Irritating to eyes.
42/43 May cause sensitisation by inhalation and skin contact.
(Contd. on page 7)
GB
Page 7/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: PRIMER BLACK PRB 83661
(Contd. of page 6)
?Safety phrases:
3/7 Keep container tightly closed in a cool place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe fumes.
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
60 This material and its container must be disposed of as hazardous waste.
?Special designation of certain preparations:
Contains isocyanates. See information supplied by the manufacturer
?National regulations
?Technical instructions (air):
Class Share in %
I 0.2
III 60.0
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
23 Toxic by inhalation.
26 Very toxic by inhalation.
36 Irritating to eyes.
36/37/38 Irritating to eyes, respiratory system and skin.
38 Irritating to skin.
40 Limited evidence of a carcinogenic effect.
41 Risk of serious damage to eyes.
42/43 May cause sensitisation by inhalation and skin contact.
43 May cause sensitisation by skin contact.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
?Department issuing data specification sheet: Environment protection department
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB
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