MATERIAL SAFETY DATA SHEET
AEROSOL BUMPER AND TRIM COATS
Containing Methylene Chloride
6/16/05
PRODUCTS COVERED: BUMPER COATS: AF-2 and TRIM COATS: AT-1, AT-2
SECTION I MANUFACTURER
Crest Industries, Inc., 1337 King Road, Trenton, MI 48183 Phone: (734) 479-4141 FAX: (734) 479-4040
24 HOUR EMERGENCY TELEPHONE (CHEMTEL): (800) 255-3924 INTERNATIONAL CALLS: (813) 248-0585
SECTION II PRODUCTS
Numbers of HMIS
Stock Ingredients RATING Solubility Volatile
No. Product Name on Label in Products H F R Appearance and Odor % in Water Volume %
AF-2 Bumper Coat, Satin Black 2,4,6,7,8,10 3* 4 0 Black liquid, strong <1 96
AT-1 Trim Coat, Gloss Black 1,2,5,6,7,9,10 3* 4 0 Black liquid, strong <1 96
AT-2 Trim Coat, Satin Black 1,2,3,5,6,7,8,10 3* 4 0 Black liquid, strong <1 95
*Chronic health effects may occur from ingredient 6. See NOTES in SECTION VI.
SECTION III HAZARDOUS INGREDIENTS
Exposure Limits* Flash Vapor Pres- Evap. Rate Boiling Flammable Autoigni-
CAS in ppm (parts Point sure (mm Hg (n-Butyl Point Limits in % tion Pt.
Ingredients Number per million) 癋 癈 at 20癈) Acetate=1) 癋 癈 Lower Upper 癋 癈
1. n-Butyl Acetate 123-86-4 150 A, O 76 24 8 1.0 248 120 1.7 7.6 797 425
3
2. Carbon Black 1333-86-4 3.5 mg/m **A, O -NA- NA NA -NA- -NA- -NA-
3. Ethyl-3-ethoxy-
propionate 763-69-9 Not Established 136 58 1.1 0.12 320 163 1.05 Unk Unknown
4. Isobutane 75-28-5 1000 A, 800 NIOSH -120 -84 >760 NA 11 -12 1.8 9.5 860 460
5. 1-Methoxy-2-
Propanol Acetate 108-65-6 Not Established 116 47 3.7 0.34 295 146 Unknown Unknown
6. Methylene
Chloride** 75-09-2 50 A, 25 O** None 340 14.5 104 40 -NA- 1224 662
7. Methyl Ethyl
Ketone 78-93-3 200 A, O 16 -9 85 4.6 174 79 1.8 10.0 759 404
8. Propane 74-98-6 1000 A, O <-40 >6000 390 -45 -43 2.1 9.5 842 450
9. Propane/Butane
Blend 68476-85-7 1000 A, O <-40 >6000 390 -45 -43 2.1 9.5 842 450
10. Toluene 108-88-3 50 A Skin, 200 O 45 7 38 1.5 230 110 1.2 7.0 896 480
*A means ACGIH TLV, O means OSHA PEL. Other abbreviations: >means greater than, < means less than, NA means Not
Applicable, NE means Not Established. Skin means vapor exposure to the skin must also be considered.
**See NOTES in SEC. VI.
SECTION IV PHYSICAL DATA terial handling point. At elevated temperatures [130癋 (54癈) or
Pressure of Can Contents: Maximum pressure less than 140 PSI over] containers may vent, rupture or burst.
Gauge at 130癋 (54癈). Evaporation Rate: See SECTIONS II, III. SECTION VI HEALTH HAZARD DATA
Vapor Density: Heavier than air. Solubility in Water (Wt%): See PRIMARY ROUTES OF EXPOSURE: Inhalation, Skin contact, Eye
SECTION II. Volatile Volume %: See SECTION II. Approximate contact
Boiling Point: See SECTIONS II, III. Product Density (water = 1): SIGNS AND SYMPTOMS OF EXPOSURE:
Less than 1. Ingredients (except 2,6): Less than 1. INHALATION:
Appearance and Odor: See SECTION II. Acute Exposure: Solvent vapors at concentrations above the
SECTION V FIRE AND EXPLOSION DATA TLV can irritate the respiratory tract (nose, throat, lungs) causing a
Flammability Class: Extremely Flammable Aerosol burning sensation, runny nose, sore throat, coughing, chest discom-
Flash Point (Tag Closed Cup Method): See SECTIONS II, III. fort (tightness). May cause central nervous system depression with
Approximate Flammable Limits: See SECTIONS II, III. the following progressive symptoms: headache, dizziness, nausea,
Autoignition Temperature: See SECTIONS II, III. staggering gait, confusion, unconsciousness, cessation of breathing
Extinguishing Media: Foam, carbon dioxide, dry chemical and death.
Special Fire Fighting Procedures: Full protective equipment, in- Chronic Exposure: Reports have associated repeated and pro-
cluding self-contained breathing apparatus, is recommended be- longed occupational overexposure to solvents with permanent brain
cause highly toxic gasses may be generated by combustion or and nervous system damage. Symptoms include loss of memory,
thermal decomposition. Water from fog nozzles may be used to loss of intellectual ability and loss of coordination. NOTE: 6. Me-
cool closed containers to prevent pressure build up (containers may thylene Chloride has caused cancer in certain laboratory animals.
leak or burst when heated). See note under CARCINOGENICITY.
Unusual Fire and Explosion Hazards: Vapors are heavier NOTE: INTENTIONAL MISUSE BY DELIBERATELY CONCEN-
than air and may travel along the ground or be moved by ventilation TRATING AND INHALING ANY SOLVENT VAPORS MAY BE
and ignited by pilot lights, other flames, sparks, heaters, electric HARMFUL OR FATAL!
motors, smoking or other ignition sources at locations far from ma-
Aerosol Bumper and Trim Coats Containing Methylene Chloride 6/16/05 Page 2
SKIN CONTACT: dilators, expectorants and antitussives may help.
Acute Exposure: Repeated or prolonged skin contact with sol- Eyes: May cause conjunctivitis. Stain for evidence of corneal in-
vents can result in dry, defatted and cracked skin causing increased jury.
susceptibility to infection. Skin irritation may develop into contact Skin: Treat as any contact dermatitis.
dermatitis. Ingestion: Treat as for solvent ingestion. Inducing vomiting is
Chronic Exposure: Exposure to small amounts of solvent over contraindicated because of the possibility of chemical pneumonia
long periods of time may cause some or all of the caused by aspiration of solvent liquid.
symptoms as in acute exposure to solvents. SECTION VIII EMPLOYEE PROTECTION
EYE CONTACT: RECOMMENDATIONS
Acute Exposure: Irritation of the eyes with itching, burning, red- EYE PROTECTION: Desirable during use of aerosol products.
ness and even permanent tissue damage if sprayed directly into the Wear safety glasses, splash goggles or face shield. Contact lenses
eyes and not flushed out immediately. should not be worn.
Chronic Exposure: Irritation of the eyes with itching, burning, SKIN PROTECTION: Cover as much of the skin as possible with
redness. appropriate clothing. Wear solvent resistant gloves.
INGESTION: VENTILATION AND RESPIRATORY PROTECTION: If exhaust
Acute Exposure: (Not likely unless deliberately sprayed into ventilation sufficient to keep the airborne concentrations of solvents
and propellants below their respective TLV's is not possible, an
mouth.) Irritation to the mouth and, if swallowed, to the esophagus,
OSHA/MSHA approved TC23C Paint Spray Respirator with Particu-
stomach tissue and digestive tract. If swallowed, vomiting may
late Prefilter or TC19C Air Supplied Respirator must be used. A
cause breathing of liquid solvent resulting in chemical pneumonia.
dust mask must be worn when sanding or grinding is done on the
Chronic Exposure: Unknown.
dry coatings. A dust mask does not protect against vapors! Ob-
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None
specifically known to Crest Industries, Inc. but it is possible that eye, serve OSHA regulations (29 CFR 1910.134) for respirator use.
respiratory tract, skin, liver, kidney, blood cell formation, nervous NOTE: THERE MUST ALWAYS BE ENOUGH VENTILATION TO
system and brain diseases may be aggravated by overexposure to KEEP VAPOR CONCENTRATION BELOW THE LOWER FLAM-
the products on this MSDS. MABLE LIMIT!
CARCINOGENICITY: Products not listed by NTP, IARC or OSHA. OTHER PROTECTIVE MEASURES: Eyewash stations should be
NOTE: 6. Methylene Chloride has caused cancer in certain labo- available. Educate and train employees in safe use of products.
ratory animals. Risk to health depends on level and duration of ex- Follow all label instructions.
posure. Be careful to minimize breathing the solvent vapors from SECTION IX REACTIVITY DATA
the products on this MSDS. Use products outdoors, if possible. If STABILITY: Stable under normal room conditions.
you must use indoors, open all windows and doors or use other HAZARDOUS POLYMERIZATION: Will not occur.
means to assure fresh air movement during application and drying. INCOMPATIBILITY (Materials to Avoid): Strong oxidizers.
If properly used, a respirator (NIOSH/MSHA TC23C or equivalent) HAZARDOUS DECOMPOSITION PRODUCTS: By high heat and
may offer additional protection. Get professional advice for respira- fire: carbon dioxide, carbon monoxide, hydrocarbon vapors, smoke,
tor use. A dust mask does not protect against vapors! Clean up hydrogen chloride, chlorine, phosgene and chlorinated hydrocarbon
vapors.
rags and other waste immediately and allow solvent vapors to
SECTION X SPILL OR LEAK PROCEDURES
evaporate outdoors. DO NOT USE IN BASEMENT OR OTHER
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR
UNVENTILATED AREA!
SPILLED: Put on protective equipment including respiratory protec-
SECTION VII EMERGENCY AND FIRST AID
tion. Prevent further spillage. Evacuate nonessential personnel.
PROCEDURES
Remove all sources of ignition and ventilate the area. Keep spill
INHALATION: Move to an area free from risk of further exposure.
from reaching sewers and waterways. Cover the spill with sawdust,
Administer oxygen or artificial respiration as needed. Obtain medical
vermiculite, Fuller's Earth or other absorbent material. Collect ma-
attention.
terial with non-sparking tools and put in a tightly sealed container.
EYE CONTACT: Flush with clean, lukewarm water (low pressure)
Remove container to a safe place.
for at least 15 minutes while lifting eyelids. Refer person to physi-
WASTE DISPOSAL METHOD: Follow all federal, state and local
cian for immediate attention.
environmental control regulations. Incineration of the liquid or dried
SKIN CONTACT: Remove contaminated clothing immedi-
material is the preferred method. DO NOT PUT AEROSOL CON-
ately. Clean affected areas thoroughly with waterless skin cleaner
TAINERS IN A HOME TRASH COMPACTOR! DO NOT INCINER-
and/or soap and water. Wash contaminated clothing thoroughly
ATE (OR BURN) AEROSOL CONTAINERS EVEN WHEN EMPTY!
before reuse. Seek medical attention if irritation develops or per-
Containers may become pressurized and burst even if they will not
sists.
spray. Containers must be handled with care due to flammable,
INGESTION: DO NOT INDUCE VOMITING! Consult physician,
pressure producing and toxic residue.
hospital emergency room or poison control center immediately.
RCRA STATUS: Since these products are ignitable and toxic, they
Have list of ingredients available.
are hazardous when discarded.
NOTES TO PHYSICIAN:
Inhalation: Treat for solvent vapor inhalation. Broncho-
Aerosol Bumper and Trim Coats Containing Methylene Chloride 6/16/05 Page 3
temperatures above 120 F (49 C) or in direct sunlight. Do not inhale
SECTION XI SPECIAL PRECAUTIONS &
vapors or spray mist. Avoid contact with skin and eyes. Wash hands
STORAGE DATA
after use and before eating, drinking, smoking or using the toilet.
STORAGE TEMPERATURE
Employee education and training in the safe use and handling of
MINIMUM / MAXIMUM: 50 F (10 C) / 120 F (49 C)
these materials are required under the OSHA Hazard Communica-
RECOMMENDED SHELF LIFE: One year
tion Standard (29 CFR 1910.1200).
PRECAUTIONS TO BE TAKEN IN HANDLING, STORAGE AND
USE: Keep away from heat, sparks and open flame. Do not store in
KEEP OUT OF THE REACH OF CHILDREN!
SECTION XII FEDERAL EPA REGULATION COMPLIANCE INFORMATION
EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT of 1986
1) Section 313 Supplier Notification: Chemicals marked with an * in the following tables are subject to the Toxic Chemical Release In-
ventory Reporting Requirements using EPA FORM R (40 CFR Part 372).
2) Section 312: All the chemicals listed are subject to Emergency and Hazardous Chemical Inventory Forms and Community Right-to-
Know Reporting Requirements: Tier I and Tier II Reports (40 CFR Part 370).
NOTE: This information must be included in all MSDSs that are copied and distributed for materials covered by this MSDS.
HAZARDOUS INGREDIENTS IN AEROSOL BUMPER AND TRIM COATS
APPROXIMATE PERCENTAGES BY WEIGHT
Ingredients (Chemicals) CAS Number AF2 AT1 AT2
1. n-Butyl Acetate 123-86-4 1-5 1-5
2. Carbon Black 1333-86-4 0.4-2 0.4-2 0.4-2
3. Ethyl-3-ethoxypropionate 763-69-9 1-5
4. Isobutane 75-28-5 10-15
5. 1-Methoxy-2-Propanol Acetate
(Glycol Ether PM Acetate) 108-65-6 0.6-3 0.6-3
* 6. Methylene Chloride 75-09-2 35-40 30-35 35-40
7. Methyl Ethyl Ketone 78-93-3 1-5 1-5 1-5
8. Propane 74-98-6 10-15 20-25
*9. Propane/Butane Blend 68476-85-7 25-30
10. Toluene 108-88-3 25-30 25-30 20-25
Physical Hazard-Fire 57 62 52
Physical Hazard-Pressure Release 28 28 28
Health Hazard-Acute 100 100 100
Health Hazard-Chronic 65 60 60
Physical Hazard-Reactivity NOT APPLICABLE
Aerosol Level ALL ARE LEVEL 2
SECTION XIII VOLATILE ORGANIC COMPOUND (VOC) CONTENT ACCORDING TO THE FEDERAL EPA
Stock Numbers AF2 AT1 AT2
Weight Percent 57.2 61.6 51.7
Pounds per Gallon 4.01 4.24 3.68
Grams per Liter 481 508 441
Pounds per Can 0.465 0.501 0.420
SECTION XIV CALIFORNIA PROPOSITION 65 WARNINGS
According to the California Safe Drinking Water and Toxic Enforcement Act (PROPOSITION 65) "No person in the course of doing busi-
ness shall knowingly and intentionally expose any individual to a chemical known to the State of California to cause cancer, birth defects
or reproductive toxicity without first giving clear and reasonable warning to such individuals of such an exposure".
The following warning applies for these products that all contain Methylene Chloride and Toluene:
WARNING: This product contains chemicals known to the State of California to cause
cancer, birth defects and other reproductive harm.
SECTION XV OZONE DEPLETION IN THE UPPER ATMOSPHERE
None of the products on this MSDS contain Upper Atmosphere ozone depleting substances.
DISCLAIMER: The information contained in this MSDS is believed to be accurate and reliable as of the date indicated.
Crest Industries, Inc. assumes no legal responsibility and makes no representation, warranty or guarantee, expressed
or implied, as to the completeness or accuracy of the information. It is offered solely for your consideration, investigation
and verification. The user is ultimately responsible for the safe use of the material in accordance with applicable federal,
state, provincial and local laws and regulations.
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