ZEP MANUFACTURING COMPANY
02/12/01
PAGE 1
ISSUE DATE: 09/23/96 ZEP 45 NC
SUPERSEDES: 11/15/94 PRODUCT NUMBER: 0149
Aerosol Lubricant
SECTION I - E M E R G E N C Y C O N T A C T S
MEDICAL EMERGENCY: TOLL FREE 1-877-541-2016 ALL CALLS RECORDED
TRANSPORTATION EMERGENCY: CHEMTREC: TOLL FREE 1-800-424-9300 ALL CALLS RECORDED
--------------------------------------------------------------------------------
SECTION II - H A Z A R D O U S I N G R E D I E N T S
TLV EFFECTS % IN
DESIGNATIONS (PPM) (SEE REVERSE) PROD.
** LIGHT AROMATIC NAPHTHA ** aromatic hydrocarbon N/D CBL CNS IRR 10-20
solvent; solvent naphtha(petroleum); CAS#
64742-95-6; RTECS# NONE; OSHA PEL-N/D
** LIGHT ALIPHATIC NAPHTHA ** solvent naphtha 100 IRR CBL 10-20
(petroleum), medium aliphatics; formerly: light
aromatic naphtha; CAS# 64742-88-7; RTECS# NONE;
OSHA PEL 500ppm
** PARAFFIN OIL ** blend of heavy and light naph- N/D IRR 10-20
thenic petroleum distillate; CAS# 64742-52-5; RTECS#
NONE; OSHA PEL - N/D; ACGIH OIL MIST LIMIT= 5mg/m3
** ETHANOL ** ethyl alcohol; grain alcohol; CAS# 1000 IRR FBL 5-15
64-17-5; RTECS# KQ6300000; OSHA PEL-1000 ppm
** MINERAL SEAL OIL ** (mineral oil); petrolatum; N/A IRR 5-15
CAS# 64742-30-9; RTECS# - NONE; ACGIH/OSHA OIL MIST
LIMIT = 5 mg/m3
** 2-ETHYL HEXYL ALCOHOL ** 2-ethyl-1-hexanol; ethyl- N/D IRR CBL < 10
hexanol; CAS# 104-76-7; RTECS# MP0350000;
OSHA PEL N/D
--------------------------------------------------------------------------------
SECTION III - H E A L T H H A Z A R D D A T A
SPECIAL NOTE: MSDS data pertains to the product as dispensed from the container.
Adverse health effects would not be expected under recommended conditions
of use (diluted) so long as prescribed safety precautions are practiced.
ACUTE EFFECTS OF OVEREXPOSURE:
Exposure by inhalation may produce eye, nose, and throat irritation. Inhalation
of harmful amounts of vapor may produce mild central nervous system depression,
characterized by headache, nausea, vertigo and stupor. If vomiting occurs,
aspiration of the solvent into the lungs can cause chemical pneumonia. Existing
respiratory disorders or skin diseases may be aggravated by exposure.
CHRONIC EFFECTS OF OVEREXPOSURE:
PAGE 2
ISSUE DATE: 09/23/96 ZEP 45 NC
SUPERSEDES: 11/15/94 PRODUCT NUMBER: 0149
Aerosol Lubricant
SECTION III - H E A L T H H A Z A R D D A T A (CONTINUED)
CHRONIC EFFECTS OF OVEREXPOSURE: (CONTINUED)
Repeated or prolonged, skin contact may produce mild central nervous system de-
pression, characterized by headache, nausea, stupor, and coma. Skin which is
defatted by repeated exposure to hydrocarbon solvents is more susceptible to
irritation, infection, and dermatitis. Animal studies of the effects of
prolonged inhalation indicated a potential for lung damage and blood production
abnormalities, some of which were fatal. Relevance of these studies to human
health and the levels of exposure which might produce these results, has not
been established.
None of the ingredients are listed as carcinogens by IARC, NTP, or OSHA.
See Section IX for additional information.
EST'D PEL/TLV: Not established PRIMARY ROUTES OF ENTRY: Inh, Skin.
--------------------------------------------------------------------------------
HMIS CODES: HEALTH 2; FLAM. 2; REACT. 0; PERS. PROTECT. B ; CHRONIC HAZ. YES
--------------------------------------------------------------------------------
FIRST AID PROCEDURES:
SKIN : Wash contaminated skin thoroughly with soap or a mild detergent. Apply a
skin cream with lanolin. Get medical attention if irritation persists.
EYES : Immediately flush eyes with plenty of water for at least 15 minutes, oc-
casionally lifting upper and lower lids. Get medical attention at once.
INHALE: Move exposed person to fresh air. If irritation persists,
get medical attention promptly.
INGEST: If swallowed, do not induce vomiting. If vomiting occurs, keep head
below hip level. Get emergency medical attention immediately.
--------------------------------------------------------------------------------
SECTION IV - S P E C I A L P R O T E C T I O N I N F O R M A T I O N
PROTECTIVE CLOTHING : If prolonged contact is expected or occurs, wear nitrile
or other gloves with proven resistance to the ingredient
EYE PROTECTION : To prevent accidental eye contact, the use of safety gla
goggles is recommended when using any aerosol product.
RESPIRATORY PROTECTION: When exposure levels exceed PEL/TLV (likely in confined
areas) use an organic vapor respirator (eg Zep 2211).
VENTILATION : Provide local exhaust/ventilation as needed to keep con-
centration of vapors below exposure limits (PEL/TLV).
--------------------------------------------------------------------------------
SECTION V - P H Y S I C A L D A T A (FOR FILL MATERIAL ONLY)
BOILING POINT (F) : 355 SPECIFIC GRAVITY : 0.860
VAPOR PRESSURE(MMHG): N/D EVAPORATION RATE(WATER =1): < 1
VAPOR DENSITY(AIR=1): N/D PH(CONCENTRATE) : N/A
SOLUBILITY IN WATER : N/A PH(USE DILUTION OF ): N/A
VOC CONTENT (CONCENTRATE) 73.0%
APPEARANCE AND ODOR :A clear, brown oily liquid with a strong, sweet odor.
--------------------------------------------------------------------------------
PAGE 3
ISSUE DATE: 09/23/96 ZEP 45 NC
SUPERSEDES: 11/15/94 PRODUCT NUMBER: 0149
Aerosol Lubricant
SECTION VI - F I R E A N D E X P L O S I O N D A T A
FLASH POINT(F) (METHOD USED): Flammable (CSMA)
FLAMMABLE LIMITS LEL N/D UEL N/D
EXTINGUISHING MEDIA : Carbon dioxide, dry chemical and foam.
SPECIAL FIRE FIGHTING: Wear self-contained positive pres. breathing apparatus.
UNUSUAL FIRE HAZARDS : Direct water onto intact containers to prevent bursting.
--------------------------------------------------------------------------------
SECTION VII - R E A C T I V I T Y D A T A
STABILITY : Stable
INCOMPATIBILITY(AVOID) : Heat, open flame, spark, and oxidizing agents.
POLYMERIZATION : Will not occur.
HAZARDOUS DECOMPOSITION: Carbon dioxide, carbon monoxide, and other unidentified
organic compounds.
--------------------------------------------------------------------------------
SECTION VIII - S P I L L A N D D I S P O S A L P R O C E D U R E S
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Observe safety precautions in sections 4 & 9 during spill clean-up. Large
spills are unlikely due to packaging. Spill may be absorbed on an inert absorb-
ent material (eg Zep-O-Zorb), and placed in a suitable container for disposal.
Wash area thoroughly with a detergent solution and rinse well with water.
WASTE DISPOSAL METHOD:
Product is consumed in use. Do not crush, puncture or incinerate spent contain-
ers. Large numbers of aerosol containers may require handling as a hazardous
waste, but in most states total hazardous waste quantities less than 220 lbs per
month may allow disposal in a chemical or industrial waste landfill. Consult
local, state and federal agencies for the proper disposal method in your area.
RCRA HAZ. WASTE NOS.: D001
--------------------------------------------------------------------------------
SECTION IX - S P E C I A L P R E C A U T I O N S
PRECAUTIONS TO BE TAKEN WHEN HANDLING AND STORING:
One of the ingredients in this product has been shown to have reproductive
effects in laboratory test animals when administered in very high oral doses.
The implications of these findings for human exposure is unknown.
Flammable! Store and use away from heat, sparks, open flame, and any source of
ignition.
Keep product away from skin and eyes.
Do not breathe spray mists or vapors.
Vapors are heavier than air and will accumulate at low points. Ventilation
should include floor level exhausting.
Keep out of the reach of children.
--------------------------------------------------------------------------------
PAGE 4
ISSUE DATE: 09/23/96 ZEP 45 NC
SUPERSEDES: 11/15/94 PRODUCT NUMBER: 0149
Aerosol Lubricant
SECTION X - R E G U L A T O R Y I N F O R M A T I O N
DOT PROPER SHIP NAME: CONSUMER COMMODITY,
NOTE: DOT information applies to larger package sizes of affected products.
For some products, DOT may require alternate names and labeling in
accordance with packaging group requirements.
DOT HAZARD CLASS: ORM-D DOT PACKING GROUP:
DOT I.D. NUMBER : N/A DOT LABEL/PLACARD: ORM-D
EPA TSCA CHEMICAL INVENTORY - ALL INGREDIENTS ARE LISTED
EPA CWA 40CFR PART 117 SUBSTANCE(RQ IN A SINGLE CONTAINER): NONE
NOTICE
Thank you for your interest in, and use of, Zep products. Zep Manufacturing Co.
is pleased to be of service to you by supplying this Material Safety Data Sheet
for your files. Zep Manufacturing is concerned for your health and safety. Zep
products can be used safely with proper protective equipment and proper handling
practices consistent with label instructions and the MSDS. Before using any Zep
product, be sure to read the complete label and the Material Safety Data Sheet.
As a further word of caution, Zep wishes to advise that serious accidents have
resulted from the misuse of "emptied" containers. "Empty" containers retain
residue (liquid and/or vapor) and can be dangerous. DO NOT pressurize, cut,
weld, braze, solder, drill, grind or expose such containers to heat, flame, or
other sources of ignition; they may explode or develop harmful vapors and pos-
sibly cause injury or death. Clean empty containers by triple rinsing with water
or an appropriate solvent. Empty containers must be sent to a drum reconditioner
before reuse.
TERMS AND ABBREVIATIONS - LISTED ALPHABETICALLY BY SECTION
SECTION II: HAZARDOUS INGREDIENTS
CAR: Carcinogen - A chemical listed by the National Toxicology Program (NTP),
the International Agency for Research on Cancer (IARC) or OSHA as a definite or
possible human cancer causing agent.
CAS #: Chemical Abstract Services Registry Number - A univers- ally accepted
numbering system for chemical substances.
CBL: Combustible - At temperatures between 100F and 200F chemical gives off
enough vapor to ignite if a source of ignition is present as tested with a
closed cup tester.
CNS: Central Nervous System depressant which reduces the activity of the brain
and spinal cord.
COR: Corrosive - Causes irreversible injury to living tissue (e.g. burns).
DESIGNATIONS: Chemical and common names of hazardous ingredients.
EIR: Eye Irritant Only - Causes reversible reddening and/or inflammation of eye
tissues.
EXPOSURE LIMITS: The time weighted average (TWA) airborne concentration at which
most workers can be exposed without any expected adverse effects.
Primary sources include ACGIH TLVs, and OSHA PELs (TWA, STEL and ceiling limits).
ACGIH: American Conference of Governmental Industrial Hygienists.
CEILING: The concentration that should not be exceeded in the workplace
during any part of the working exposure.
OSHA: Occupational Safety and Health Administration
PEL: Permissible Exposure Limit - A set of time weighted average exposure
values, established by OSHA, for a normal 8-hour day and a 40-hour work week.
PPM: Parts per million - unit of measure for exposure limits.
(S) SKIN: Skin contact with substance can contribute to overall exposure.
STEL: Short Term Exposure Limit - Maximum concentration for a continuous
15-minute exposure period.
TLV: Threshold Limit Value - A set of time weighted average exposure limits,
established by the ACGIH, for a normal 8-hour day and a 40-hour work week.
FBL: Flammable - At temperatures under 100F, chemical gives off enough vapor to
ignite if a source of ignition is present as tested with a closed cup tester.
HAZARDOUS INGREDIENTS: Chemical substances determined to be potential health or
physical hazards based on the criteria established in the OSHA Hazard Communi-
cation Standard - 29 CFR 1910.1200
HTX: Highly toxic - the probable lethal dose for a 70kg (150 lb.) man and may be
approximated as less than 6 teaspoons (2 tablespoons).
IRR: Irritant - Causes reversible effects in living tissues
(e.g. inflammation) - primarily skin and eyes.
N/A: Not Applicable - Category is not appropriate for this product.
N/D: Not Determined - Insufficient information to make a determination for this
item.
RTECS#: Registry of Toxic Effects of Chemical Substances - an unreviewed listing
of published toxicology data on chemical substances.
SARA: Superfund Amendment and Reauthorization Act - Section
313 designates chemicals for possible reporting for the Toxics Release Inventory.
SEN: Sensitizer - Causes allergic reaction after repeated exposure.
TOX: Toxic - The probable lethal dose for a 70 kg (150 lb.) man is one ounce
(2 tablespoons) or more.
SECTION III: HEALTH HAZARD DATA
ACUTE EFFECT: An adverse effect on the human body from a single exposure with
symptoms developing almost immediately after exposure or within a relatively
short time.
CHRONIC EFFECT: Adverse effects that are most likely to occur from repeated
exposure over a long period of time.
EST D PEL/TLV: This estimated, time-weighted average, exposure limit, developed
by using a formula provided by the ACGIH, pertains to airborne concentrations
from the product as a whole. This value should serve as guide for providing safe
workplace conditions to nearly all workers.
HMIS CODES: Hazardous Material Identification System - a rating system developed
by the National Paint and Coating Association for estimating the hazard
potential of a chemical under normal workplace conditions. These risk estimates
are indicated by a numerical rating given in each of three hazard areas
(Health/Flammability/Reactivity) ranging from a low of zero to a high of 4. The
presence of a chronic hazard is indicated with a yes. Consult HMIS training
guides for Personal Protection letter codes which indicate necessary protective
equipment.
PRIMARY ROUTE OF ENTRY: The way one or more hazardous ingredients may enter the
body and cause a generalized-systemic or specific-organ toxic effect.
ING: Ingestion - A primary route of exposure through swallowing of material
INH: Inhalation - A primary route of exposure through breathing of vapors.
SKIN: A primary route of exposure through contact with the skin.
SECTION IV: SPECIAL PROTECTION INFORMATION
Where respiratory protection is recommended, use only MSHA and NIOSH approved
respirators and dust masks.
MSHA: Mine Safety and Health Administration
NIOSH: National Institute for Occupational Safety and Health
SECTION V: PHYSICAL DATA
EVAPORATION RATE: Refers to the rate of change from the liquid state to the
vapor state at ambient temperature and pressure in comparison to a given sub-
stance (e.g. water).
pH; A value representing the acidity or alkalinity of an aqueous solution
(Acidic pH = 1; Neutral pH = 7; Alkaline pH = 14)
VOC CONTENT: The percentage or amount in pounds per gallon of the product that
is regulated as a Volatile Organic Compound under the Clean Air Act of 1990 and
various state jurisdictions.
SOLUBILITY IN WATER: A description of the ability of the product to dissolve in
water.
SECTION VII: REACTIVITY DATA
HAZARDOUS DECOMPOSITION: Breakdown products expected to be produced upon product
decomposition by extreme heat or fire.
INCOMPATIBILITY: Material contact by extreme heat and the conditions to avoid to
prevent hazardous reactions.
POLYMERIZATION: Indicates the tendency of the product's molecules to combine
with themselves in a chemical reaction, releasing excess pressure and heat.
STABILITY: Indicates the susceptibility of the product to spontaneously and
dangerously decompose.
SECTION VIII: SPILL AND DISPOSAL PROCEDURES
RCRA WASTE NOS: RCRA (Resource Conservation and Recovery Act) waste codes
(40 CFR 261) applicable to the disposal of spilled or unusable product from the
original container.
SECTION X: TRANSPORTATION DATA
CWA: Clean Water Act- Federal Law which regulates chemical releases to bodies of
water.
RQ: Reportable Quantity - The amount of the specific ingredient that, when spil-
led to the ground and can enter a storm sewer or natural watershed, must be re-
ported to the National Response Center, and other regulatory agencies.
TSCA: Toxic Substances Control Act - a federal law requiring all commercial
chemical substances to appear on an inventory maintained by the EPA.
DISCLAIMER
All statements, technical information and recommendations contained herein are
based on available scientific tests or data which we believe to be reliable. The
accuracy and completeness of such data are not warranted or guaranteed. We can-
not anticipate all conditions under which this information and our products, or
the products of other manufacturers in combination with out products, may be
used. Zep assumes no liability or responsibility for loss or damage resulting
from the improper use or handling of our products, from incompatible product
combinations, or from the failure to follow instructions, warnings, and
advisories in the products label and Material Safety Data Sheet.
(rev. 1/98)
|