3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
11/11/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 11/11/2005
Supercedes Date: 07/27/2005
Document Group: 20-2765-4
Product Use:
Specific Use: Moisture Curing Hot Melt Adhesive
SECTION 2: INGREDIENTS
Ingredient
p,p'-DIPHENYLMETHANEDIISOCYANATE (MDI)
POLYURETHANE RESIN - N.J. TRADE SECRET(T.S.) REGISTRY NO.
04499600-6412PC.A.S. No. % by Wt
101-68-8 < 3
Trade Secret > 97
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Waxy Solid
Odor, Color, Grade: white/off-white, mild odor.
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause thermal burns.
May cause allergic respiratory reaction.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
11/11/2005
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Thermal Burns: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction.
Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
Skin Contact:
Thermal Burns: Signs/symptoms may include intense pain, redness and swelling, and tissue destruction.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:
Vapors from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal
discharge, headache, hoarseness, and nose and throat pain.
Prolonged or repeated exposure may cause:
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion:
Physical Blockage: Signs/symptoms may include cramping, abdominal pain, and constipation.
Target Organ Effects:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE
MOLTEN MATERIAL. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of cold water for at least 15
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
11/11/2005
minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Get immediate
medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available
Flash Point >=200 咰
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
5.2 EXTINGUISHING MEDIA
Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. Collect as much of the spilled material as possible. Place in a
closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid skin contact with hot material. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or
professional use only. Avoid eye contact with dust or airborne particles. Keep container closed when not in use. Keep out of the
reach of children. Do not heat or expose adhesive to temperatures above 275 degrees F (135 degrees C).
7.2 STORAGE
Store away from heat. Store out of direct sunlight.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
11/11/2005
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no
air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational
Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. Avoid skin contact. Avoid skin
contact with hot material. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure
assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
8.2.3 Respiratory Protection
Avoid breathing of vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface supplied-air respirator. Consult the current 3M Respiratory Selection Guide for
additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not ingest.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
FREE ISOCYANATES 3M TWA 0.005 ppm
FREE ISOCYANATES 3M STEL 0.02 ppm
p,p'-ACGIH TWA 0.005 ppm
DIPHENYLMETHANEDIISOCYANATE
(MDI)
p,p'-OSHA CEIL 0.02 ppm Table Z-1
DIPHENYLMETHANEDIISOCYANATE
(MDI)
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: Waxy Solid
Odor, Color, Grade: white/off-white, mild odor.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
11/11/2005
General Physical Form: Solid
Autoignition temperature No Data Available
Flash Point >=200 咰
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
Boiling point 302 咶 [@ 5 mmHg] [Details: MDI]
Density 1.05 g/ml
Vapor Density 8.6 [Ref Std: AIR=1] [Details: MDI]
Vapor Pressure 0.0003 mmHg [@ 25 咰] [Details: MDI]
Specific Gravity 1.05 [Ref Std: WATER=1]
pH Not Applicable
Melting point Approximately 55 咰
Solubility in Water Nil
Evaporation rate No Data Available
Hazardous Air Pollutants 2 - 3 % weight [Test Method: Calculated]
Volatile Organic Compounds 3.2 g/l [Test Method: tested per EPA method 24]
Percent volatile <=0.5 % weight
VOC Less H2O & Exempt Solvents 3.2 g/l [Test Method: tested per EPA method 24]
Viscosity Approximately 9000 centipoise [Details: CONDITIONS: @ 250 F]
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Amines; Alcohols; Heat; Reaction with water, alcohols, and amines is not hazardous if
container can vent to the atmosphere to prevent pressure buildup.
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Amine Compounds During Combustion
Isocyanates During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Cyanide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
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ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of waste product in a sanitary landfill. Incinerate in an industrial or commercial facility in the
presence of a combustible material. As a disposal alternative, incinerate in an industrial or commercial facility.
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-3881-5230-8, 62-3881-5235-7, 62-3881-6825-4, 62-3881-6839-5, 62-3881-8530-8, 62-3881-9530-7
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's
transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable
current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to
transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified
for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory
requirements.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
p,p'-DIPHENYLMETHANEDIISOCYANATE 101-68-8 < 3
(MDI) (Diisocyanates (EPCRA 313))
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
11/11/2005
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product name was modified.
Section 2: Ingredient table was modified.
Page Heading: Product name was modified.
Section 15: EPCRA 313 information was modified.
Section 8: Exposure guidelines ingredient information was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Polyurethane Reactive (PUR) Easy Adhesive EZ17005
11/11/2005
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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