Material Safety Data Sheet
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1. Chemical Product and Company Identification
DESCRIPTION: PROBOND POLYURETHANE GLUE
PRODUCT TYPE: POLYURETHANE
APPLICATION: FOR PRODUCT CODES SEE SECTION 16
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* Manufacturer/Supplier Information
MSDS Prepared by:
Elmer's Products, Inc. Emergency Phone Number
1000 Kingsmill Parkway Poison Control Center
Columbus, OH 43229 1-800-228-5635 ext 22
For additional health, safety or regulatory information, call 614-225-7689.
Call 1-800-848-9400 to place an order or request additional MSDSs.
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2. Composition, Information on Ingredients
The ingredients listed below have been associated with one or more
immediate and/or delayed(*) health hazards. Risk of damage and effects
depends upon duration and level of exposure. BEFORE USING, HANDLING, OR
EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.
% by weight
101-68-8 *Diphenylmethane 4,4'-Diisocyanate 10-30
9016-87-9 *Polymeric Diphenylmethane Diisocyanate 30-50
*Modified Polymeric MDI 50-70
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3. Hazards Identification
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3.1 Emergency Overview
Appearance Viscous dark brown liquid
Odor Slightly musty
WARNING!
Hazardous polymerization may occur.
Reacts with water.
Will burn.
Harmful if inhaled.
May cause allergic skin and respiratory reactions.
May be harmful if absorbed through skin.
Skin irritant.
Eye irritant.
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* HMIS Rating
HEALTH = 3 (serious)
FLAMMABILITY = 1 (slight)
REACTIVITY = 1 (slight)
CHRONIC = *
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3.2 Potential Health Effects
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* Immediate Hazards
INGESTION: Not expected to be harmful under normal conditions of
use.
If accidently swallowed, burns or irritation to mucous
membranes, esophagus or GI tract can result.
INHALATION: Harmful if inhaled. If material is heated, sprayed
or otherwise dispersed, may cause irritation of nose,
throat and lungs. Concentrations below the exposure
guidelines may cause allergic respiratory reactions
in individuals already sensitized. Symptoms may
include coughing, difficult breathing and a feeling
of tightness in the chest. Effects may be delayed.
SKIN: Skin contact may result in allergic skin reactions or
respiratory sensitization. However, it is not expected
to result in absorption of amounts sufficient to cause
other adverse effects. Causes irritation.
EYES: Causes irritation.
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* Delayed Hazards
Diphenylmethane 4,4'-Diisocyanate 101-68-8
Lung tumors have been observed in laboratory animals exposed to
aerosol droplets of diphenylmethane 4,4'-diisocyanate (MDI)/polymeric
MDI (6 mg/m? for their lifetime. Tumors occurred concurrently with
respiratory irritation and lung injury. This material has not been
listed by NTP, classified by IARC, nor regulated by OSHA as a
carcinogen.
May cause allergic skin and respiratory reactions.
Can cause lung damage. Pre-existing respiratory disorders may be
aggravated by exposure.
Polymeric Diphenylmethane Diisocyanate 9016-87-9
Lung tumors have been observed in laboratory animals exposed to
aerosol droplets of diphenylmethane 4,4'-diisocyanate (MDI)/polymeric
MDI (6 mg/m? for their lifetime. Tumors occurred concurrently with
respiratory irritation and lung injury. This material has not been
listed by NTP, classified by IARC, nor regulated by OSHA as a
carcinogen.
May cause allergic skin and respiratory reactions.
Can cause lung damage. Pre-existing respiratory disorders may be
aggravated by exposure.
Modified Polymeric MDI
May cause allergic skin and respiratory reactions.
-- See Footnote C.
Footnote C: As of the date of issuance of this document, this
material has not been listed by NTP, classified by IARC nor regulated
by OSHA as a carcinogen.
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4. First Aid Measures
INGESTION: If accidently swallowed, dilute by drinking large
quantities of water. Immediately contact poison control
center or hospital emergency room for any other
additional treatment directions.
INHALATION: If inhaled, remove to fresh air. If not breathing
give artificial respiration, preferably mouth-to-mouth.
If breathing is difficult, give oxygen. Call a
physician.
SKIN: Immediately wash with soap and plenty of water for
at least 15 minutes while removing contaminated clothing
and shoes. Call a physician if symptoms occur. Wash
clothing and shoes before reuse.
EYES: Immediately flush eyes with plenty of water for at
least 15 minutes. Eyelids should be held apart during
irrigation to insure water contact with entire surface of
eyes and lids. Call a physician.
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5. Fire Fighting Measures
Flash Point >250 deg F (121 deg C)
Will burn.
In case of fire, DO NOT use water. Use dry chemical or CO2.
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6. Accidental Release Measures
Soak up with absorbent material and remove to a chemical disposal
area. Prevent entry into natural bodies of water.
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7. Handling and Storage
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7.1 Handling
Handle in accordance with good industrial hygiene and safety
practices. These practices include avoiding unnecessary exposure and
removal of the material from eyes, skin and clothing.
Wash thoroughly after handling.
INHALATION: Do not breathe vapor. Use with adequate ventilation.
SKIN: Avoid contact with skin and clothing.
EYES: Avoid contact with eyes.
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7.2 Storage
Keep container closed.
Keep from freezing.
Keep in tightly sealed containers and store in a cool dry place,
avoiding exposure to heat, light, moisture and air.
Store at 60-100 F (16-38 C).
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8. Exposure Controls/Personal Protection
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8.1 Exposure Controls
ENGINEERING CONTROLS: The following exposure control techniques may
be used to effectively minimize employee exposure: local exhaust
ventilation, enclosed system design, process isolation and remote
control in combination with appropriate use of personal protective
equipment and prudent work practices. These techniques may not
necessarily address all issues pertaining to your operations. We,
therefore, recommend that you consult with experts of your choice to
determine whether or not your programs are adequate.
If airborne contaminants are generated when the material is heated or
handled, sufficient ventilation in volume and air flow patterns should
be provided to keep air contaminant concentration levels below
acceptable criteria.
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8.2 Personal Protection
Wear synthetic apron and boots if contact is likely. Where air
contaminants can exceed acceptable criteria, use NIOSH/MSHA approved
respiratory protection equipment. Respirators should be selected
based on the form and concentration of contaminants in air in
accordance with OSHA laws and regulations or other applicable
standards or guidelines, including ANSI standards regarding
respiratory protection. Use goggles and face shield if contact is
likely. Wear impervious gloves as required to prevent skin contact.
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8.3 Exposure Guidelines
Diphenylmethane 4,4'-Diisocyanate 101-68-8
ACGIH TLV: 0.005 ppm (0.051 mg/m? TWA
OSHA PEL: 0.02 ppm (0.2 mg/m? Ceiling
Polymeric Diphenylmethane Diisocyanate 9016-87-9
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
Modified Polymeric MDI
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
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9. Physical and Chemical Properties
pH @ 25 C Not applicable
Specific Gravity 1.14
Appearance Viscous dark brown liquid
Boiling Point Not applicable
Vapor Density (Air=1) 8.5 approx.
Vapor Pressure, mm Hg @ 20 C <0.0003
Evaporation Rate (Butyl Acetate=1) Not available
Flash Point >250 deg F (121 deg C)
Melting point Not available
Odor Slightly musty
Odor Threshold, ppm 0.4 (4,4'-Diphenylmethane diisocyanate)
Solubility (other) Soluble in most organic solvents
Solubility in Water Reacts with water
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10. Stability and Reactivity
Normally stable, but will react with water.
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* Incompatibilities:
Contact with water, alcohols, amines and alkalies causes
polymerization.
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* Decomposition products may include:
None known to Borden.
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* Hazardous polymerization:
May occur.
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* Other Hazards:
None known to Borden.
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11. Toxicological Information
See Section 3 Hazards Identification information.
Diphenylmethane 4,4'-Diisocyanate 101-68-8
LC50: rat=178 mg/m?(RTECS)
LD50: orl-mus=2200 mg/kg (RTECS)
Polymeric Diphenylmethane Diisocyanate 9016-87-9
LC50: rat=490 mg/m?4H (respirable aerosol)
LD50: orl-rat>5000 mg/kg; skn-rbt>5000 mg/kg
Modified Polymeric MDI
LC50: Not available
LD50: Not available
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12. Ecological Information
Not determined.
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13. Disposal Considerations
Recover free liquid. Absorb residue and dispose of according to
local, state/provincial, and federal requirements.
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14. Transport Information
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14.1 U.S. Department of Transportation (DOT)
The data provided in this section is for information only and may not
be specific to your package size. You will need to apply the
appropriate regulations to properly classify your shipment for
transportation.
Non-Regulated.
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14.2 Canadian Transportation of Dangerous Goods (TDG)
Non-Regulated.
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15. Regulatory Information (Selected Regulations)
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15.1 U.S. Federal Regulations
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* OSHA Hazard Communication Standard 29CFR1910.1200
This material is a "health hazard" and/or a "physical hazard" as
determined when reviewed according to the requirements of the
Occupational Safety and Health Administration 29 CFR Part 1910.1200
"Hazard Communication" Standard.
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* SARA Title III: Section 311/312
Reactivity hazard
Immediate health hazard
Delayed health hazard
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* SARA Title III Section 313 and 40 CFR Part 372
This product contains the following toxic chemical(s) subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
Notification Requirement of 40 CFR Part 372.
Methylenebis(4-phenylisocyanate) (MDI) 101-68-8 28.00%
Polymeric Diphenylmethane Diisocyanate 9016-87-9 45.00%
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* TSCA Section 8(b) Inventory
All reportable chemical substances are listed on the TSCA Inventory.
We rely on certifications of compliance from our suppliers for
chemical substances not manufactured by Borden.
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15.2 Canadian Regulations
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* Workplace Hazardous Materials Information System (WHMIS)
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all the information required by the CPR.
CLASS D, DIV 1A
CLASS D, DIV 2A, 2B
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* Canadian Environmental Protection Act (CEPA)
All reportable chemical substances are listed on the Domestic
Substances List (DSL) or otherwise comply with CEPA new substance
notification requirements.
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* National Pollutant Release Inventory (NPRI)
This product contains the following chemical(s) subject to the
reporting requirements of the Canadian Environmental Protection Act
(CEPA) subsection 16(1), National Pollutant Release Inventory.
Methylenebis(phenylisocyanate) 101-68-8 28.00%
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16. Other Information
MSDS covers items:
U.S.: P9401, P9402, P9405, P9406
Canada: 69401, 69402, 69406
HL (Cautions Required): Products bearing the HL Health Label
(Cautions Required) Seal of The Art & Creative Materials Institute,
Inc. (ACMI) are certified to be properly labeled in a program of
toxicological evaluation by a medical expert. This program is
reviewed by ACMI's Toxicological Advisory Board. These products are
certified by ACMI to be labeled in accordance with the chronic hazard
labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695.
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* User's Responsibility
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Hazardous Materials Information System (WHMIS) require that the information
contained on these sheets be made available to your workers. Educate and
train your workers regarding OSHA and WHMIS precautions. Instruct your
workers to handle this product properly. Consult with appropriate experts
to guard against hazards associated with use of this product and its
ingredients.
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* Disclaimer
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind
shall be greater in amount than the purchase price of the quantity of
product in respect of which damages are claimed. In no event shall Seller
be liable for incidental or consequential damages, whether Buyer's claim is
based on contract, breach of warranty, negligence or otherwise.
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CUR ISSUE 15-JUN-99
PREVIOUS ISSUE: 29-JAN-98
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