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MSDS Material Safety Data Sheet
CAS

27136-15-8
9010-79-1
8002-74-2
1309-38-2

File Name: 27136-15-8.asp

                      Panasonic Communications Co., Ltd.
Digital Imaging Company
9-1 Hiraide Industrial Park, Utsunomiya City, Tochigi, 321-8502 Japan
TEL : Japan (0) 28-683-6660, FAX : Japan (0) 28-662-8393


Material Safety Data Sheet
Page: 1 of 4
MSDS No.: 021-000373
Date : 21st January, 2003

SECTION 1 PRODUCT IDENTIFICATION
Product Name : Toner of DQ-TU18B Toner Cartridge, DQ-RK18B Toner Refill Kit
and DZHP004267/DZHP0004985 Process Unit for Panasonic Digital
Copier Models DP-2000, DP-2000E, DP-2000P, DP-2500, DP-2500D,
DP-2500E, DP-2500P, DP-3000, DP-3000P and DP-3000E

Product No. : Toner of DQ-TU18B Toner Cartridge, DQ-RK18B Toner Refill Kit
and DZHP004267/DZHP0004985 Process Unit


SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENTS PROPORTION
(Common Name) CAS # (% by wt.) OSHA PEL ACGIH TLV OTHER LIMITS
鈥? Styrene-acrylate 27136-15-8 > 47.0 None established None established None
copolymer
鈥? Polypropylene 9010-79-1 < 4.0 None established None established None

鈥? Paraffine wax 8002-74-2 < 4.0 None established None established None

鈥? Iron oxide 1309-38-2 < 45.0 None established None established None




SECTION 3 HAZARDOUS IDENTIFICATION
EMERGENCY OVERVIEW : Odorless black fine powder.
Not a highly flammable, but when suspended in air, is
combustible as with most organic powders.
POTENTIAL HEALTH EFFECTS:
EYE EFFECTS : Solid or dusts may cause irritation or corneal injury.

SKIN EFFECTS : Essentially nonirritating to skin.
Skin absorption is unlikely due to physical properties.
INGESTION EFFECTS : Oral toxicity is believed to be low.

INHALATION EFFECTS : Minimal irritation to respiratory track may occur.


FIRE AND EXPLOSION:
SENSITIVITY TO MECHANICAL IMPACT : None
SENSITIVITY TO STATIC CHARGE: None



MSDS-2003
Page: 2 of 4
MSDS No.: 021-000373

SECTION 4 FIRST AID MEASURES
EYE CONTACT: Any material that contacts the eye should be washed out
immediately with water.
Wash di
G t afterleach contact.
tt ti if t i
SKIN CONTACT:
Get medical attention if symptoms is occur.
INHALATION: If symptomatic, remove to fresh air.
Get medical attention if symptoms persist.
INGESTION : If swallowed, drink 1-2 glasses of water and immediately induce
vomiting. Get medical attention.



SECTION 5 FIRE FIGHTING MEASURES
FLASH POINT : Not applicable.

FLAMMABLE LIMITS : Not applicable.

EXTINGUISHING MEDIA : Water fog, dry chemical, foam or CO2.

HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, Carbon dioxide and Smoke
FIRE-FIGHTING EQUIPMENT : Wear full bunker gear including a positive pressure
self-contained breathing apparatus in case of
burning in large quantities.

SECTION 6 ACCIDENTAL RELEASE MEASURES
Minimize the release of particulates. Wear personal protective equipment. Sweep
up or vacuum spilled toner and carefully transfer into sealed waste container.
Sweep slowly to minimize generation of dust during cleanup. If a vacuum is used,
the motor must be rated as dust tight. Residue can be removed with soap and water.
Garments may be washed or dry cleaned, after removal of loose toner.


SECTION 7 HANDLING AND STORAGE
HANDLING : Avoid creating dust. Clean up all spills promptly.
Inhalation and contact with skin or eyes should be avoided.
Provide general ventilation. Good general ventilation should be
sufficient of most conditions.
STORAGE : Store in a cool, well ventilated place away from flames and
spark-producing equipment.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV= 10mg/m3(Total dust)
EXPOSURE GUIDELINES:
OSHA PEL= 15mg/m3(Total dust), 5mg/m3(Respirable dust)
ENGINEERING CONTROLS: Good general ventilation is recommended.

RESPIRATORY PROTECTION : Not required under normal conditions. For use other
than in normal operating procedures (such as in the
event of large spill), goggles and respirators may be
required.

SKIN PROTECTION : No precautions should be needed under normal use.

EYE PROTECTION : No precautions should be needed under normal use.


MSDS-2003
Page: 3 of 4
MSDS No.: 021-000373
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE : Black fine powder
ODOR : None
pH : Not applicable
VAPOR PRESSURE (mg Hg.) : Not applicable
VAPOR DENSITY (AIR = 1) : Not applicable
% VOLATILE : Not applicable
BOILING POINT (掳C) : Not applicable
MELTING POINT (掳C) : Not applicable
SOLUBILITY IN WATER : Negligible
SPECIFIC GRAVITY (H2O=1) : 1.6



SECTION 10 STABILITY AND REACTIVITY
STABILITY: Stable

HAZARDOUS REACTIONS: Dust explosion, like most finely divided organic
powders.
CONDITIONS TO AVOID: Electronic discharge, throwing into fire.

MATERIALS TO AVOID: Oxidizing materials.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon dioxide and Smoke.


SECTION 11 TOXICOLOGICAL INFORMATION
HEALTH EFFECTS FROM EXPOSURE: No symptoms expected with intended use.

ACUTE TOXICITY:

INHALATION: Finely divided solid. Avoid exposure to dust.
EYES: No specific hazard known. May cause temporary irritation.
SKIN: Low hazard for recommended handling.
INGESTION: Expected to be a low ingestion hazard.
MUTAGENICITY: Negative in the Ames test
CARCINOGENICITY:
No carcinogen or potential carcinogen, according to IARC Monographs, NTP,
OSHA(USA) regulation and EU Directive.




CHRONIC EFFECTS:
In study in rats (H. Muhle) by chronic inhalation exposure to a typical toner,
a mild to moderate degree of lung fibrosis was observed in 92% of the rats
in the high concentration (16mg/m3) exposure group, and a minimal to mild degree
of fibrosis was noted in 22% of the animals in the middle (4mg/m3) exposure
group.
But no pulmonary change was reported in the lowest (1mg/m3) exposure group,
the most relevant level to potential human exposure.




MSDS-2003
Page: 4 of 4
MSDS No.: 021-000373
SECTION 12 ECOLOGICAL INFORMATION
No data available.


SECTION 13 DISPOSAL CONSIDERATION
METHOD OF DISPOSAL: When disposing of the waste or recovered material,
consult federal, state and/or local regulations for
the proper disposal method.


SECTION 14 TRANSPORT INFORMATION
UN CLASS: None allocated.

DOT CLASS: None allocated.

TDG CLASS: None allocated.


SECTION 15 REGULATORY INFORMATION
USA Information:
All chemical substances in this product comply with all applicable rules or orders
under TSCA.
Australia Information:
Not classified as hazardous according to criteria of NOHSC.



SECTION 16 OTHER INFORMATION
REFERENCES:
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper,
J.C.Mackenzie, P.Morrow, U.Mohr, S.Takenaka and R.Mermelstein (1991) Pulmonary
Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and
Applied Toxicology 17, pp.280-299.


Information on this data sheet represents our current data and best opinion as to the proper use in handling
of this product under normal conditions.




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