S A FE T Y D A T A S H E E T
according to EC Directive 2001/58/EC Date of issue: 23-08-2005
revised on: 14-05-2007
Page: 1 of 4
WUXAL庐 Liquid
Trade name:
Product-No.: 11817
1 Identification of the preparation and Company
Preparation: NPK-fertilizer solution 8-8-6 with micronutrients
Description: Aqueous solution of nutrient salts.
Use: Fertilizer, preparation for plant nutrition
Manufacturer/Supplier: AGLUKON Speziald眉nger GmbH & Co. KG Telephone: +49 (0)211 5064-0
Address: Heerdter Landstra脽e 199 Telefax: +49 (0)211 5064-247
40549 D眉sseldorf, Germany
Australian Distributor AgNova Technologies Pty Ltd
Informing department: See chapter 16:
Emergency telephone (D/Berlin): Telephone No.: +49 (0)30 19240 (Day and Night)
Emergency telephone Australia: Telephone No.: 1800 033 111 (Day and Night)
2 Composition/Information on Ingredients
Harmful components:
Marking EC-No. CAS-No. Content (%) Danger symbol R-phrases
10 鈥? 45
Ammonium nitrate 229-347-8 6484-52-2 O: Oxidizing 8-9
Additional information: Full text of R-Phrases: see under section 16.
3 Hazards Identification
Hazards designation: None.
Particular hazards (R-phrases): No hazardous product as specified in Directive 67/548/EEC.
No hazardous product as specified in Directive 96/82/EC and 2003/105/EC
(Seveso II).
Harmful effects/symptoms: In event of fire, the formation of nitrous gases is possible.
Additional information: Preparation as a solution harmless, but danger of explosion in the dry state if in
mixture with inflammable materials.
4 First-Aid Measures
General hints: Remove soiled clothes.
after inhalation Take out to the fresh air, rest quiet and warm. Medical assistance is necessary in
of vapours/aerosols: case of difficulty in breathing.
after skin contact: Immediately wash affected skin regions thoroughly with soap and plenty of water.
Summon doctor if necessary.
after eyes contact: Thoroughly rinse eyes with lids wide apart under running water (protect the uninjured
eye, remove contact lenses). Summon eye specialist if necessary.
after ingestion: Immediately rinse the mouth with water, then drink a lot of water. Consult the doctor
in case of persistent trouble.
General hints: Remove soiled clothes.
5 Fire-Fighting Measures
Suitable extinguishing media: Water
Unsuitable extinguishing media: Do not use chemical extinguishers or foams or attempt to smother the fire with steam
or sand.
Special risks: Preparation as a solution harmless, but danger of explosion in the dry state if in
mixture with inflammable materials.
The material itself is hardly inflammable. Ambient fire may liberate hazardous
vapours. If larger quantities of the product are on fire, the formation of nitrous gases,
ammonia and phosphoric acid gases is possible.
Special equipment to protect Do not stay in dangerous zone without suitable protecting clothes and selfcontained
firefighters: breathing apparatus.
Other information: Contain escaping vapours with water.
Prevent fire-fighting water from entering surface water or groundwater.
6 Accidental Release Measures
Personal precautions: Wear suitable protecting clothes. Avoid product contact and formation of
vapours/aerosols. Do not inhale vapours/aerosols. In event of vapours/aerosols wear
respiratory protection, safety glasses and gloves.
Specific hazards: The material itself is harmless and hardly inflammable as. Ambient fire may liberate
11817 WUXAL Liquid AgNovaEG-Sida07_eng.doc / print: 2007-05-14
S A FE T Y D A T A S H E E T
according to EC Directive 2001/58/EC Date of issue: 23-08-2005
revised on: 14-05-2007
Page: 2 of 4
WUXAL庐 Liquid
Trade name:
Product-No.: 11817
hazardous vapours. If larger quantities of the product are on fire, the formation of
nitrous gases, ammonia and phosphoric acid gases is possible.
Special equipment to protect Do not stay in dangerous zone without suitable protecting clothes and selfcontained
firefighters: breathing apparatus.
Other information: Contain escaping vapours with water.
Prevent fire-fighting water from entering surface water or groundwater.
Environmental precautions: Ensure that the product does not reach the ground-water, water bodies or the
drainage system.
Methods for cleaning up/taking up: Take up with absorption media;. Disposal of contaminated material as waste
according to section 13.
7 Handling and Storage
Handling
Advice as to safe handling: Wear suitable protecting clothes. Avoid product contact and formation of
vapours/aerosols. Do not inhale vapours/aerosols. In event of vapours/aerosols wear
respiratory protection, safety glasses and gloves.
Remove soiled and soaked clothes and wash hands and face after work
(see section 8).
Advice to prevent fire and explosion: Product rests to be cleared away by rinsing with water before starting fire and hot
works on containers and devices. Fire and hot works can only be carried out by an
expert after previous permission in writing or under permanent supervision of an
expert.
Pumps must be so constituted and used that no hazardous reactions can occur.
Pumps without stuffing boxes to be used only. Crystallized product to be dissolved
again with plenty of water.
Storage
Stockrooms and containers It is recommended to design stockrooms so that the product is well-protected from
required: weather factors, solar radiation, heat up, dry up and impurities.
Keep stockrooms free from fireplaces and other ignition sources.
Keep containers densely closed and store in a cool dry place.
To fight a fire and decomposition keep care of a sufficient water supply.
Ensure high standard of housekeeping in the storage area.
Do not store in metal containers (corrosion risk).
Temperature in stockrooms not below +5 掳 and above +40 掳
C C.
Storage together with other Do not store together with:
materials: - strong alcaline materials,
- strong acid materials,
- combustible materials,
- substances, which form perilous reactions with ammonium nitrate.
Do not store together with food and luxury food, beverage and animal feed.
More information see section 10.
8 Exposure Controls / Personal Protection
Exposure limits
The preparation contains no constituents with occupational exposure limits rsp. biological occupational exposure limits
requiring monitoring.
Personal protective equipment
Respiratory protection: Not required. Respiratory protection necessary at vapour/aerosol and wet fog
formation.
Hand protection: Rubber or plastic gloves
Eye protection: Safety goggles
Skin and body protection: Closed working clothes
Preventive and hygiene measures: Do not eat and drink at work. Remove immediately soiled and soaked clothes. Wash
hands and face after work.
9 Physical and Chemical Properties
Appearance
Form/physical state: Aqueous liquid
Colour: Green
Odour: Product-specific
Data relevant to safety Method:
pH (original state): Approx. 5,5
11817 WUXAL Liquid AgNovaEG-Sida07_eng.doc / print: 2007-05-14
S A FE T Y D A T A S H E E T
according to EC Directive 2001/58/EC Date of issue: 23-08-2005
revised on: 14-05-2007
Page: 3 of 4
WUXAL庐 Liquid
Trade name:
Product-No.: 11817
pH at 10 g/l H2O and 20掳 C: Approx. 6,5
> 100o C evaporation of water
Change in physical state:
Boiling point/-range: Not determined 掳C
Melting point/-range: Not determined 掳C
Flash point: Not applicable 掳C
Inflammability: Not determined
Ignition temperature: Not determined 掳C
Self-ignition: The product is not spontaneously inflammable.
Fire-promotive properties: The product is not fire-promotive.
Explosion hazard: The product has no explosion hazardous properties.
Vapor pressure (at 掳
C): Not determined hPa
g/cm 3
Density (at 20掳 C): approx. 1,24
Solubility in water (at 20掳
C): To a very high degre e. mg/l
10 Stability and Reactivity
Conditions to avoid: Direct solar radiation, heat up and dry up.
Temperatures above +40掳 C.
Materials to avoid: Strong alcaline materials, as alkalis, calcinated lime, slaked lime, cement,
strong acid materials, as all acids, chlorate, chlorite, hypochloride, nitrite,
combustible materials, as coal dust, oil, fuel, organic peroxide, metal powder, grain,
paper, wood fiber, hay, straw, combustible packing materials.
Hazardous decomposition products: Reacts with alkalis setting ammonia free.
Thermic decomposition products: If larger quantities of the product are on fire, the formation of nitrous gases, ammonia,
sufuric acid gases and phosphoric acid gases is possible.
Further information: No decomposition if correctly used.
The product is stable under normal conditions.
11 Toxicological Information
Toxicological tests
Acute toxicity Toxicological data are not available.
Toxicological effects are unknown.
Property that must be anticipated on the basis with comparable preparations:
LD50 (oral, rat): >10.000 mg/kg
The following applies to ammonium nitrate: LD50 (oral, rat): 4820 mg/kg.
Further toxicological information
After inhalation of aerosols: Slight irritations of the mucous membranes and coughing.
After skin contact: Slight irritations.
After eye contact: Slight irritations.
After swallowing: Nausea and vomiting.
After uptake of large quantities: diarrhoea, disturbed electrolyte balance.
The following applies to nitrates in general:
methaemoglobinaemia after the uptake of large quantities.
Further data
Further hazardous properties cannot be excluded.
The product should be handled with the care usual when dealing with chemicals.
No toxicological effects are to be expected when the product is handled and used with due care and attention.
12 Ecological Information
General information: Fertilizer material.
Ensure that the product does not reach the ground-water, water bodies or the
drainage system.
Further ecologic data: Depending on the concentration, phosphorus and/or nitrogen compounds may
contribute to the eutrophication of drinking- water supplies.
The following applies to ammonium ions in general:
biological effects: fish: toxic as from 0.3 mg/l ;
animal nourishment for fish: toxic as from 0.3 mg/l .
No ecological problems are to be expected when the product is handled and used
with due care and attention.
Water pollution class: WGK 1 - slightly water polluting preparation (own classification)
13 Disposal Considerations
11817 WUXAL Liquid AgNovaEG-Sida07_eng.doc / print: 2007-05-14
S A FE T Y D A T A S H E E T
according to EC Directive 2001/58/EC Date of issue: 23-08-2005
revised on: 14-05-2007
Page: 4 of 4
WUXAL庐 Liquid
Trade name:
Product-No.: 11817
Product
Recommendation: Disposal of product rests in accordance with the official local disposal regulations.
According to european waste regulations:
Waste Code (EWC-No.): 061000
Waste Name: Wastes from the manufacture, formulation, supply and use of nitrogen chemicals,
nitrogen chemical processes and fertiliser manufacture.
Contaminated packaging
Recommendation: Disposal of contaminated packages in accordance with the local official disposal
regulations.
Cleaners: Water
14 Transport Information
Surface transport: No hazardous good.
River transport No hazardous good.
Sea navigation transport: No hazardous good.
Air transport: No hazardous good.
The transport regulations are cited according to international regulations and in the
Further information:
form applicable in Germany (GGVS/GGVE). Possible national deviations in other
countries are not considered.
15 Regulatory Information
Labelling according to EC Directives
Danger symbol and designation: No labelling duty according to the EC-Hazardous Materials Regulation.
contains R-phrases: None
contains S-phrases: None
National regulations Germany
Particular labelling of certain According to the Hazardous Materials Regulation (Germany):
preparations: 鈥濬ertilizer with ammonium nitrate, Group D鈥?
Employment limitations: None
Interference regulations: None
Classification according to VbF: None
Technical Regulations Air: None
Storage class according to
VCI-concept: 12 Liquid product with no fire risk.
Water pollution class: WGK 1 - slightly water polluting preparation (own classification)
Further regulations, limitations and
prohibition regulations: None
16 Other information
Relevant R-Phrases (Number and full text)
For section 2: R8 Contact with combustible material may cause fire.
R9 Explosive when mixed with combustible material.
Reason for alteration
General update.
Further information:
Data sheet writing department: Development Special Fertilizers
Contact persons: Peter Wehr Telephone: +49 (0)211 5064-241
Dr. Bernhard Kloth +49 (0)211 5064-262
The information contained herein is based on the present state of our knowledge. It
characterizes the product with regard to the appropriate safety precautions. It does not
represent a guarantee of the properties of the product.
11817 WUXAL Liquid AgNovaEG-Sida07_eng.doc / print: 2007-05-14
|