Commercial Food Equipment Service Association P_0000000399 D_0000000394
SAFETY-KLEEN 105 SOLVENT RECYCLED
MATERIAL SAFETY DATA SHEET FOR USA AND CANADA
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SAFETY-KLEEN 105 SOLVENT RECYCLED
SYNONYMS: Parts Washer Solvent; Petroleum Distillates; Petroleum Naptha;
Naptha, Solvent; Stoddard Solvent; Mineral Spirits.
PRODUCT PART
NUMBERS: 6614, 6617, 1011662, 1014662.
PRODUCT USE: Cleaning and degreasing metal parts.
If this product is used in combination with other products,
refer to the Material Safety Data Sheets for those
products.
24-HOUR EMERGENCY PHONE NUMBERS
These numbers are for MEDICAL: TRANSPORTATION (SPILL): emergency
use only. If you desire non-emergency 1-800-752-7869 1-800-468-1760
product information,
please call a phone
number listed below.
SUPPLIER: Safety-Kleen Systems, Inc.
5400 Legacy Drive
Cluster II, Building 3
Plano, Texas 75024
USA
1-800-669-5740
TECHNICAL INFORMATION: 1-800-669-5740, Press 1 then Extension 7500
MSDS FORM NUMBER: 82310 ISSUE: November 27, 2002
ORIGINAL ISSUE: April 8, 1976 SUPERSEDES: March 24, 2000
PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force
SAFETY-KLEEN 105
Revision 11/02; MSDS Form No. 82310 - Page 1 of 11
SOLVENT RECYCLED MATERIAL SAFETY DATA SHEET FOR
USA AND CANADA Revision 11/02; MSDS Form No. 82310 - Page 2 of 11
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL ACGIH TLV庐
WT% NAME SYNONYM CAS TWA STEL TWA STEL LD LC
NO.
99 to Distillates N.Av. 64742- ppm N.Av. 100d N.Av. >5000g, >5500d,
100 (petroleum), 47-8 ppm c h
hydrotreated lighte 500d mg/m3/4
hours
0 to 0.2* Tetrachloroethene Perchloroethylene; 127-18-4 100 200 25 100 2629a,f 34200b
Tetrachloroethylene ppm ppm ppm ppm mg/m3/8
(ceiling) hours
Commercial Food Equipment Service Association P_0000000399 D_0000000394
N.Av. = Not Available bInhalation-Rat LC50 eBased on Stoddard Solvent, NIOSH IDLH
*Even though the concentration range does cBased on Stoddard solvent: Skin-Rabbit (Immediately Dangerous to Life or Health):
not fall under the ranges prescribed by LD50 >3000 mg/kg 20000 mg/m3 (5000 ppm)
WHMIS, this is the actual range which dBased on Stoddard Solvent. fSkin-Rabbit LD50 >10000 mg/kg
varies with each batch of the product. gOral-Rat LD (mg/kg)
aOral-Rat LD50 (mg/kg) hInhalation-Rat LC
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
APPEARANCE
Liquid, clear and green, mild hydrocarbon odor.
WARNING!
PHYSICAL HAZARD
Combustible liquid and vapor.
HEALTH HAZARDS
May be harmful if inhaled.
May irritate eyes and skin.
May be harmful if swallowed.
Suspect cancer hazard. Contains material (less than 0.3 WT%) which may cause
cancer. Risk of cancer depends on duration and level of exposure.
Contains material which may cause birth defects.
Contains material which may cause central nervous system damage.
ENVIRONMENTAL HAZARDS
Toxic to aquatic life.
SAFETY-KLEEN 105 SOLVENT RECYCLED MATERIAL SAFETY
DATA SHEET FOR USA AND CANADA
POTENTIAL HEALTH EFFECTS
INHALATION High concentrations of vapor or mist may be harmful if inhaled.
High
(BREATHING): concentrations of vapor or mist may irritate the respiratory tract
(nose, throat, and lungs). High concentrations of vapor or mist
may cause nausea, vomiting, headaches, dizziness, loss of
coordination, numbness, and other central nervous system
effects. Massive acute overexposure may cause rapid central
nervous system depression, sudden collapse, coma, and/or
death.
EYES: May cause irritation with watering, stinging, and/or redness.
SKIN: May cause irritation. Not likely to be absorbed through the skin in harmful
amounts.
INGESTION May be harmful if swallowed. May cause throat irritation, nausea,
vomiting,
(SWALLOWING): and central nervous system effects as noted under
INHALATION
(BREATHING). Breathing product into the lungs during
ingestion or vomiting may cause lung injury and possible
death.
MEDICAL CONDITIONS Individuals with pre-existing respiratory tract (nose,
Commercial Food Equipment Service Association P_0000000399 D_0000000394
throat, and
AGGRAVATED BY lungs), central nervous system, eye, and/or skin disorders
may have
EXPOSURE: increased susceptibility to the effects of exposure.
CHRONIC: Prolonged or repeated inhalation may cause toxic effects as noted
under INHALATION (BREATHING). Prolonged or repeated
inhalation and/or ingestion has been suggested to produce
kidney toxicity in dogs but in no other species, including
humans. According to one unsubstantiated human case report,
prolonged or repeated inhalation, skin contact, and/or ingestion
may cause mild, acute chemical hepatitis and acute, yellow
atrophy (size reduction) of the liver. Prolonged or repeated eye
contact may cause inflammation of the membrane lining the
eyelids and covering the eyeball (conjunctivitis). Prolonged or
repeated skin contact may cause drying, cracking, redness,
itching, and/or swelling (dermatitis); and/or burns.
CANCER This product contains perchloroethylene which may cause cancer.
Risk of
INFORMATION: cancer depends on duration and level of exposure. For more
information,
see SECTION 11: CARCINOGENICITY.
Also see SECTION 15: CALIFORNIA.
POTENTIAL ENVIRONMENTAL EFFECTS
Product is toxic to aquatic life. Also see SECTION 12: ECOLOGICAL
INFORMATION.
SAFETY-KLEEN 105
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SOLVENT RECYCLED MATERIAL SAFETY DATA SHEET FOR
USA AND CANADA Revision 11/02; MSDS Form No. 82310 - Page 4 of 11
SECTION 4: FIRST AID MEASURES
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If
breathing
(BREATHING) is difficult, give oxygen. Oxygen should only be administered by
qualified personnel. Someone should stay with victim. Get
medical attention if breathing difficulty persists.
EYES: If irritation or redness from exposure to vapor develops, move away from
exposure into fresh air. Upon contact, immediately flus h
eyes with plenty of lukewarm water, holding eyelids apart, for
15 minutes. Get medical attention.
SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and
water. Get medical attention if irritation or pain develops or
persists.
INGESTION: Do NOT induce vomiting. Immediately get medical attention. Call
(SWALLOWING) 1-800-752-7869 for additional information.
If spontaneous vomiting occurs, keep head below hips to
avoid breathing the product into the lungs. Never give
anything to an unconscious person by mouth.
Commercial Food Equipment Service Association P_0000000399 D_0000000394
NOTE TO Treat symptomatically and supportively. Administration of gastric
lavage,
PHYSICIANS: if warranted, should be performed by qualified medical personnel.
Treatment may vary with condition of victim and specifics of
incident. Call 1-800-752-7869 for additional information.
SECTION 5: FIRE FIGHTING MEASURES
FLASH POINT: 105掳F (40掳C) (minimum) Tag Closed Cup
FLAMMABLE LIMITS IN AIR: LOWER: 0.7 VOL% (minimum)
UPPER: 5 VOL% (maximum)
AUTOIGNITION
TEMPERATURE: 410掳F (210掳C) (minimum)
HAZARDOUS COMBUSTION Decomposition and combustion materials may be
toxic.
PRODUCTS: Burning may produce carbon monoxide and unidentified
organic compounds.
CONDITIONS OF
FLAMMABILITY: Heat, sparks, or flame.
EXTINGUISHING MEDIA: Carbon dioxide, regular foam, dry chemical, water
spray, or water fog.
SAFETY-KLEEN 105 SOLVENT RECYCLED MATERIAL SAFETY
DATA SHEET FOR USA AND CANADA
NFPA 704
HAZARD This information is intended solely for the use by individuals
IDENTIFICATION: trained in this system.
FIRE FIGHTING Keep storage containers cool with water spray.
INSTRUCTIONS: A positive-pressure, self-contained breathing apparatus
(SCBA) and full-body protective equipment are
required for fire emergencies.
FIRE AND Vapor explosion ha zard indoors, outdoors, or in sewers.
EXPLOSION HAZARDS: Vapors may travel to ignition source and flashback.
Vapors will spread along the ground and
collect in low or confined areas. Run-off to
sewer may create a fire hazard. Heated
containers may rupture. 鈥淓mpty鈥? containers
may retain residue and can be dangerous. Not
sensitive to mechanical impact. Product may
be sensitive to static discharge, which could
result in fire or explosion.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Remove all ignition sources. Do not touch or walk through spilled product. Stop
leak if you can do it without risk. Wear protective equipment and provide
engineering controls as specified in SECTION 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep
unnecessary and unprotected personnel from entering. Ventilate area and avoid
breathing vapor or mist. A vapor suppressing foam may be used to reduce
vapors. Contain spill away from surface waters and sewers. Contain spill as a
Commercial Food Equipment Service Association P_0000000399 D_0000000394
liquid for possible recovery or sorb with compatible sorbent material and shovel
with a clean, sparkproof tool into a sealable container for disposal.
Additionally, for large spills: Water spray may reduce vapor, but may not prevent
ignition in closed spaces. Dike far ahead of liquid spill for collection and later
disposal.
There may be specific federal regulatory reporting requirements associated with
spills, leaks, or releases of this product. Also see SECTION 15: REGULATORY
INFORMATION.
SAFETY-KLEEN 105
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SOLVENT RECYCLED MATERIAL SAFETY DATA SHEET FOR
USA AND CANADA Revision 11/02; MSDS Form No. 82310 - Page 6 of 11
SECTION 7: HANDLING AND STORAGE
HANDLING: Keep away from heat, sparks, or flame. Where flammable mixtures
may be present, equipment safe for such locations should be
used. Use clean, sparkproof tools and explosion-proof
equipment. When transferring product, metal containers,
including trucks and tank cars, should be grounded and
bonded. Do not breathe vapor or mist. Use in a well
ventilated area. Avoid contact with eyes, skin, clothing, and
shoes. Do not smoke while using this product.
SHIPPING AND Keep container tightly closed when not in use and during
transport. Do not
STORING: pressurize, cut, weld, braze, solder, drill, or grind containers. Keep
containers away from heat, flame, sparks, static electricity,
or other sources of ignition. Empty product containers may
retain product residue and can be dangerous. See SECTION
14: TRANSPORT INFORMATION for Packing Group
information.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING Provide general ventilation needed to maintain concentration of
vapor or
CONTROLS: mist below applicable e xposure limits. Where adequate general
ventilation is unavailable, use process enclosures, local
exhaust ventilation, or other engineering controls to control
airborne levels below recommended exposure limits. Where
explosive mixtures may be present, equipment safe for such
locations should be used.
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY Use NIOSH-certified, air-purifying respirators with organic vapor
cartridges
PROTECTION: respiratory protective equipment when concentration of vapor or
mist exceeds applicable exposure limits. Protection provided
by air-purifying respirators is limited. Selection and use of
respiratory protective equipment should be in accordance in
the USA with OSHA General Industry Standard 29 CFR
1910.134; or in Canada with CSA Standard Z94.4.
Commercial Food Equipment Service Association P_0000000399 D_0000000394
EYE Where eye contact is likely, wear chemical goggles; contact lens use
PROTECTION: is not recommended.
SKIN Where skin contact is likely, wear nitrile, supported neoprene, Viton庐,
PROTECTION: polyvinyl alcohol (PVA), laminate (such as North Silver Shield庐,
Safety 4 4h庐, Ansell Edmont Barrier庐), or equivalent
protective gloves; use of polyvinyl chloride (PVC), natural
rubber (latex), or equivalent gloves is not recommended.
SAFETY-KLEEN 105 SOLVENT RECYCLED MATERIAL SAFETY
DATA SHEET FOR USA AND CANADA
To avoid prolonged or repeated contact where spills and splashes are likely,
wear appropriate chemical-resistant faceshield, boots,
apron, whole body suits, or other protective clothing.
PERSONAL Use good personal hygiene. Wash thoroughly with soap and water
HYGIENE: after handling product and before eating, drinking, or using tobacco
products. Clean affected clothing, shoes, and protective
equipment before reuse. Discard affected clothing, shoes, or
protective equipment if they cannot be thoroughly cleaned.
Discard leather articles, such as shoes, saturated with the
product.
OTHER Where spills and splashes are likely, facilities storing or using this
product
PROTECTIVE should be equipped with an emergency eyewash and shower,
both
EQUIPMENT: equipped with clean water, in the immediate work area.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE,
APPEARANCE, AND ODOR: Liquid, clear and green, mild hydrocarbon odor.
ODOR THRESHOLD: 30 ppm (based on Stoddard Solvent)
MOLECULAR WEIGHT: Not available.
SPECIFIC GRAVITY: 0.77 to 0.80 at 60掳F/60掳F (15.6掳C/15.6掳C) (water = 1)
DENSITY: 6.4 to 6.7 LB/US gal (770 to 800 g/l)
VAPOR DENSITY: 5 (air = 1) (approximately)
VAPOR PRESSURE: 0.4 mm Hg at 68掳F (20掳C) (approximately)
1.0 mm Hg at 100掳F (38掳C) (approximately)
BOILING POINT: 310掳F (155掳C) (initial)
FREEZING/MELTING POINT: -45掳F (-43掳C) (maximum)
pH: Not applicable.
EVAPORATION RATE: 0.1 (butyl acetate = 1) (based on Stoddard Solvent)
SOLUBILITY IN WATER: Insoluble.
FLASH POINT: 105掳F (40掳C) (minimum) Tag Closed Cup
SAFETY-KLEEN 105
Revision 11/02; MSDS Form No. 82310 - Page 7 of 11
SOLVENT RECYCLED MATERIAL SAFETY DATA SHEET FOR
USA AND CANADA
FLAMMABLE LIMITS IN AIR: LOWER: 0.7 VOL% (minimum)
UPPER: 5 VOL% (maximum)
AUTOIGNITION
Commercial Food Equipment Service Association P_0000000399 D_0000000394
TEMPERATURE: 410掳F (210掳C) (minimum)
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable under normal temperatures and pressures. Avoid heat,
sparks, or flame.
INCOMPATIBILITY: Avoid acids, alkalies, oxidizing agents, reducing agents,
reactive halogens, or reactive metals.
REACTIVITY: Polymerization is not known to occur under normal temperatures
and pressures. Not reactive with water.
HAZARDOUS
DECOMPOSITION None under normal temperatures and pressures. See
PRODUCTS: also SECTION 5: HAZARDOUS COMBUSTION PRODUCTS.
SECTION 11: TOXICOLOGICAL INFORMATION
SENSITIZATION: Based on best current information, there is no known human
sensitization associated with this product.
MUTAGENICITY: Perchloroethylene has demonstrated animal effects of
mutagenicity.
Based on best current information, the other component
listed in SECTION 2 is not a mutagen.
CARCINOGENICITY: Perchloroethylene is categorized by IARC as probably
carcinogenic to humans (Group 2A). Perchloroethylene is
listed by NTP as having limited evidence of
carcinogenicity in humans or sufficient evidence of
carcinogenicity in experimental animals.
Perchloroethylene is categorized by ACGIH as a
confirmed animal carcinogen with unknown relevance to
humans (A3). This agent is carcinogenic in experimental
animals at a relatively high dose, by route(s) of
administration, at site(s), of histologic type(s), or by
mechanism(s) that may not be relevant to worker
exposure. Available epidemiologic studies do not confirm
an increased risk of cancer in exposed humans. Available
evidence does not suggest that the agent is likely to
cause cancer in humans except under uncommon or
unlikely routes or levels of exposure.
SAFETY-KLEEN 105
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SOLVENT RECYCLED MATERIAL SAFETY DATA SHEET FOR
USA AND CANADA
Based on best current information, the other component
listed in SECTION 2 is not a carcinogen.
Also see SECTION 3: CANCER INFORMATION and
SECTION 15: CALIFORNIA.
REPRODUCTIVE Based on best current information, there is no known
reproductive
TOXICITY: toxicity associated with this product.
Also see SECTION 15: CALIFORNIA.
TERATOGENICITY: Perchloroethylene has demonstrated animal effects of
Commercial Food Equipment Service Association P_0000000399 D_0000000394
teratogenicity.
Based on best current information, the other component
listed in
SECTION 2 is not a teratogen.
TOXICOLOGICALLY Based on best current information, there are no known
SYNERGISTIC toxicologically synergistic products associated with this
PRODUCT(S): product.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICITY: 2900 ug/L 96 hour LC50 Rainbow trout, donaldson trout
(Oncorhynchus mykiss) (based on Distillates
(petroleum) hydrotreated light).
OCTANOL/WATER
PARTITION COEFFICIENT: Not available.
VOLATILE ORGANIC 100 WT%; 6.4 to 6.7 LB/US gal; 770 to 800 g/l
COMPOUNDS: As per 40 CFR Part 51.100(s).
SECTION 13: DISPOSAL CONSIDERATIONS
DISPOSAL: Dispose in accordance with federal, state, provincial, and local
regulations. Regulations may also apply to empty containers.
The responsibility for proper waste disposal lies with the
owner of the waste. Contact Safety-Kleen regarding
recycling or proper disposal.
USEPA WASTE D001, D018, D039, and D040
CODE(S): Based on available data, this information applies to the product as
supplied to the user. Processing, use, or contamination by
the user may change the waste code(s) applicable to the
disposal of this product.
SAFETY-KLEEN 105
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SOLVENT RECYCLED MATERIAL SAFETY DATA SHEET FOR
USA AND CANADA Revision 11/02; MSDS Form No. 82310 - Page 10 of 11
SECTION 14: TRANSPORT INFORMATION
DOT: COMBUSTIBLE LIQUID, N.O.S. (PETROLEUM NAPHTHA),
NA1993, PG III
TDG: Petroleum Distillates, N.O.S., Class 3, UN1268, PG III
EMERGENCY RESPONSE 128
GUIDE NUMBER: Reference North American Emergency Response Guidebook
SECTION 15: REGULATORY INFORMATION
USA REGULATIONS
SARA SECTIONS Based on the ingredients listed in SECTION 2, this product
does not
302 AND 304: contain any 鈥渆xtremely hazardous substances鈥? listed pursuant to
Title III of the Superfund Amendments and
Reauthorization Act of 1986 (SARA) Section 302 or
Section 304 as identified in 40 CFR Part 355, Appendix A
and B.
SARA SECTIONS This product poses the following physical and health hazards
as
Commercial Food Equipment Service Association P_0000000399 D_0000000394
311 AND 312: defined in 40 CFR Part 370 and is subject to the requirements of
sections 311 and 312 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 (SARA):
Immediate (Acute) Health Hazard
Delayed (Chronic) Health Hazard
Fire Hazard
SARA SECTION The following component is subject to the requirements of
313: section 313 of Title III of the Superfund Amendments and Reauthorization
Act of 1986 (SARA) and 40 CFR Part 372.
Material CAS
Perchloroethylene 127-18-4
CERCLA: Based on the ingredients listed in SECTION 2, this product contains
the
following 鈥渉azardous substance鈥? listed under the
Comprehensive Environmental Response, Compensation
and Liability Act of 1980 (CERCLA) in 40 CFR Part 302,
Table 302.4 with the following reportable quantity (RQ):
Material CAS RQ
Perchloroethylen 127-18-4 100 LB (15.4 kg)
e
TSCA: All the components of this product are listed on the TSCA Inventory.
SAFETY-KLEEN 105 SOLVENT RECYCLED MATERIAL SAFETY
DATA SHEET FOR USA AND CANADA
CALIFORNIA: This product may contain detectable amounts of benzene CAS
71-43-2, p-dichlorobenzene CAS 106-46-7, methylene
chloride CAS 75-09-2, perchloroethylene CAS 127-18-4,
and trichloroethylene CAS 79-01-6. WARNING: These
chemicals are known to the State of California to cause
cancer.
This product may contain detectable amounts of benzene
CAS 71-43-2 and toluene CAS 108-88-3. WARNING:
These chemicals are known to the State of California to
cause birth defects or other reproductive harm.
CANADIAN REGULATIONS
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all the
information required by the CPR.
WHMIS: B3, D2A, D2B
CANADIAN
ENVIRONMENTAL
PROTECTION ACT All the components of this product are listed on
(CEPA): the Canadian Domestic Substances List (DSL).
SECTION 16: OTHER INFORMATION
REVISION INFORMATION: Updated with Safety-Kleen Texas address, modified
Commercial Food Equipment Service Association P_0000000399 D_0000000394
Medical Emergency phone number,
modification to Transportation Spill number,
and modification of Technical Information
phone number.
LABEL/OTHER INFORMATION: This product is United States Department of
Agriculture (USDA) approved, Underwriter鈥檚
Laboratories (UL) classified, and Factory
Mutual (FM) approved.
User assumes all risks incident to the use of this product. To the best of our knowledge, the information contained herein
is accurate. However, Safety-Kleen assumes no liability whatsoever for the accuracy or completeness of the information
contained herein. No representations or warranties, either express or implied, or merchantability, fitness for a particular
purpose or of any other nature are made hereunder with respect to information or the product to which information refers.
The data contained on this sheet apply to the product as supplied to the user.
脝脡2000 Printed in the USA.
Revision 11/02; MSDS Form No. 82310 - Page 11 of 11
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