Material Safety Data Sheet
Rating
NFPA HMIS (U.S.A.) Protective Clothing DOT (pictograms)
Health Hazard 1 0 Insignificant
Fire Hazard
1
Fire Hazard 1 Slight
1
1 0 2 Moderate
Reactivity Reactivity 0
Health
3 High
Personal Protection 4 Extreme
B
Specific hazard
Section I. Chemical Product and Company Identification
490-028-1; XSULSRF
Product Name Code
SULLAIR SRF 1/4000
On the DSL.
DSL
None.
Synonym On TSCA inventory list.
TSCA
PETRO-CANADA Petro-Canada: 403-296-3000
Manufacturer In case of
P.O. Box 2844 Emergency Canutec Transportation:
Calgary, Alberta T2P 3E3 613-996-6666
Poison Control Centre: Consult
This product is used for the lubrication of air and inert gas compressors of the
Material Uses
local telephone directory for
reciprocating, rotary screw, and rotary vane types. This compressor oil should
emergency number(s).
NEVER be used in equipment compressing pure oxygen.
Section II. Composition and Information on Ingredients
Exposure Limits (ACGIH)
Name CAS # % (Wt) TLV-TWA(8 h) STEL CEILING
Severely hydrotreated paraffinic oil and additives Mixture 100 5 mg/m鲁 (oil mist) 10 mg/m鲁 (oil Not applicable
mist)
8-hour TLV-TWA of 5 mg/m鲁 recommended by manufacturer based on ACGIH TLV for oil mists. Consult local authorities for
Manufacturer
acceptable exposure limits.
Recommendation
Consult local, state, provincial or territory authorities for acceptable exposure limits.
Other Exposure Limits
Section III. Hazards Identification.
Non irritating to slight transient irritation to skin and eyes, but no permanent damage. Relatively non-toxic via ingestion. This
Potential Health
product has a low vapour pressure and is not expected to present an inhalation exposure at ambient conditions. Upon heating to
Effects
high temperatures, or mechanical actions which may produce vapours or mists, inhalation of product may cause irritation of the
breathing passages. For more information, refer to Section 11.
Section IV. First Aid Measures
Check for and remove any contact lenses. IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids
Eye Contact
open. Seek medical attention if irritation persists.
Remove contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin with running water and
Skin Contact
non-abrasive soap. Get medical attention if redness or irritation occurs.
Evacuate the victim to a safe area as soon as possible. Allow the victim to rest in a well ventilated area. Administer oxygen if
Inhalation
available. If the victim is not breathing, perform mouth-to-mouth resuscitation. If resuscitation is required, physician assessment
mandatory.
DO NOT induce vomiting because of danger of aspirating liquid into lungs. Has laxative effect - rapidly eliminated. Physician
Ingestion
assessment advised.
No additional remark.
Note to Physician
Section V. Fire-fighting Measures
Combustible liquid. Not available.
Flammability Flammable Limits
OPEN CUP: >200掳C (392掳F). (Cleveland.). Fire Point: 246掳C (474.8掳F)
Flash Points Auto-Ignition
Temperature
Low fire hazard. Must be moderately heated before Explosion Hazards Do not cut, weld, heat, drill or pressurize empty
Fire Hazards in
ignition will occur. Avoid contact with strong oxidizing in Presence of container. Containers may explode in heat of fire.
Presence of
agents, including peroxides, chlorine and strong Various Substances
Various Substances
acids.
Products of Combustion Carbon oxides (CO, CO2), nitrogen oxides (NOx), phosphorus compounds (POx), smoke and irritating vapours as products of
incomplete combustion.
NAERG96, GUIDE 171, Substances (low to moderate hazard). If tank, rail car or tank truck is involved in a fire, ISOLATE for 800
Fire Fighting
meters (0.5 mile) in all directions; also, consider initial evacuation for 800 meters (0.5 mile) in all directions. Shut off fuel to fire if it is
Media and
possible to do so without hazard. If this is impossible, withdraw from area and let fire burn out under controlled conditions.
Instructions
Withdraw immediately in case of rising sound from venting safety device or any discolouration of tank due to fire. Cool containing
vessels with water spray in order to prevent pressure build-up, autoignition or explosion. SMALL FIRE: use DRY chemicals, foam,
water spray or CO2. LARGE FIRE: use water spray, fog or foam. For small outdoor fires, portable fire extinguishers may be used,
and self contained breathing apparatus (SCBA) may not be required. For all indoor fires and any significant outdoor fires, SCBA is
required. Respiratory and eye protection are required for fire fighting personnel.
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SULLAIR SRF 1/4000 Page Number: 2
Section VI. Accidental Release Measures
NAERG96, GUIDE 171, Substances (low to moderate hazard). ELIMINATE ALL IGNITION SOURCES. Avoid contact. Stop leak if
Material Release
without risk. Contain spill. Absorb with inert absorbents, dry clay, or diatomaceous earth. Avoid inhaling dust of diatomaceous earth
or Spill
for it may contain silica in very fine particle size, making this a potential respiratory hazard. Place used absorbent in closed metal
containers for later disposal or burn absorbent in a suitable combustion chamber. DO NOT FLUSH TO SEWERS, STREAMS OR
OTHER BODIES OF WATER. Check with applicable jurisdiction for specific disposal requirements of spilled material and empty
containers. Notify the appropriate authorities immediately.
Section VII. Handling and Storage
Keep away from sources of ignition. DO NOT reuse empty containers without commercial cleaning or reconditioning. Practice good
Handling
personal hygiene. Wash hands after handling and before eating. Launder work clothes frequently. Discard saturated leather goods.
Store in tightly closed containers in cool, dry, isolated, well-ventilated area, and away from strong oxidizing agents.
Storage
Section VIII. Exposure Controls/Personal Protection
For normal application, special ventilation is not necessary. If user's operations generate vapours or mist, use ventilation to keep
Engineering Controls
exposure to airborne contaminants below the exposure limit. Make-up air should always be supplied to balance air removed by
exhaust ventilation. Ensure that eyewash station and safety shower are close to work-station.
Personal Protection
Eyes Safety glasses or chemical splash goggles in case of splashing.
Body Wear long sleeved clothing to minimize skin contact.
Respiratory No special respiratory protection is normally required. If mist generated by heating, spraying, etc., wear an organic vapour respirator
with a mist filter. All respirators must be NIOSH approved.
Hands For casual contact, PVC gloves are suitable. For direct contact for more than 2 hours, NEOPRENE or NITRILE gloves are
recommended.
Feet Safety boots or shoes.
Section IX. Physical and Chemical Properties
Viscous liquid. 30-40 cSt @ 40掳C, 6.2 cSt @ 100掳C, VI=108.
Physical State and Viscosity
Appearance
Pale yellow. <-30潞C (-22潞F).
Colour Pour Point
Mild petroleum oil like. Copper corrosion, 3h, 100掳C (ASTM D0130): 1a.
Odour Softening Point
Not available. Not available.
Odour Threshold Dropping Point
349掳C (660.2掳F) Not available.
Boiling Point Penetration
0.8614 kg/L @ 15掳C (59掳F). Not available.
Specific Gravity Oil / Water Dist. Coeff.
Not available. Insoluble in water.
Vapour Density Ionicity (in water)
0.0075 mmHg @ 20掳C (68潞F). Nonvolatile and immobile.
Vapour Pressure Dispersion Properties
Non-volatile. Insoluble in cold water, soluble in non-polar
Volatility Solubility
hydrocarbon solvents.
Section X. Stability and Reactivity
Copper corrosion, 3h, 100掳C (ASTM D0130): 1a.
Corrosivity
The product is stable under normal handling and Hazardous Will not occur under normal working conditions.
Stability
storage conditions. Polymerization
Incompatible Substances Reactive with oxidizing agents, acids, alkalis. May release COx, NOx, POx, methacrylate monomers,
Decomposition
smoke and irritating vapours when heated to
/ Conditions to Avoid Products
decomposition.
Section XI. Toxicological Information
Skin contact, eye contact, inhalation and ingestion.
Routes of Entry
Based on toxicity of components. Acute oral toxicity (LD50): >5000 mg/kg (rat). Acute dermal toxicity (LD50): >2000
Acute Lethality
mg/kg (rabbit).
Chronic or Other Toxic Effects
Prolonged or repeated contact may cause skin irritation characterized by dermatitis or oil acne.
Dermal Route:
Due to the low volatility of the product, inhalation is not likely. However, prolonged or repeated inhalation of excessive
Inhalation Route:
amount of mists or vapours may cause irritation of the respiratory tract. Oil deposits in the lung may lead to fibrosis and
reduced pulmonary function.
Low toxicity; has laxative effect.
Oral Route:
Repeated or prolonged contact may produce eye irritation, but no permanent damage.
Eye Irritation/Inflammation:
Not available.
Immunotoxicity:
Based on toxicity of severely hydrotreated base oil, it is not a skin sensitizer in guinea pig.
Skin Sensitization:
This product is not expected to be a respiratory tract sensitizer.
Respiratory Tract Sensitization:
Based on actual test results of base oils and results of similar products, severely hydrotreated base oils give negative
Mutagenic:
results when tested for: (a) Salmonella Typhimurium TA98 using the Modified Ames Assay for Petroleum Product; (b)
Salmonella-Escherichia coli/Mammalian-Microsome Reverse Mutation Assay (Ames test) with a Confirmatory Assay; (c)
Structural Chromosomal Aberrations in Chinese Hamster Ovary (CHO) Cells.
Based on the available animal data, severely hydrotreated base oils do not pose a reproductive risk.
Reproductive Toxicity:
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SULLAIR SRF 1/4000 Page Number: 3
Based on the available animal data, severely hydrotreated base oils do not pose a developmental or reproductive risk.
Teratogenicity/Embryotoxicity:
Based on the available human studies, exposure to oil mist alone has not been demonstrated to cause human health
Carcinogenicity (ACGIH):
effects at levels below 5 mg/m鲁. It is anticipated that this level minimize the potential for skin and respiratory tract
irritation.
This product is not known to contain any chemicals at reportable quantities that are listed as A1 or A2 carcinogens by
ACGIH.
This product is not known to contain any chemicals at reportable quantities that are listed as group 1, 2A or 2B
Carcinogenicity (IARC):
carcinogens by IARC.
This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by NTP.
Carcinogenicity (NTP):
Not available.
Carcinogenicity (IRIS):
OSHA PEL (8-hour TWA) = 5 mg/m鲁 for mineral oil mists. This product is not known to contain any chemicals at
Carcinogenicity (OSHA):
reportable quantities that are listed as carcinogens by OSHA.
No additional remark.
Other Considerations
Section XII. Ecological Information
The product has the potential for degradation by Not available
Environmental Fate Persistance/
hydroxyl radicals in the troposphere under the Bioaccumulation
influence of sunlight, and by bacteria in soil or Potential
water.
Not available. Not available.
BOD5 and COD Products of
Biodegradation
No additional remark.
Additional Remarks
Section XIII. Disposal Considerations
Spent/used/waste oil may meet the requirements of a hazardous waste. Consult your local or regional authorities. Preferred waste
Waste Disposal
management priorities are: (1) recycle or reprocess; (2) incineration with energy recovery; (3) disposal at licensed waste disposal
facility. Ensure that disposal or reprocessing is in compliance with government requirements and local disposal regulations.
Section XIV. Transport Information
Not a DOT controlled material in USA. Not regulated
DOT Classification Special Provisions
for Transport
Section XV. Regulatory Information
CEPA: This product is acceptable for use under the provisions of WHMIS-CPR. All components of this formulation are listed on
Other
DSL.
Regulations
USEPA: All components of this formulation are listed on TSCA Inventory.
EU: All components of this formulation are listed on EINECS. Not listed as hazardous chemical in CHIP96-Approved Supply List
(67/548/EEC). Not classified as R65 - Aspiration hazard, by the 22nd ATP (Adaptation to Technical Progress) of the European
DSD.
Please contact Product Safety for more information.
Not classified under the Dangerous Substances or WHMIS (Canada) Not controlled
DSD/DPD (EEC)
Dangerous Preparations Directives.
ADR (Europe) TDG (Canada)
(Pictograms) (Pictograms)
Section XVI. Other Information
Available upon request.
References
Glossary
ACGIH - American Conference of Governmental Industrial Hygienists IRIS - Integrated Risk Information System
ADR - Agreement on Dangerous goods by Road (Europe) LD50/LC50 - Lethal Dose/Concentration kill 50%
ASTM - American Society for Testing and Materials ( LDLo/LCLo - Lowest Published Lethal Dose/Concentration
BOD5 - Biological Oxygen Demand in 5 days NAERG'96 - North American Emergency Response Guide Book (1996)
CAN/CGA B149.2 Propane Installation Code NFPA - National Fire Prevention Association
CAS - Chemical Abstract Services NIOSH - National Institute for Occupational Safety & Health
CEPA - Canadian Environmental Protection Act NPRI - National Pollutant Release Inventory
CERCLA - Comprehensive Environmental Response, Compensation and Liability NSNR - New Substances Notification Regulations (Canada)
Act NTP - National Toxicology Program
CFR - Code of Federal Regulations OSHA - Occupational Safety & Health Administration
CHIP - Chemicals Hazard Information and Packaging Approved Supply List PEL - Permissible Exposure Limit
COD5 - Chemical Oxygen Demand in 5 days RCRA - Resource Conservation and Recovery Act
CPR - Controlled Products Regulations SARA - Superfund Amendments and Reorganization Act
DOT - Department of Transport SD - Single Dose
DSCL - Dangerous Substances Classification and Labeling (Europe) STEL - Short Term Exposure Limit (15 minutes)
DSD/DPD - Dangerous Substances or Dangerous Preparations Directives TDG - Transportation Dangerous Goods (Canada)
(Europe) TDLo/TCLo - Lowest Published Toxic Dose/Concentration
DSL - Domestic Substance List TLm - Median Tolerance Limit
EEC/EU - European Economic Community/European Union TLV-TWA - Threshold Limit Value-Time Weighted Average
EINECS - European Inventory of Existing Commercial Chemical Substances TSCA - Toxic Substances Control Act
EPCRA - Emergency Planning and Community Right to Know Act USEPA - United States Environmental Protection Agency
FDA - Food and Drug Administration USP - United States Pharmacopoeia
FIFRA - Federal Insecticide, Fungicide and Rodenticide Act WHMIS - Workplace Hazardous Material Information System
Continued on Next Page Available in French
SULLAIR SRF 1/4000 Page Number: 4
HCS - Hazardous Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
Information Contact Western Canada, telephone: 1-800-661-1199; fax: (780) Prepared by Product Safety - TAR on 01/17/2000.
464-9564 Data entry by Product Safety - TAR.
Ontario & Central Canada, telephone: 1-800-268-5850
and (905) 822-4222; fax: 1-800-201-6285
Quebec & Eastern Canada, telephone: 1-800-576-1686;
fax: 800-201-6285
For Product Safety Information: (905) 804-4752
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user.
All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
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