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MATERIAL SAFETY DATA SHEET Sales Order: {SalesOrd}
MSDS Revision No: E3 -5
BRIGHTSIDE SAPPHIRE BLUE MSDS Revision Date: 11/05/2002
EMERGENCY NUMBERS:
(800) 424-9300 CHEMTREC (USA)
International Paint Inc.
(703) 527-3887 CHEMTREC (Intl)
(800) 854-6813 Poison Control Center
6001 Antoine Drive
CUSTOMER SERVICE: (Non-Emergency)
(800) 589-1267 International Paint
Houston, Texas 77091 (800) 631-7481 Interlux
1. GENERAL INFORMATION
Product Identity: BRIGHTSIDE SAPPHIRE BLUE
Bulk Sales Reference No:Y4241
IMPORTANT: Read this MSDS before handling or disposing of this product, and provide this information to the
employee, customers, and users of this product. PLEASE NOTE THE MSDS REVISION NUMBER AT THE TOP OF THIS
PAGE. If the MSDS Revision Number posted at the top of this page does not match the MSDS Revision Number on the
product label, please contact Customer Service at the phone number included above for the correct MSDS. This product
is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard.
2. HAZARDOUS INGREDIENT INFORMATION
CAS No. Ingredient Name & % Source Exposure Data
OSHA: 500 ppm TWA; 2900 mg/m3 TWA
ACGIH: 100 ppm TWA
NIOSH: 350 mg/m3 TWA1800 mg/m3 Ceiling20,000 mg/m3 IDLH
Supplier: No Data Available
OHSA,
525 mg/m3 TWAEV (140 Degree C Flash Aliphatic Solvent)
CAN:
100 ppm TWA; 523 mg/m3 TWA200 ppm STEL; 1050 mg/m3
Mexico:
STEL
Stoddard solvent
008052-41-3 Brazil: No Data Available
10 - 25% by Weight
Health Data
Source
NIOSH: Eye nose
Carcinogen Data
Source
OSHA: Select Carcinogen: No
NTP: Known Carcinogen: No; Suspected Carcinogen: No
Group 1: No; Group 2A: No;
IARC:
Group 2b: No; Group 3: No; Group 4: No
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CAS No. Ingredient Name & % Source Exposure Data
OSHA: 15 mg/m3 TWA (total dust)
ACGIH: 10 mg/m3 TWA
NIOSH Potential Occupational Carcinogen - see Appendix
NIOSH:
APotential NIOSH carcinogen.
Supplier: No Data Available
OHSA,
10 mg/m3 TWAEV (total dust)
CAN:
Mexico: 10 mg/m3 TWA (nuisance particulate)20 mg/m3 STEL
Titanium dioxide
013463-67-7 Brazil: No Data Available
1.0 - 10% by Weight
Health Data
Source
NIOSH: Lung tumors in animals
Carcinogen Data
Source
OSHA: Select Carcinogen: No
NTP: Known Carcinogen: No; Suspected Carcinogen: No
Group 1: No; Group 2A: No;
IARC:
Group 2b: No; Group 3: Yes; Group 4: No
CAS No. Ingredient Name & % Source Exposure Data
OSHA: No Data Available
ACGIH: No Data Available
NIOSH: No Data Available
Supplier: No Data Available
OHSA,
No Data Available
CAN:
Mexico: No Data Available
Petroleum distillates,
Brazil: No Data Available
hydrotreated light
064742-47-8
1.0 - 10% by Weight Health Data
Source
NIOSH: No Data Available
Carcinogen Data
Source
OSHA: Select Carcinogen: No
NTP: Known Carcinogen: No; Suspected Carcinogen: No
Group 1: No; Group 2A: No;
IARC:
Group 2b: No; Group 3: No; Group 4: No
CAS No. Ingredient Name & % Source Exposure Data
OSHA: No Data Available
ACGIH: No Data Available
NIOSH: No Data Available
Supplier: No Data Available
OHSA,
No Data Available
CAN:
Mexico: No Data Available
Solvent naphtha (petroleum),
Brazil: No Data Available
064742-88-7 medium aliphatic
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p
064742 88 7
10 - 25% by Weight Health Data
Source
NIOSH: No Data Available
Carcinogen Data
Source
OSHA: Select Carcinogen: No
NTP: Known Carcinogen: No; Suspected Carcinogen: No
Group 1: No; Group 2A: No;
IARC:
Group 2b: No; Group 3: No; Group 4: No
CAS No. Ingredient Name & % Source Exposure Data
OSHA: No Data Available
ACGIH: No Data Available
NIOSH: No Data Available
Supplier: No Data Available
OHSA,
No Data Available
CAN:
Mexico: No Data Available
Naphtha (petroleum), heavy
Brazil: No Data Available
064742-94-5 aromatic
1.0 - 10% by Weight Health Data
Source
NIOSH: No Data Available
Carcinogen Data
Source
OSHA: Select Carcinogen: No
NTP: Known Carcinogen: No; Suspected Carcinogen: No
Group 1: No; Group 2A: No;
IARC:
Group 2b: No; Group 3: No; Group 4: No
3. HAZARD IDENTIFICATION
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents
with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating
Overview:
and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing.
Harmful if inhaled. Causes nose and throat irritation. Vapors may affect the brain or nervous system
Inhalation: causing dizziness, headache or nausea.
Causes severe eye irritation. Do not get in eyes.
Eyes:
Causes skin irritation. May be harmful if absorbed through the skin.
Skin:
Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness.
Ingestion:
Contains an ingredient which can cause organ damage (See Section 2 and Section 15 for each
ingredient). Possible cancer hazard. Contains an ingredient which may cause cancer based on animal
Chronic Effects: data (See Section 2 and Section 15 for each ingredient). Risk of cancer depends on duration and level
of exposure.
HMIS Rating: Health: Unknown Flammability: Unknown Reactivity: Unknown
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4. FIRST AID MEASURES
Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before
General: reuse. Thoroughly clean or destroy contaminated shoes.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
Inhalation: oxygen. Get medical attention immediately.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
Eyes: attention immediately.
In case of contact, immediately flush skin with soap and plenty of water. Get medical attention
Skin: immediately.
If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting
unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious
Ingestion:
person.
5. PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Select equipment to provide protection from the ingredients listed in Section 2 of this document.
Ensure fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M
Respiratory: RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health
and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in
Canada call 1-800-267-4414. Please do not contact these numbers regarding other
manufacturer's respiratory protection products. 3M does not endorse the accuracy of the
information contained in this Material Safety Data Sheet.
Do not get in eyes. Protective equipment should be selected to provide protection from exposure
to the chemicals listed in Section 2 of this document. Depending on the site-specific conditions of
Eyes: use, safety glasses, chemical goggles, and/or head and face protection may be required to
prevent contact. The equipment must be thoroughly cleaned, or discarded after each use.
Protective equipment should be selected to provide protection from exposure to the chemicals
listed in Section 2 of this document. Depending on the site-specific conditions of use, protective
Skin/Hand: gloves, apron, boots, head and face protection may be required to prevent contact. The
equipment must be thoroughly cleaned, or discarded after each use.
Engineering Controls:Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.
Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure. Use good personal hygiene practices. Wash hands before eating,
Other Work Practices:drinking, using toilet facilities, etc. Promptly remove soiled clothing and wash clothing thoroughly
before reuse. Shower after work using plenty of soap and water.
6. FIRE AND EXPLOSION INFORMATION
F: 105
Flash Point:
C: 41
Lower Explosive Limit
.5 (%vol in air) at Normal Atmospheric Temp and Pressure
(LEL):
Combustible liquid and vapor. FLAMMABLE/COMBUSTIBLE MATERIALS: Will be easily
ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may
Fire and Explosion travel to source of ignition and flash back. Most vapors are heavier than air. They will spread
along ground and collect in low or confined areas (sewers, basements, tanks) creating a
Hazards:
vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers
may explode when heated.
Fire Fighting Procedures: Also Reference Emergency Response Guide Number: Not Determined
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7. PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Physical State:
Not Determined
pH:
0.931639
Specific Gravity:
295
Boiling Point (F):
Vapor Density: Heavier than air
VOC Content (lbs): Refer to the Technical Data Sheet for this product
Evaporation Rate: Slower than ether
8. STABILITY AND REACTIVITY DATA
This product is stable and hazardous polymerization will not occur.
General:
Incompatible
Strong oxidizing agents.
Materials:
Hazardous May produce hazardous fumes when heated to decomposition as in welding. Fumes may
produce Carbon Dioxide and Carbon Monoxide.
Decompostion:
9. HANDLING AND STORAGE
Storage Temperature: Store between 32 and 120 F
Keep away from heat, sparks and flame. Do not smoke. Extinguish all flames and pilot lights, and
Handling and Storage turn off stoves, heaters, electric motors and other sources of ignition during use and until all
vapors are gone. Vapors may cause flash fire or ignite explosively. Prevent build-up of vapors by
Precautions: opening all windows and doors to achieve cross-ventilation. Do not get in eyes, on skin or
clothing. Close container after each use. Wash thoroughly after handling.
10. TOXICOLOGICAL DATA
NOTICE: Reports have associated repeated and prolonged occupational overexposure to
solvents with permanent brain and nervous system damage. Intentional misuse by deliberately
General: concentrating and inhaling the contents may be harmful or fatal. No additional information
provided for this product. See Section 2 for chemical specific data.
11. ECOLOGICAL DATA
No additional information provided for this product. See Section 2 for chemical specific data.
General:
12. ACCIDENTAL RELEASE MEASURES
ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area).
Use only non-sparking equipment to handle spilled material and absorbent. Do not touch or walk
Spill Response through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways,
sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors.
Procedures:
Absorb or cover with dry earth, sand, or other non-combustible material and transfer to
containers. Use non-sparking tools to collect absorbed material.
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CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area
immediately for at least 25 to 50 meters (80 to 160 feet) in all directions. Keep unauthorized
personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering.
Public Safety:
LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet).
Also, Reference Emergency Response Guide Number: Not Determined
13. DISPOSAL CONSIDERATION
Dispose of in accordance with local, state and federal regulations. (Also reference RCRA
Waste Disposal: information in Section 15 if listed).
14. TRANSPORTATION INFORMATION
DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation)
DOT Proper Shipping Name: IMDG Proper Shipping Name:
CONSUMER COMMODITY, ORM-D CONSUMER COMMODITY, ORM-D
DOT Hazard Class: NR IMDG Hazard Class: Not Regulated
UN / NA Number: Not Regulated UN Number: Not Regulated
IMDG Packing
DOT Packing Group: Not Regulated Not Regulated
Group:
System Reference
CERCLA/DOT RQ: 1569 gal. / 12177 lbs. 5
Code:
15. REGULATORY INFORMATION
The regulatory data in Section 15 is not intended to be all-inclusive, only selected
regulations are represented. All ingredients of this product are listed on the TSCA
Regulatory Overview: (Toxic Substance Control Act) Inventory or are not required to be listed on the
TSCA Inventory.
WHMIS Classification: Not Determined
Regulatory List Product Ingredients on List
DOT Marine Pollutants (10%):
(No Product Ingredients
Listed)
DOT Severe Marine Pollutants (1%):
(No Product Ingredients
Listed)
EPCRA 311/312 Chemicals and
RQs:
000091-20-3 Naphthalene : final RQ = 100 pounds (45.4 kg)
Propylene glycol monomethyl ether acetate : (Includes mono- and di- ethers of
ethylene glycol; diethylene glycol and triethylene glycol R-(OCH2CH2)n-OR'' where
n = 1 2 or 3; R = alkyl or aryl groups; R'' = R h or groups which when removed yield
000108-65-6
glycol ethers with the structure R-(OCH2CH2)n-OH. Polymers are excluded from
glycol category); Statutory RQ = 1 pound (.454 kg); no final RQ is being assigned
to the generic or broad class
001330-20-7 Xylenes (o-, m-, p- isomers) : final RQ = 100 pounds (45.4 kg)
EPCRA 302 Extremely Hazardous:
(No Product Ingredients
Listed)
EPCRA 313 Toxic Chemicals:
001344-28-1 Aluminum oxide
000091-20-3 Naphthalene
000108-65-6 Propylene glycol monomethyl ether acetate
001330-20-7 Xylenes (o-, m-, p- isomers)
Mass RTK Substances:
008052-41-3 Stoddard solvent
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013463-67-7 Titanium dioxide
Mass Extraordinarily Haz
Substances:
(No Product Ingredients
Listed)
Penn RTK Substances:
008052-41-3 Stoddard solvent
013463-67-7 Titanium dioxide
Penn Special Hazardous
Substances:
001333-86-4 Carbon black
Rhode Island Hazardous
Substances:
001344-28-1 Aluminum oxide
000091-20-3 Naphthalene
008052-41-3 Stoddard solvent
013463-67-7 Titanium dioxide
001330-20-7 Xylenes (o-, m-, p- isomers)
RCRA Status:
(No Product Ingredients
Listed)
N.J. RTK Substances:
008052-41-3 Stoddard solvent
013463-67-7 Titanium dioxide
N.J. Special Hazardous Substances:
(No Product Ingredients
Listed)
N.J. Env. Hazardous Substances:
001344-28-1 Aluminum oxide
000091-20-3 Naphthalene
000108-65-6 Propylene glycol monomethyl ether acetate
001330-20-7 Xylenes (o-, m-, p- isomers)
Proposition 65 - Carcinogens:
001333-86-4 Carbon black
014808-60-7 Quartz
Proposition 65 - Female
Reproductive Toxins:
(No Product Ingredients
Listed)
Proposition 65 - Male Reproductive
Toxins:
(No Product Ingredients
Listed)
Proposition 65 - Developmental
Toxins:
(No Product Ingredients
Listed)
16. OTHER INFORMATION
The information and recommendations contained herein are based upon data believed to be correct. However, no
guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We
accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products.
Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
End Of Document
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