Material Safety Data Sheet
Clariant (Australia) Pty Ltd
FORON BLACK RD-3GI 300 Page: 1 of 6
PRODUCT: 1206141 Date of Issue:
12 October 2004
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
1. Identification of the material and supplier
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Product (material) name: Product Code:
FORON BLACK RD-3GI 300 1206141
Recommended Use:
Textiles dye
Supplier:
Clariant (Australia) Pty Ltd.
ACN 069 435 552 ABN 30 069 435 552
675 - 685 Warrigal Road,
Chadstone Victoria 3148
Australia
Telephone: +61 3 9254 1000 Facsimile: +61 3 9254 1010
Emergency Telephone Number: 1800 643 555 (24 Hours)
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
2. Hazards identification
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Not classified as hazardous according to criteria of
NOHSC.
Not classified as dangerous goods according to the Australian Code for
Transport of Dangerous Goods.
Risk phrases:
R52 Harmful to aquatic organisms.
R53 May cause long-term adverse effects in the
aquatic environment.
Safety phrases:
S61 Avoid release to the environment. Refer to special
instructions/safety data sheets.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
3. Composition/information on ingredients
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Chemical identity CAS Number Proportion
Azo dyestuff, mixture 25-30%
nonionic
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
4. First aid measures
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
After inhalation:
Remove from the source of vapour/ dust/ spray/ fumes;
remove to open space or fresh air.
After contact with skin:
MSD$62 8/05
Material Safety Data Sheet
Clariant (Australia) Pty Ltd
FORON BLACK RD-3GI 300 Page: 2 of 6
PRODUCT: 1206141 Date of Issue:
12 October 2004
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
(Continued)
4. First aid measures
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Wash the skin thoroughly with soap and water.
After contact with eyes:
Immediately rinse eyes thoroughly, including under eyelids,
with running water for at least 15 minutes.
Seek immediate medical advice.
After ingestion:
Seek medical advice immediately if swallowed.
Advice to Doctor:
Treat symptomatically.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
5. Fire fighting measures
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Suitable extinguishing media:
All extinguishing media are suitable.
Special protective precautions and equipment for fire fighters:
Use water spray to cool fire-exposed containers and metallic
parts.
In case of fire, prevent by any means possible spillage
from entering drains or water courses.
Hazchem Code: N/A
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
6. Accidental release measures
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Emergency procedures:
Collect product and consider recycling.
In case of spillage prevent the material from entering
drains or water courses.
Methods and materials for containment and clean up:
Remove mechanically using a shovel or any other suitable
equipment.
Collect in a convenient manner to avoid dusty conditions.
Take up into tightly closed containers.
Wash the residue and small amounts from the contaminated
area with water.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
7. Handling and storage
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Precautions for safe handling:
Keep the container tightly closed.
Avoid formation/ deposition of dust.
Take precautionary measures against static discharges.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
8. Exposure controls/personal protection
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
MSD$62 8/05
Material Safety Data Sheet
Clariant (Australia) Pty Ltd
FORON BLACK RD-3GI 300 Page: 3 of 6
PRODUCT: 1206141 Date of Issue:
12 October 2004
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(Continued)
8. Exposure controls/personal protection
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
National exposure standards:
No exposure standards have been assigned by the National
Occupational Health and Safety Commission for any components
of this product.
Engineering controls:
Use only in well-ventilated areas.
Personal protective equipment:
Eye/ face protection:
Avoid contact with the eyes.
Skin protection:
Avoid contact with the skin.
Wear suitable protective clothing.
Respiratory protection:
Do not breathe vapour/ dust/ spray/ fumes.
Other protection:
Do not eat, drink or smoke until after washing.
Wash thoroughly after handling.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
9. Physical and chemical properties
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Appearance (colour, physical form, shape) / Odour:
black granules / no odour
pH (10 g/L water) : 7.5-8.5 @ 20C
Vapour pressure : not appl.
Boiling point/ Melting Point (C) : not appl
Solubility in Water (g/l) at 20 C : disperses
Specific gravity or density : no data
Flash Point (C) and method of detecting flash point:
not appl.
Upper and lower flammable (explosive) limits (% Volume in air): no data
Additional Information:
Flammability:
Combustible solid.
Bulk Density : 490 kg/m3, estimated
Self-ignition Test (SIT400) : 140 C, Method: SEDEX isoperibolic in a
400 ml wire basket, air open.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
10. Stability and reactivity
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Reactivity Hazards:
No hazards are expected, if the material is handled, stored
and used according to instructions & government regulations.
May form flammable/explosive dust-air mixture.
MSD$62 8/05
Material Safety Data Sheet
Clariant (Australia) Pty Ltd
FORON BLACK RD-3GI 300 Page: 4 of 6
PRODUCT: 1206141 Date of Issue:
12 October 2004
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
(Continued)
10. Stability and reactivity
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Hazardous decomposition products/ Hazardous Reactions:
Thermal decomposition: 140 C (Long duration test,
decomposition test; Heating rate, 0K/min., Air open cup). Thermal decomp-
osition: 160 C (Heating rate, 0.75K/min.,Radex dynamic decomp'n test; Air-
open cup; Spontaneous decomposition. Hazardous decomposition products:
oxides of carbon, nitrogen & sulfur; hydrogen bromide, hydrogen chloride.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
11. Toxicological information
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Health Effects of Acute Overexposure:
If swallowed:
The product is of low acute oral toxicity in the rat.
If in eyes:
The material should not be allowed to contact the eyes.
Not expected to cause eye irritation.
If on skin:
The material should not be allowed to come into contact
with the skin.
Not expected to be irritating to the skin.
If inhaled:
Avoid breathing vapour/ dust/ spray/ fumes.
Health Effects of Chronic Overexposure:
The substance may be absorbed through the skin.
Acute oral toxicity LD50 (mg/kg): >2000 Species: rat
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
12. Ecological information
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Ecotoxicity:
Fish toxicity: LC50: 10-100 mg/l Testing Time(h): 96 Species: Rainbow trout
Toxicity to Bacteria in Effluent: IC50: >100 mg/l Test: Activatd sludge
Persistence and degradability:
Biodegradation: <10 Parameter: BOD/COD Method:
Additional Information:
Chemical oxygen demand: 1234 mg/g
Aquatic, Air or Soil Environment Hazards:
Avoid release to the environment.
Do not allow product to enter waste water, rivers or creeks.
Harmful to aquatic organisms.
May cause long-term adverse effects in the aquatic
environment.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
13. Disposal considerations
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
MSD$62 8/05
Material Safety Data Sheet
Clariant (Australia) Pty Ltd
FORON BLACK RD-3GI 300 Page: 5 of 6
PRODUCT: 1206141 Date of Issue:
12 October 2004
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
(Continued)
13. Disposal considerations
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Disposal methods and containers:
In accordance with government regulations for the disposal
of special waste.
Consider recycling the product.
Special precautions for landfill or incineration:
Incinerate in an approved incinerator equipped with an
afterburner and scrubber appropriate for the gas evolved.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
14. Transport information
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Australian Code for Transport of Dangerous Goods by Road and Rail:
U.N. Number: N/A
U.N. Proper Shipping Name:
Not Applicable
Class: N/A
Subsidiary risk: N/A
Packing Group: N/A
Hazchem Code: N/A
Transport information:
Not classified as dangerous goods according to the
Australian Code for the Transport of Dangerous Goods
by Road and Rail.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
15. Regulatory information
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Poison schedule (SUSDP): None allocated
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
16. Other information
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Special precautions/ comments:
Composition: C, H, N, Na, O, S, Br, Cl.
Toxicological and ecotoxicity information based on data for components.
Data sources/ references:
Clariant (Switzerland) AG, Switzerland
- Material Safety Data Sheet
Abbreviation(s):
N/A, Not appl. = Not applicable
Contact point:
For specialist advice in emergency - contact Emergency Response Co-ordinator
Clariant (Australia) Pty. Ltd.
MSD$62 8/05
Material Safety Data Sheet
Clariant (Australia) Pty Ltd
FORON BLACK RD-3GI 300 Page: 6 of 6
PRODUCT: 1206141 Date of Issue:
12 October 2004
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(Continued)
16. Other information
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Tel: 1800 643 555 (24 hours)
For non-emergency enquiries - contact Product Safety Manager
Clariant (Australia) Pty. Ltd.
Tel: (03)9254 1000 Fax: (03)9254 1010
This MSDS summarises our best knowledge of the health and safety hazard
information of the product and how to safely handle and use the product in
the workplace. Each user should read this MSDS and consider the information
in the context of how the product will be handled and used in the workplace,
including in conjunction with other products.
If clarification or further information is needed to ensure that an
appropriate risk assessment can be made, the user should contact this company.
Our responsibility for products sold is subject to our standard terms and
conditions, a copy of which is sent to our customers and is also available on
request.
MSD$62 8/05
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