SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 08/JUN/2005
Date Updated: 21/JUN/2004
Version 1.4
According to 91/155/EEC
1 - Product and Company Information
Product Name SODIUM FORMATE, 99.998%
Product Number 456020
Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
SODIUM FORMATE 141-53-7 205-488-0 None
Formula CHO2Na
Molecular Weight 68.01 AMU
Synonyms Mravencan sodny (Czech) * Salachlor * Sodium
formate
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Not hazardous according to Directive 67/548/EEC.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Exercise appropriate precautions to minimize direct contact with
skin or eyes and prevent inhalation of dust.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Avoid inhalation. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed.
SPECIAL REQUIREMENTS: Moisture sensitive.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Wear dust mask.
Hand Protection: Protective gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Color: Colorless
Form: Fine crystals
Property Value At Temperature or Pressure
pH 7 - 8.5
BP/BP Range N/A
MP/MP Range 261 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
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Explosion Limits N/A
Vapor Pressure N/A
SG/Density 1.92 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density 2.35 g/l
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density 1 - 1.05 kg/l 20 掳C
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility Solubility in Water:1 M in H2O, 20掳C
complete, colorless
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Conditions to Avoid: Moisture.
Materials to Avoid: Strong oxidizing agents, Strong acids.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Sodium/sodium oxides.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: LR0350000
ACUTE TOXICITY
LD50
Oral
Mouse
11,200 mg/kg
LD50
Intravenous
Mouse
807 mg/kg
LD50
Intrauterine
Mouse
2,500 mg/kg
LDLO
Oral
Dog
4,000 mg/kg
LDLO
Intravenous
Dog
3,000 mg/kg
LDLO
Subcutaneous
Cat
1,140 mg/kg
LDLO
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Intravenous
Rabbit
1,250 mg/kg
LD50
Inhalation
Rat
670 mg/m3
4H
LD50
Oral
Mouse
11200 mg/kg
LD50
Intravenous
Mouse
807 MG/KG
IRRITATION DATA
Skin
Rabbit
Remarks: Mild irritation effect
Eyes
Rabbit
Remarks: Moderate irritation effect
Drinking
Rat
1%
1.5 YEARS
Remarks: No irritation effect
Eyes
Rabbit
Remarks: No irritation effect
Skin
Rabbit
Remarks: No irritation effect
SIGNS AND SYMPTOMS OF EXPOSURE
Other symptoms may include rash and itching. Eye contact may
result in irritation or eye burns. Prolonged or repeated
exposure to skin may cause irritation. Coughing, chest pains,
difficulty in breathing. Asthmatic symptoms: cough, hoarseness,
rhinorrhea, wheezing, and conjunctivitis. Nausea, vomiting,
diarrhea.
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: May be harmful if inhaled. Material may be
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
12 - Ecological Information
ELIMINATION
Elimination: 92 %
ECOTOXICOLOGICAL EFFECTS
Test Type: EC0 Daphnia
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Species: Daphnia magna
Time: 24 h
Value: > 1,000 mg/l
Test Type: LC50 Fish
Species: Lepomis macrochirus (Bluegill)
Time: 24 h
Value: 5,000 mg/l
Test Type: LC50 Fish
Species: Leuciscus idus
Time: 48 h
Value: > 1,000 mg/l
Test Type: LC50 Fish
Species: Pimephales promelas (Fathead minnow)
Time: 96 h
Value: > 954 mg/l
Test Type: LC50 Fish
Species: Onchorhynchus mykiss (Rainbow trout)
Time: 96 h
Value: > 887 mg/l
Test Type: EC50 Daphnia
Species: Daphnia magna
Time: 48 h
Value: 1,070 mg/l
Test Type: EC50 Algae
Species: Selenastrum capricornutum resp.
Time: 96 h
Value: 790 mg/l
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
Non-hazardous for road transport.
IMDG
Non-hazardous for sea transport.
IATA
Non-hazardous for air transport.
15 - Regulatory Information
Not hazardous according to Directive 67/548/EEC.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 1
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SWITZERLAND
SWISS POISON CLASS: 5
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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