Material Safety Data Sheet
Date Printed: 16/AUG/2005
Date Updated: 15/JUN/2005
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
1 - Product and Company Information
Product Name ERIOCHROME BLUE BLACK B, FOR
Product Number 45540
Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
ERICHROME BLUE-BLACK B,INDICATOR 3564-14-5 222-639-6 None
FOR METALTITRATION (C.I.
Molecular Weight 416.39 AMU
Synonyms Alizarine Blue Black OCBN * Alizarine Blue Black
OCGN * Alizarine Blue Black OCGP * Alizarine
Blue OCB * Azochromol Blue Black EB *
Calcochrome Blue Black BC * Chromazine Blue
Black B * Chrome Blue Black BF * Chrome Fast
Cyanine BP * Chrome Fast Cyanide G * Chrome Fast
Cyanine GN * Chrome Fast Cyanine GNN * Chrome
Fast Cyanine GP * Chrome Fast Cyanine GSS *
Chromocard Blue Black B * C.I. 14640 * C.I.
Mordant Black 3 * C.I. Mordant Black 3,
monosodium salt * Diacromo Blue G * Diamond Blue
Black AE * Diamond Blue Black EB * Diamond Blue
Black EBS-CF * Durochrome Blue OCG * Durochrome
cyanine G * Durochrome Fast Cyanine 6BN *
Eriochrome Blue Black * Eriochrome Blue Black B
* Eriochrome Blue Black 2B * Eriochrome Blue
Black BC * Eriochrome Blue Black 2BP *
Eriochrome Blue Black BSS * Eriochrome Blue
Black 2G * Fast chrome cyanine 6B * Fast chrome
cyanine G * Fenakron Blue Black EB * Hispacrom
Blue BG * Java Chrome Blue Black BN * Kenachrome
Black 6B * Lighthouse Chrome Black 6B * Mitsui
Chrome Blue Black BC * Omega Chrome Blue Black B
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Irritating to eyes.
4 - First Aid Measures
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and
heavy rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
Directions for Safe Handling: Do not breathe dust. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
Conditions of Storage: Keep tightly closed.
8 - Exposure Controls / Personal Protection
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
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PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
Partition Coefficient N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Miscellaneous Data N/A
Solubility Solubility in Water:20 mg/ml H2O, 20藲C
10 - Stability and Reactivity
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides, Sulfur oxides.
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: QK2195000
Remarks: No irritation effect
Remarks: Moderate irritation effect
SIGNS AND SYMPTOMS OF EXPOSURE
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To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: May be harmful if inhaled. Material may be
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
12 - Ecological Information
No data available.
13 - Disposal Considerations
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
14 - Transport Information
Non-hazardous for road transport.
Non-hazardous for sea transport.
Non-hazardous for air transport.
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: Xi
Irritating to eyes.
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
COUNTRY SPECIFIC INFORMATION
WGK: 2 (Self classification)
16 - Other Information
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
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or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
For R&D use only. Not for drug, household or other uses.
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