MSDS: ERIONYL RED A-2BF
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: ERIONYL RED A-2BF
MSDS CODE : C1599631AO
VERSION : 2
UPDATED : May 2002
Not classified as hazardous according to criteria of Worksafe Aust.
:
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn: Attention:
CHEMICAL SAFTEY OFFICER
or
EMERGENCY RESPONCE SERVICES
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IDENTIFICATION
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PRODUCT NAME ..: ERIONYL RED A-2BF
Other name(s)..: AZO DYE PREPARATION
Correct Shipping name: NOT APPLICABLE
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
Poison Schedule . . : NONE ALLOCATED
USE:
TEXTILE DYE
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Appearance. . . . . . : RED POWDER WITH NO ODOUR
Boiling/Melting point : NOT APPLICABLE
Vapour pressure . . . : NOT APPLICABLE
Density . . . . . . . : NOT AVAILABLE
Flash Point . . . . . : NOT APPLICABLE
Flammability Limits . : not applicable
Solubility in water . : 80 g/l at 30 oC (g/L @ 20 deg.C)
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SOLUBILITY IN WATER : 100 g/l at 90 oC
THERMAL DECOMPOSITION : > 200 oC
IGNITION TEMPERATURE : > 500 oC
OXIDISING PROPERTIES : NONE
BULK DENSITY : 860 kg/m3
pH value : ca. 10 in water (20 g/l)
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Chemical Entity CAS No. Proportion
SODIUM 6-AMINO-5-[[5-CHLORO-2-(2-CHLOROP 103241-64-1 18 - 24 %
HENOXY)PHENYL]AZO-4-HYDROXY-2-NAPHTHALEN
E SULFONATE
NON HAZARDOUS COMPONENTS TO 100 %
THIS PRODUCT CONTAINS AN INGREDIENT WHICH IS HAZARDOUS TO THE
ENVIRONMENT. AS AN ENVIRONMENTAL PRECAUTION PREVENT PRODUCT FROM
ENTERING NATURAL WATERWAYS, DRAINS, SEWER AND SOIL.
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HEALTH HAZARD INFORMATION
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Page 1 of 3
MSDS: ERIONYL RED A-2BF
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Swallowed : SLIGHT (Oral, Rat LD50) > 2000 mg/kg.
Eye . . . : NON-IRRITANT - EC 83 RABBIT.
Skin . . : NON-IRRITANT - EC 83 RABBIT.
Inhaled . : NOT YET AVAILABLE.
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NONE KNOWN.
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Swallowed : WASH OUT MOUTH WITH WATER. DRINK PLENTY OF WATER.
SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES.
Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING.
Inhaled . : REMOVE PATIENT TO FRESH AIR AND REST. IF YOU FEEL
UNWELL OR IF EXPOSURE PROLONGED, SEEK MEDICAL
ATTENTION.
First aid facility: NO SPECIAL FACILITIES REQUIRED.
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
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PRECAUTIONS FOR USE
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TWA : 10 mg/m3 NUISANCE DUST (C.I.A)
AVOID EXPOSURE BY USE OF VENTILATION AND/OR PERSONAL PROTECTION.
FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
AVOID DUST FORMATION.
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE EXPOSURE LIMITS ARE MET. STATE REGULATIONS ON SPEED
AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
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GLOVES (PVC, LONG IMPERVIOUS), OVERALLS AND SAFETY GLASSES/FACE SHIELD
ARE RECOMMENDED TO BE WORN WITH THIS PRODUCT.
WHERE SUFFICIENT VENTILATION IS NOT AVAILABLE, AVOID BREATHING DUST OR
VAPOURS BY WEARING THE FOLLOWING AS1716 APPROVED RESPIRATORY
PROTECTION : DISPOSABLE DUST MASK: "PARTICULATE FILTER P1,
SUITABLE".
FOLLOW GOOD WORKING PRACTICE: Handle with care, avoid ingestion,
inhalation, eye or skin contact. Wash hands and face thoroughly
after handling and before eating, drinking or smoking.
Avoid unnecessary personal contact.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
DUST CLOUDS FROM FINELY PARTICULATED PRODUCT MAY BE HAZARDOUS (DUST
EXPLOSION RISK). EQUIPMENT SHOULD BE ADEQUATELY GROUNDED.
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SAFE HANDLING INFORMATION
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General . . . . . . : STORE IN A COOL, DRY AREA WITH ADEQUATE
Storage . . . . . . : VENTILATION. KEEP CONTAINERS CLOSED.
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
IATA Class . . . . . : FREE
IMDG Reference . . . : FREE
Minimum temperature : NOT APPLICABLE
Maximum temperature : NOT APPLICABLE
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: NOT APPLICABLE
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Page 2 of 3
MSDS: ERIONYL RED A-2BF
IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE. DAMPEN
DOWN POWDER AND AVOID DUST. SCOOP INTO MARKED CONTAINERS FOR DISPOSAL
AS CHEMICAL WASTE.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS: LAND FILL: "NO"
SECURE LAND FILL: "NO" INCINERATION: "YES" HIGH TEMPERATURE
INCINERATION: "SUITABLE" - CONTAMINATED, EMPTY CONTAINERS MUST BE
DISPOSED OF AS CHEMICAL WASTE. NOTE: IF IN DOUBT, CONTACT CIBA
SPECIALTY CHEMICALS TELEPHONE NUMBER ON PAGE 1.
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Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
THERMAL DECOMPOSITION OR BURNING MAY RELEASE OXIDES OF CARBON,
NITROGEN AND SULFUR. SOME HYDROGEN CHLORIDE GAS ALSO POSSIBLE. IN CASE
OF FIRE, SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
EQUIPMENT MUST BE WORN.
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 0 mg02/g
COD . . . . . . . . . . . . : 1025 mgO2/g
TOC . . . . . . . . . . . . : 34 %
Fish toxicity . . . . . . . : SPECIES : ZEBRA FISH
LC0 : 10 mg/l
LC50 : 17 mg/l, 48 hrs OECD 203
DAPH.TOXICITY:
EC50 : 64 mg/l, 48 hrs OECD 202
Toxicity to Bacteria . . . : BST : > 300 mg/l
OECD Biological degredation : < 10 %, DOC ANALYSIS, OECD 310A
Organo-halogen content. . . : 3.4 % CHLORO
Heavy-metal content . . . . : UNDER THE ETAD RECOMMENDED LIMITS
BIOELIMINATION SUMMARY: NOT READILY BIODEGRADABLE.
NITROGEN CONTENT: 3.7 %.
TESTED MATERIAL: BASED ON KNOWN DATA OF THE COMPONENTS.
HARMFUL TO AQUATIC ORGAMISMS,, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN
THE AQUATIC ENVIRONMENT. PREVENT DISCHARGE OF PRODUCT INTO NATURAL
WATERWAYS, DRAINS, SEWER AND SOIL. CONTAIN SPILLS AND ANY RESIDUES AND
DISPOSE OF AS SHOWN ABOVE.
Do not release chemically contaminated water into drains, soil or
surface water. Sufficient measures must be taken to retain the water
for extinguishing. Dispose of contaminated water and soil according to
local regulations.
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EEC classification/labelling: ** NOT CLASSIFIED AS HAZARDOUS **
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0412 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: DEANGGU1 Date: 10 May 02
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