MATERIAL SAFETY DATA SHEET
PRODUCT NAME: ERIONYL YELLOW A-R
MSDS CODE : C1599619AL
VERSION : 3
UPDATED : April 2005
Not classified as hazardous according to criteria of NOHSC Australia
:
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn:
CHEMICAL SAFETY OFFICER
or
EMERGENCY RESPONSE SERVICES
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IDENTIFICATION
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PRODUCT NAME ..: ERIONYL YELLOW A-R
Other name(s)..: AZO DYE PREPARATION
Correct Shipping name: NOT APPLICABLE
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
Poison Schedule . . : NONE ALLOCATED
USE:
TEXTILE DYE
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Appearance. . . . . . : YELLOW POWDER; NO ODOUR
Boiling/Melting point : NOT AVAILABLE
Vapour pressure . . . : NOT APPLICABLE
Density . . . . . . . : NOT AVAILABLE
Flash Point . . . . . : NOT APPLICABLE
Flammability Limits . : Upper NO DATA Lower (% in air)
Solubility in water . : 20 g/L (30酶C) (g/L @ 20 deg.C)
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Decomposition temperature: >200酶C
pH : 8.5 - 10 (20 g/L)
Bulk Density : 598 - 657 kg/m3
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Chemical Entity CAS No. Proportion
SODIUM-4-[4-[[2-METHYL-4-[[(P-TOLYL)SULP 12220-06-3 45 - 55 %
HONYL]OXY]PHENYL]AZO]ANILINO]-3-NITROBEN
ZENESULPHONATE
NON-HAZARDOUS COMPONENTS PROPRIETARY to 100 %
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HEALTH HAZARD INFORMATION
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Swallowed : SLIGHT - ORAL LD50 >5000 mg/kg (RAT)
Eye . . . : NON-IRRITANT - RABBIT
Skin . . : NON-IRRITANT - RABBIT
Inhaled . : NOT YET AVAILABLE
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NO ADVERSE HEALTH EFFECTS HAVE BEEN REPORTED FROM WORKERS WHO HAVE
BEEN HANDLING THIS MATERIAL OVER MANY YEARS.
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Swallowed : WASH OUT MOUTH WITH WATER. DRINK PLENTY OF WATER.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 10 MINUTES.
Skin . . : REMOVE CONTAMINATED CLOTHING. WASH AFFECTED SKIN
WITH SOAP AND PLENTY OF RUNNING WATER.
Inhaled . : MOVE PATIENT TO FRESH AIR AND REST.
First aid facility: ENSURE EYEWASH AND DELUGE SHOWER ARE READILY
ACCESSIBLE.
Advice to Doctor .: SYMPTOMATIC TREATMENT.
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PRECAUTIONS FOR USE
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TWA : 10 mg/m3 PARTICULATES NOT OTHERWISE CLASSIFIED
AVOID EXPOSURE BY USE OF VENTILATION AND/OR PERSONAL PROTECTION.
FOLLOW GOOD WORKING PRACTICE: HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE EXPOSURE LIMITS ARE MET. STATE REGULATIONS ON SPEED
AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
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GLOVES (PVC, LONG IMPERVIOUS), OVERALLS AND GLASSES/FACE SHIELD ARE
RECOMMENDED TO BE WORN WITH THIS PRODUCT. RECOMMENDED RESPIRATORY
PROTECTION: PARTICULATE FILTER RESPIRATOR - CLASS P1 OR P2.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
DUST CLOUDS FROM FINELY PARTICULATED PRODUCT MAY BE HAZARDOUS (DUST
EXPLOSION RISK). EQUIPMENT SHOULD BE ADEQUATELY GROUNDED.
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SAFE HANDLING INFORMATION
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General . . . . . . : STORE IN A COOL, DRY AREA WITH ADEQUATE
Storage . . . . . . : VENTILATION.
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
IATA Class . . . . . : FREE
IMDG Reference . . . : FREE
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: NOT APPLICABLE
AVOID INGESTION, INHALATION, SKIN AND EYE CONTACT. HANDLE IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE AND ANY LEGAL
REQUIREMENTS.
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IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE. DAMPEN
DOWN FIRST, SCOOP UP MATERIAL AND PLACE INTO MARKED CONTAINERS FOR
DISPOSAL AS CHEMICAL WASTE. WASH DOWN SPILL AREA WITH DETERGENT AND
WATER AND DISCHARGE FOR EFFLUENT TREATMENT ONLY. DO NOT FLUSH DIRECTLY
TO SEWER OR SURFACE WATERS.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS: LAND FILL: "NO"
SECURE LAND FILL: "NO" INCINERATION: "YES" HIGH TEMPERATURE
INCINERATION: "SUITABLE" - CONTAMINATED, EMPTY CONTAINERS MUST BE
DISPOSED OF AS CHEMICAL WASTE. NOTE: IF IN DOUBT, CONTACT CIBA
SPECIALTY CHEMICALS TELEPHONE NUMBER ON PAGE 1.
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Extinguishing Media : WATERSPRAY, CARBON DIOXIDE, FOAM, POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
VAPOURS OF NITROGEN, CARBON AND SULFUR OXIDES POSSIBLE IN A FIRE. WEAR
SELF CONTAINED BREATHING APPARATUS.
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 0 mgO2/g
COD . . . . . . . . . . . . : 1215 mgO2/g
TOC . . . . . . . . . . . . : 40.5 %
Fish toxicity . . . . . . . : SPECIES: RAINBOW TROUT
LC0 2 mg/L
LC50 20 mg/l 48h (OECD 203)
DAPHNIA TOXICITY: EC50 31 mg/L 48h
NITROGEN CONTENT: 11.8 %
Toxicity to Bacteria . . . : BST >300 mg/L
OECD Biological degredation : >90 % TOC ANALYSIS - OECD 303A (mod)
Organo-halogen content. . . : 0 %
Heavy-metal content . . . . : CONTENT UNDER ETAD RECOMMENDED LIMITS
Phosphorous content . . . . : 0 %
HARMFUL TO AQUATIC ORGANISMS IF RUN DIRECTLY TO SURFACE WATERS.
BEHAVIOUR IN TRETMENT PLANTS: NO INHIBITION. NO NITRIFICATION
INHIBITION KNOWN. BIOELIMINATION SUMMARY: ELIMINATED BY ADSORPTION ON
EFFLUENT TREATMENT SLUDGE. TESTED MATERIAL IS BASED ON PRODUCT/ACTIVE
COMPONENT.
NOTE: PREVENT SPILLAGE FROM ENTERING WATERWAYS OR DRAINS.
R52/53: HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE
EFFECTS IN THE AQUATIC ENVIRONMENT. S61: AVOID RELEASE TO THE
ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY DATA SHEETS.
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EEC classification/labelling: ** NOT CLASSIFIED **
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0408 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: HUDSOAL1 Date: 13 April 05
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