SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 19/JUN/2005
Date Updated: 13/APR/2005
Version 1.3
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name GLUTARALDEHYDE 50% AQUEOUS SOLUTION
PHOTOGRAPHIC GRADE
Product Number G6403
Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
GLUTARALDEHYDE, 50% AQUEOUS None 203-856-5 605-022-00-X
SOLUTION
Ingredient Name Percent CAS # EC no Annex I
Index Number
GLUTARALDEHYDE 50 111-30-8 203-856-5 605-022-00-X
Symbols: T N
R-Phrases: 23/25 34 42/43 50
Toxic by inhalation and if swallowed. Causes burns. May cause
sensitization by inhalation and skin contact. Very toxic to
aquatic organisms.
WATER 49.5 7732-18-5 231-791-2 None
METHANOL 0.5 67-56-1 200-659-6 603-001-00-X
Symbols: F T
R-Phrases: 11 23/24/25 39/23/24/25
Highly flammable. Toxic by inhalation, in contact with skin and if
swallowed. Toxic: danger of very serious irreversible effects
through inhalation, in contact with skin and if swallowed.
Formula C5H8O2
Molecular Weight 100.12 AMU
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Toxic by inhalation and if swallowed. Causes burns. May cause
sensitization by inhalation and skin contact. Very toxic to
aquatic organisms.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately. Do not induce vomiting.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Store under inert gas. Keep tightly
closed.
SPECIAL REQUIREMENTS: Store under inert gas. Air sensitive.
8 - Exposure Controls / Personal Protection
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ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Remove and wash contaminated clothing promptly. Discard
contaminated shoes. Wash thoroughly after handling.
EXPOSURE LIMITS - DENMARK
Source Type Value
OEL TWA 0.8 mg/m3
0.2 ppm
Remarks: L
EXPOSURE LIMITS - GERMANY
Source Type Value
TRGS 900 OEL 0.4 mg/m3
0.1 ppm
Remarks: =1=
Remarks: Y
EXPOSURE LIMITS - SWITZERLAND
Source Type Value
OEL OEL 0.4 mg/m3
0.1 ppm
Remarks: S C
EXPOSURE LIMITS - UNITED KINGDOM
Source Type Value
OEL OEL 0.2 mg/m3
0.05 ppm
OEL STEL 0.2 mg/m3
0.05 ppm
Remarks: Sensitizer.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
Special Protective Measures: Faceshield (8-inch minimum).
9 - Physical and Chemical Properties
Appearance Physical State: Clear liquid
Color: Colorless
Property Value At Temperature or Pressure
pH N/A
BP/BP Range 101 掳C 760 mmHg
MP/MP Range -6 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure 15 mmHg 20 掳C
SG/Density 1.106 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density 1.05 g/l
Saturated Vapor Conc. N/A
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Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility Solubility in Water:Soluble.
Other Solvents: SOLUBLE IN ALCOHOL, BENZENE
ETHER
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Conditions of Instability: May discolor on exposure to air.
Materials to Avoid: Strong acids, Strong bases, Strong oxidizing
agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Nonhazardous polymerization may occur.
Avoid initiators, accelerators, heat, pressure, and contamination
11 - Toxicological Information
SENSITIZATION
Respiratory: May cause allergic respiratory reaction.
Skin: May cause allergic skin reaction.
SIGNS AND SYMPTOMS OF EXPOSURE
Material is extremely destructive to tissue of the mucous
membranes and upper respiratory tract, eyes, and skin.
Inhalation may result in spasm, inflammation and edema of the
larynxand bronchi, chemical pneumonitis, and pulmonary edema.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting. To the best of our knowledge, the chemical, physical,
and toxicological properties have not been thoroughly
investigated.
ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: Harmful if absorbed through skin.
Eye Contact: Causes burns.
Inhalation: Toxic if inhaled. Material is extremely destructive
to the tissue of the mucous membranes and upper respiratory
tract.
Ingestion: Toxic if swallowed.
TARGET ORGAN INFORMATION
Central nervous system. Heart.
12 - Ecological Information
13 - Disposal Considerations
SUBSTANCE DISPOSAL
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Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 2922
Class: 8
PG: II
Proper Shipping Name: Corrosive liquid, toxic, n.o.s.
IMDG
UN#: 2922
Class: 8
PG: II
Subrisk: 6.1
Proper Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 2922
Class: 8
PG: II
Subrisk: 6.1
Proper Shipping Name: Corrosive liquid, toxic, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 605-022-00-X
INDICATION OF DANGER: T N
Toxic. Dangerous for the environment.
R-PHRASES: 23/25 34 42/43 50
Toxic by inhalation and if swallowed. Causes burns. May cause
sensitization by inhalation and skin contact. Very toxic to
aquatic organisms.
S-PHRASES: 23 26 36/37/39 45 61
Do not breathe vapor. In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable protective clothing, gloves, and eye/face protection.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible). Avoid release to
the environment. Refer to special instructions/safety data
sheets.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 2 (Self classification)
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
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information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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