SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 11/SEP/2005
Date Updated: 13/MAR/2004
Version 1.1
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name GLYCIDYL METHACRYLATE, 97%
Product Number 151238
Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
GLYCIDYL METHACRYLATE 106-91-2 203-441-9 607-123-00-4
Ingredient Name Percent CAS # EC no Annex I
(+/-)-EPICHLOROHYDRIN 0.2 106-89-8 203-439-8 603-026-00-6
Carc. Cat.2
Symbols: T
R-Phrases: 45-10-23/24/25-34-43
May cause cancer. Flammable. Also toxic by inhalation, in contact
with skin and if swallowed. Causes burns. May cause sensitization
by skin contact.
Formula C7H10O3
Molecular Weight 142.16 AMU
Synonyms CP 105 * Acriester G * Blemmer G * Blemmer GMA *
2,3-Epoxypropyl methacrylate * Glycidyl
methacrylate * Glycidyl alpha-methyl acrylate *
Light Ester G * 2-((Methacryloxy)methyl)oxirane
* 1-Propanol, 2,3-epoxy-, methacrylate *
2-Propenoic acid, 2-methyl-, oxiranylmethyl
ester (9CI) * SR 379 * SY-Monomer G
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin. May cause sensitization by skin
contact.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
SPECIAL RISKS
Specific Hazard(s): Combustible liquid. Emits toxic fumes under
fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe vapor. Avoid
contact with eyes, skin, and clothing. Avoid prolonged or
repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Keep away from heat
and open flame.
Store at 2-8掳C
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
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PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Clear liquid
Color: Colorless
Property Value At Temperature or Pressure
pH N/A
BP/BP Range 192.0 - 197.0 掳C
MP/MP Range N/A
Flash Point 77 掳C Method: closed cup
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure 34 mmHg 100 掳C
SG/Density 1.075 g/cm3
Partition Coefficient N/A
Viscosity 2.5 Pas 20 掳C
Vapor Density 4.9 g/l
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension 25 mN/m 20 掳C
Conductivity N/A
Miscellaneous Data N/A
Solubility Other Solvents: BENZENE, ETHYL ETHER ETHYL
ALCOHOL
10 - Stability and Reactivity
STABILITY
Conditions to Avoid: May polymerize on exposure to light.
Materials to Avoid: Peroxides, Strong bases, Strong acids, Strong
oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: OZ4375000
ACUTE TOXICITY
LD50
Oral
Rat
290 mg/kg
LD50
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Oral
Rat
597 mg/kg
LD50
Oral
Mouse
390 mg/kg
LD50
Skin
Rabbit
450 UL/KG
LD50
Oral
Guinea pig
697 mg/kg
IRRITATION DATA
Skin
Rabbit
0.5 ml
24H
Remarks: Severe irritation effect
Eyes
Rabbit
0.1 ml
Remarks: Moderate irritation effect
SENSITIZATION
Skin: May cause allergic skin reaction.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: Harmful if absorbed through skin.
Eye Contact: Causes eye irritation.
Inhalation: Harmful if inhaled. Material is irritating to mucous
membranes and upper respiratory tract.
Ingestion: Harmful if swallowed.
TARGET ORGAN INFORMATION
Kidneys. Nerves.
CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that has been
reported to be probably carcinogenic based on its IARC, OSHA,
ACGIH, NTP, or EPA classification.
CHRONIC EXPOSURE - MUTAGEN
Rat
300 MG/KG
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Intraperitoneal
Cytogenetic analysis
Hamster
900 UG/L
Cell Type: Embryo
Morphological transformation.
Hamster
78 UMOL/L
Cell Type: lung
Sister chromatid exchange
Hamster
200 UMOL/L
Cell Type: lung
Mutation in mammalian somatic cells.
CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
Species: Rat
Dose: 110 MG/KG
Route of Application: Oral
Exposure Time: (5-15D PREG)
Result: Effects on Newborn: Stillbirth. Effects on Fertility:
Post-implantation mortality (e.g., dead and/or resorbed implants
per total number of implants).
Species: Rabbit
Dose: 50 PPM/6H
Route of Application: Inhalation
Exposure Time: (7-19D PREG)
Result: Maternal Effects: Other effects.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
This combustible material may be burned in a chemical incinerator
equipped with an afterburner and scrubber. Contact a licensed
professional waste disposal service to dispose of this material.
Observe all federal, state, and local environmental regulations.
14 - Transport Information
RID/ADR
UN#: 2810
Class: 6.1
PG: II
Proper Shipping Name: Toxic liquid, organic, n.o.s.
IMDG
UN#: 2810
Class: 6.1
PG: II
Proper Shipping Name: Toxic liquid, organic, n.o.s.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
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IATA
UN#: 2810
Class: 6.1
PG: II
Proper Shipping Name: Toxic liquid, organic, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 607-123-00-4
NOTA: D
INDICATION OF DANGER: Xn
Harmful.
R-PHRASES: 20/21/22-36/38-43
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin. May cause sensitization by skin
contact.
S-PHRASES: 26-28
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. After contact with skin, wash
immediately with plenty of soap-suds.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 2 (self-classification)
SWITZERLAND
SWISS POISON CLASS: 4
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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