Material Name: Safety Data Sheet
JM Two-Part Urethane Insulation Adhesive (Part 2) ID: 3145
Section 1 - Product and Company Identification
Product Name JM Two-Part Urethane Insulation Adhesive (Part 2)
Generic Name Urethane Adhesive
Formula Mixture
Chemical Name: Mixture
Hazard Label CAUTION label
Company Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: JM Two-Part Urethane Insulation Adhesive (Part 2)
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
9082-00-2 Polyol 47-57
29434-03-5 Polyol 9-19
111-46-6 Diethylene glycol <10
25265-71-8 Dipropylene glycol <10
62-53-3 Aniline <0.1
75-21-8 Ethylene oxide <0.1
123-91-1 1,4-Dioxane <0.1
75-07-0 Acetaldehyde <0.1
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Off-white viscous liquid.
HMIS Ratings: Health = 1 Fire = 0 Reactivity = 0
Potential Health Effects
Inhalation
Avoid breathing vapors or mists. Prolonged or excessive inhalation may cause respiratory tract irritation.
Skin
Not expected to be a skin irritant. A single, prolonged exposure is not likely to result in the material being absorbed through
the skin in harmful amounts.
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. Harmful if swallowed.
Eyes
Contact may cause eye irritation and injury.
Primary Routes of Entry (Exposure)
Inhalation (breathing), skin, and eye contact.
Target Organs
Respiratory system, skin, and eye.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
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Material Name: JM Two-Part Urethane Insulation Adhesive (Part 2) Safety Data Sheet
ID: 3145
First Aid: Ingestion
Product is not intended to be ingested or eaten. If the material is swallowed, get immediate medical attention or advice -- Do
not induce vomiting.
First Aid: Eyes
Flush eyes for 10 to 20 minutes while holding eyelids open. Seek medical attention.
Section 5 - Fire Fighting Measures
Flash Point: 190.6癈/375.1癋 Method Used: PMCC
Upper Flammable Limit (UFL): Not determined Lower Flammable Limit (LFL): Not determined
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
Extinguishing Media
Carbon dioxide, dry chemical, water, or foam. Do not use a direct water stream.
Fire Fighting Equipment/Instructions
Wear self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode when fighting
fires.
Section 6 - Accidental Release Measures
Containment Procedures
Avoid contact. Barricade area. Evacuate and ventilate spill area. Dam spill area with sand, earth, or other suitable absorbent.
Prevent entry of material into sewers, other water sources, or land areas. Wear full-protective clothing and respiratory
protection as required to maintain exposures during clean-up below the applicable exposure limits. Shovel absorbed material
into unsealed containers in well-ventilated area.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material. Do
not re-seal if contamination is suspected.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Containers should be kept cool, dry and
protected from moisture. Shelf life (in original, sealed containers) is 18 months at 26.7?br>
C.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be provided as necessary to prevent irritation of the eyes, skin, and respiratory tract, and to keep
exposure levels below the applicable exposure limits.
B: Component Exposure Limits
Aniline (62-53-3)
ACGIH: 2 ppm TWA
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 2 ppm TWA; 8 mg/m3 TWA
Prevent or reduce skin absorption
Acetaldehyde (75-07-0)
ACGIH: 25 ppm Ceiling
OSHA: 100 ppm TWA; 180 mg/m3 TWA
150 ppm STEL; 270 mg/m3 STEL
Ethylene oxide (75-21-8)
ACGIH: 1 ppm TWA
OSHA: 0.5 ppm Action Level; 1 ppm TWA; 5 ppm Excursion Limit (15 min. Cancer hazard and
reproductive hazard - see 29 CFR 1910.1047)
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Material Name: JM Two-Part Urethane Insulation Adhesive (Part 2) Safety Data Sheet
ID: 3145
1,4-Dioxane (123-91-1)
ACGIH: 20 ppm TWA
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 25 ppm TWA; 90 mg/m3 TWA
Prevent or reduce skin absorption
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Chemical goggles are required at a minimum.
Personal Protective Equipment: Skin
Protective gloves should be worn when handling this material. Depending on operation, chemical resistant boots, overshoes,
and apron may also be required.
Personal Protective Equipment: Respiratory
Wear a NIOSH approved respirator when airborne exposures exceed applicable limits.
Ventilation
Use only with adequate ventilation. Provide general and/or local exhaust ventilation to control airborne levels below the
exposure guidelines. The need for ventilation systems should be evaluated by a professional industrial hygienist, while the
design of specific ventilation systems should be conducted by a professional engineer.
Personal Protective Equipment: General
Loose-fitting, long-sleeved clothing should be worn to protect skin from exposure. Exposed areas should be washed with soap
and warm water. Clothing should be washed separately from other clothes, and the washer should be rinsed thoroughly (run
empty for a complete wash cycle).
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Off-white viscous liquid Slight, sweet odor
Physical State: pH:
liquid Not determined
Vapor Pressure: Vapor Density:
Not determined Not determined
Boiling Point: Melting Point:
Not determined Not determined
Solubility (H2O): Specific Gravity:
Slight 1.0
Freezing Point: Solids Content
Not determined Not determined
Evaporation Rate: Percent Volatile:
Not determined <0.15
VOC: None expected - test method
ASTM standard D5201-05a
Section 10 - Stability & Reactivity Information
Stability
Stable
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
No additional information available.
B: Component Analysis - LD50/LC50
Polyol (9082-00-2)
Oral LD50 Rat: >10 g/kg; Dermal LD50 Rabbit: >5 g/kg
Diethylene glycol (111-46-6)
Oral LD50 Rat: 12565 mg/kg; Dermal LD50 Rabbit: 11890 mg/kg
Dipropylene glycol (25265-71-8)
Oral LD50 Rat: 13300 mg/kg; Dermal LD50 Rabbit: 20600 mg/kg
Aniline (62-53-3)
Oral LD50 Rat: 200 mg/kg; Dermal LD50 Rabbit: 820 礚/kg
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Material Name: JM Two-Part Urethane Insulation Adhesive (Part 2) Safety Data Sheet
ID: 3145
Acetaldehyde (75-07-0)
Inhalation LC50 Rat: 13300 mg/kg/4H; Oral LD50 Rat: 661 mg/kg; Dermal LD50 Rabbit: 3540 mg/kg
Ethylene oxide (75-21-8)
Inhalation LC50 Rat: 1.44 mg/L/4H; Inhalation LC50 Rat: 9 mg/L/1H; Inhalation LC50 Rat: 800 ppm/4H; Oral LD50 Rat: 0.05
mg/kg
1,4-Dioxane (123-91-1)
Oral LD50 Rat: 7120 mg/kg; Dermal LD50 Rabbit: 7600 礚/kg
Carcinogenicity
A: General Product Information
No additional information available.
B: Component Carcinogenicity
Aniline (62-53-3)
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
IARC: Group 3 - Not Classifiable (IARC Supplement 7 [1987], Monograph 27 [1982])
Acetaldehyde (75-07-0)
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
NTP: Reasonably Anticipated To Be A Carcinogen (Possible Select Carcinogen)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 71 [1999], Supplement 7
[1987], Monograph 36 [1985])
Ethylene oxide (75-21-8)
ACGIH: A2 - Suspected Human Carcinogen
OSHA: 0.5 ppm Action Level; 1 ppm TWA; 5 ppm Excursion Limit (15 min. Cancer hazard and
reproductive hazard - see 29 CFR 1910.1047)
NTP: Known Carcinogen (Select Carcinogen)
IARC: Group 1 - Known Human Carcinogen (IARC Monograph 60 [1994] (overall evaluation upgraded
from 2A to 1 with supporting evidence from other data relevant to the evaluation of
carcinogenicity and its mechanisms))
1,4-Dioxane (123-91-1)
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
NTP: Reasonably Anticipated To Be A Carcinogen (Possible Select Carcinogen)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 71 [1999], Supplement 7
[1987], Monograph 11 [1976])
Chronic Toxicity
No additional information available.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No additional information available.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Diethylene glycol (111-46-6)
96 Hr LC50 Pimephales promelas: 75200 mg/L [flow-through]
15 min EC50 Photobacterium phosphoreum: 29228 mg/L
96 Hr EC50 water flea: 0.3 mg/L [Static]; 48 Hr EC50 Daphnia magna: 84000 mg/L
Dipropylene glycol (25265-71-8)
24 Hr LC50 Carassius auratus: >5000 mg/L [static]
16 Hr EC50 Pseudomonas putida: 10000 mg/L
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Material Name: JM Two-Part Urethane Insulation Adhesive (Part 2) Safety Data Sheet
ID: 3145
Aniline (62-53-3)
96 Hr LC50 Pimephales promelas: 75.5 mg/L [flow-through]
5 min EC50 Photobacterium phosphoreum: 425 mg/L; 15 min EC50 Photobacterium phosphoreum: 488 mg/L
Acetaldehyde (75-07-0)
96 Hr LC50 Pimephales promelas: 30.8 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 53 mg/L [static]
120 Hr EC50 Nitzschia linearis: 237-249 mg/L
5 min EC50 Photobacterium phosphoreum: 280.6 mg/L; 15 min EC50 Photobacterium phosphoreum: 280.6 mg/L; 25 min
EC50 Photobacterium phosphoreum: 280.6 mg/L
48 Hr EC50 water flea: 9000 mg/L; 48 Hr EC50 Daphnia magna: 48.3 mg/L
Ethylene oxide (75-21-8)
96 Hr LC50 Pimephales promelas: 84 mg/L
48 Hr EC50 Daphnia magna: 137 mg/L
1,4-Dioxane (123-91-1)
96 Hr LC50 Lepomis macrochirus: >10000 mg/L [static]; 96 Hr LC50 Pimephales promelas: 9850 mg/L [flow-through]
5 min EC50 Photobacterium phosphoreum: 610 mg/L; 15 min EC50 Photobacterium phosphoreum: 668 mg/L; 30 min EC50
Photobacterium phosphoreum: 733 mg/L
48 Hr EC50 water flea: 163 mg/L [Static]
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Comply with state and local regulations for disposal. If you are unsure of the regulations, contact your local Public Health
Department, or the local office of the EPA.
Section 14 - Transportation Information
International Transportation Regulations
This product is not classified as a hazardous material for transport.
Adhesive NEC. NMFC 4620 Sub 5 Class 60
STCC 2891124
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Immediate (acute) health hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Aniline (62-53-3)
SARA 302: 1000 lb TPQ
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Acetaldehyde (75-07-0)
CERCLA: 1000 lb final RQ; 454 kg final RQ
Ethylene oxide (75-21-8)
SARA 302: 1000 lb TPQ
CERCLA: 10 lb final RQ; 4.54 kg final RQ
1,4-Dioxane (123-91-1)
CERCLA: 100 lb final RQ; 45.4 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
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Material Name: JM Two-Part Urethane Insulation Adhesive (Part 2) Safety Data Sheet
ID: 3145
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Diethylene glycol 111-46-6 No No No Yes No Yes
Dipropylene glycol 25265-71-8 No No No No No Yes
Aniline 62-53-3 Yes No Yes Yes Yes Yes
Acetaldehyde 75-07-0 Yes No Yes Yes Yes Yes
Ethylene oxide 75-21-8 Yes No Yes Yes Yes Yes
1,4-Dioxane 123-91-1 Yes No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Aniline 62-53-3
Acetaldehyde 75-07-0
Ethylene oxide 75-21-8
1,4-Dioxane 123-91-1
WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects.
Component CAS #
Ethylene oxide 75-21-8
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Polyol 9082-00-2 Yes Yes No
Polyol 29434-03-5 Exempt No No
Diethylene glycol 111-46-6 Yes Yes Yes
Dipropylene glycol 25265-71-8 Yes Yes Yes
Aniline 62-53-3 Yes Yes Yes
Acetaldehyde 75-07-0 Yes Yes Yes
Ethylene oxide 75-21-8 Yes Yes Yes
1,4-Dioxane 123-91-1 Yes Yes Yes
Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
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Material Name: JM Two-Part Urethane Insulation Adhesive (Part 2) Safety Data Sheet
ID: 3145
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
05/02/07 3145-1.0000 New MSDS for JM Two-Part Urethane Insulation Adhesive (Part 2)
This is the end of MSDS # 3145
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