OlyBond 500, Part 1 (Dark Brown) Page 1
MSDS Number: foam00 February 23, 2007
________________________________________
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identification
______________________
Product Name: OlyBond 500, Part 1 (Dark Brown)
Product Number: pails
Chemical Name: Polymeric MDI
Chemical Family: POLYMETHYLENE POLYPHENYLISOCYANATE
CAS Number: Mixture
Company Identification
______________________
ERSystems- Elastomeric Roofing Systems, Inc.
6900 Bleck Dr
Rockford, MN 55373 USA
1-800-403-7747 (For product information)
1-800-535-5053 Infotrac (For emergencies)
SPECIAL NOTES:
Part A of two part polyurethane system. Polymethylene
polyphenylisocyanate.
2. COMPOSITION/INFORMATION ON INGREDIENTS
100.0% OlyBond 500, Part 1 (Dark Brown)
CONTAINING:
HAZARDOUS AND/OR REGULATED COMPONENTS
_____________
Chemical Name ________
Amount CAS Number
__________
4,4'-DIPHENYLMETHANE DIISOCYANATE 38.0 % 101-68-8
NON-HAZARDOUS COMPONENTS
Chemical Name
_____________ Amount
________ __________
CAS Number
POLYMERIC MDI < 55.0 % 9016-87-9
MDI MIXED ISOMERS < 10.0 % 26447-40-5
(See Section 8 for exposure guidelines)
(See Section 15 for regulatory information)
OlyBond 500, Part 1 (Dark Brown) Page 2
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
(section 2 continued)
HAZARDS DISCLOSURE
This product contains hazardous materials as defined by the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
As defined under Sara 311 and 312, this product contains materials that
are hazards.
3. HAZARDS IDENTIFICATION
***************** EMERGENCY OVERVIEW *****************
* *
* CAUTION *
* *
* Contains Diphenylmethane Diisocyanate. Inhalation *
* of MDI mists or vapors may cause respiratory *
* irritation, breathlessness, chest discomfort and *
* reduced pulmonary function. Overexposure well *
* above the PEL may result in bronchitis, bronchial *
* spasms and pulmonary edema. Long-term exposure to *
* isocyanates has been reported to cause lung damage, *
* including reduced lung function which may be *
* permanent. Acute or chronic overexposure to *
* isocyanates may cause sensitization in some *
* individuals, resulting in allergic respiratory *
* reactions including wheezing, shortness of breath, *
* and difficulty breathing. *
* *
**********************************************************
HMIS Rating - Health: *2
Flammability: 1
Reactivity: 1
NFPA/HMIS Definitions: (0-Least, 1-Slight, 2-Moderate, 3-High,
4-Extreme). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or
the National Paint and Coating Association (for HMIS ratings).
POTENTIAL HEALTH EFFECTS
OlyBond 500, Part 1 (Dark Brown) Page 3
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
(section 3 continued)
EYE:
Contact may cause eye irritation. May result in corneal opacity (clouding
of the eye surface).
SKIN:
Causes skin burns, irritation, and possible allergic reaction. In those
who have developed skin sensitization, these symptoms can develop as a
result of contact with a very small amount of the liquid material.
INHALATION:
Inhalation of MDI vapors may cause irritation of the mucous membranes of
the nose, throat or trachea, breathlessness, chest discomfort, difficult
breathing and reduced pulmonary function.
INGESTION:
Harmful if swallowed. Can burn mouth, throat, and stomach.
Gastrointestinal symptoms include nausea, vomiting and abdominal pain.
CHRONIC EFFECTS:
As a result of previous repeated overexposures or a single large dose,
certain individuals will develop isocyanate sensitization (chemical
asthma) which will cause them to react to a later exposure to isocyanate
at levels well below the PEL/TLV. These symptoms, which include chest
tightness, wheezing, cough, shortness of breath, or asthmatic attack,
could be immediate or delayed up to several hours after exposure. Chronic
overexposure to isocyanates has also been reported to cause lung damage,
including a decrease in lung function, which may be permanent.
Sensitization may be either temporary or permanent. Prolonged contact can
cause reddening, swelling, rash, scaling, or blistering. In those who
have developed skin sensitization, these symptoms can develop as a result
of contact with very small amounts of liquid material.
REPRODUCTIVE HAZARDS:
No birth defects or teratogenic effects were reported in a teratology
study with rats exposed to 1, 4 and 12mg/m3 polymeric MDI for 6 hr/day on
days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at
the top dose in the presence of maternal toxicity.
CARCINOGENICITY INFORMATION:
Listed by IARC and NTP as a carcinogen.
MEDICAL CONDITIONS AGRAVATED BY EXPOSURE:
Individuals who are sensitized to isocyanates and those with preexisting
lung disease or conditions, including non-specific bronchial
hyperreactivity or asthma, must avoid all exposure to isocyanates.
OlyBond 500, Part 1 (Dark Brown) Page 4
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
4. FIRST AID MEASURES
EYE CONTACT FIRST AID:
After initial flushing, remove any contact lenses and continue flushing
for at least 15 minutes. Get immediate medical attention.
SKIN CONTACT FIRST AID:
Remove contaminated clothing and shoes. Wash affected area immediately
with large amounts of soap and water. Get medical attention immediately.
INHALATION FIRST AID:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. Get immediate medical attention.
INGESTION FIRST AID:
If swallowed, immediately give 2 glasses of water. Do not induce
vomiting. Contact a physician. Never give anything by mouth to an
unconscious person. Get immediate medical attention.
NOTES TO PHYSICIAN:
There is no antidote to counteract the effects of MDI. Care should be
supportive and treatment should be based on the judgment of the physician
in response to the action of the patient.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
COC Flash Point: 220 C (428.0 F)
Autoignition Temperature: N/A
FLAMMABLE LIMITS IN AIR
LEL: N/A
UEL: N/A
FLAMMABLE PROPERTIES:
Full emergency equipment with self contained breathing apparatus and full
protective clothing should be worn. At temperatures greater than 400 F
material may polymerize causing pressure build up in closed containers.
Explosive rupture is possible. Use cold water to cool containers exposed
to fire.
EXTINGUISHING MEDIA:
Water, carbon dioxide, foam or dry powder.
OlyBond 500, Part 1 (Dark Brown) Page 5
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
(section 5 continued)
FIRE & EXPLOSION HAZARDS:
Material will burn in a fire.
FIRE FIGHTING INSTRUCTIONS:
As in any fire, wear self-contained breathing apparatus pressure-demand
MSHA/NIOSH (approved or equivalent) and full protective gear.
MISCELLANEOUS:
Reacts with water to form carbon dioxide gas, which may create excessive
pressure in containers. Reacts exothermically with polyol and alcohols.
Reacts exothermically and possibly violently with acids, amines and
alkaline solutions.
6. ACCIDENTAL RELEASE MEASURES
SAFEGUARDS (PERSONNEL):
Evacuate non-emergency personnel to a safe area. Avoid breathing vapor.
Ventilate spill area. Wear safety goggles. Wear appropriate personal
protective equipment.
INITIAL CONTAINMENT:
Contain spilled material. Absorb spills with inert material. Place in
closed containers but do not seal.
LARGE SPILLS PROCEDURE:
Absorb spill with inert material (e g, dry sand or earth), then place in a
chemical waste container.Place in closed containers but do not seal.
Neutralize spill with mixture of 90% water, 3-8% ammonia and 2-7%
detergent. Add at a 10 to 1 ratio and let stand for 48 hrs allowing CO2
to escape.
MISCELLANEOUS:
Do not discharge into drains/surface waters/groundwater.
7. HANDLING AND STORAGE
RECOMMENDED STORAGE TEMPERATURE
Minimum: 15.6 C (60.1 F)
Maximum: 26.7 C (80.1 F)
SHELF LIFE: (in original, sealed containers)
18 months @ 26.7 C
OlyBond 500, Part 1 (Dark Brown) Page 6
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
(section 7 continued)
HANDLING (PERSONNEL):
Avoid contact with eyes. Avoid prolonged or repeated contact with skin.
Wash hands thoroughly after handling. Do not reuse this container.
HANDLING (PHYSICAL ASPECTS):
Provide appropriate ventilation. Close container after each use. Keep
container closed to avoid contamination. Keep out of reach of children.
STORAGE PRECAUTIONS:
Avoid extreme temperatures. Keep container closed when not in use. Store
in a cool dry place.
SPECIAL SENSITIVITY:
All handling equipment should be electrically grounded.
MISCELLANEOUS:
Protect from moisture.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower. Use process enclosures, local
exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits.
EYE / FACE PROTECTION REQUIREMENTS:
Wear safety glasses. A respiratory protection program that meets OSHA's
29 CFR 1910-134 and ANSI Z88-2 requirements must be followed whenever
workplace conditions warrant a respirator's use.
SKIN PROTECTION REQUIREMENTS:
Selection of specific items such as gloves, boots, apron or full-body suit
will depend on operation.
RESPIRATORY PROTECTION REQUIREMENTS:
When there is potential for airborne exposures in excess of applicable
limits, wear NIOSH/MSHA approved respiratory protection.
EXPOSURE GUIDELINES:
No Information Available.
OlyBond 500, Part 1 (Dark Brown) Page 7
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
FORM .....................: Liquid
COLOR ....................: Dark Brown
ODOR .....................: Aromatic
BOILING POINT ............: 200 C @ 5 mm Hg
VAPOR PRESSURE ...........: 0.00001 mm Hg @ 20 C
SOLUBILITY IN WATER ......: Reacts with water
SPECIFIC GRAVITY .........: 1.22 (Water = 1)
BULK DENSITY .............: 10.16 lb/USg
MELTING/FREEZING POINT ...: 3C
VISCOSITY ................: 200 cps
10. STABILITY AND REACTIVITY
STABILITY:
Stable.
POLYMERIZATION:
May occur.
INCOMPATIBILITY WITH OTHER MATERIALS:
Reacts with water, with formation of carbon dioxide. Risk of bursting.
Reacts with alcohols, acids, alkalies, amines. Risk of exothermic
reaction. Risk of violent reaction. Contact with certain rubbers and
plastics can cause brittleness of the substance with subsequent loss in
strength.
DECOMPOSITION:
Hazardous decomposition products: carbon monoxide, hydrogen cyanide,
nitrogen oxides, aromatic isocyanates, gases/vapors.
CONDITIONS TO AVOID:
Avoid moisture.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL EFFECTS:
LD50/rat: > 10,000 mg/kg. Practically nontoxic.
ACUTE INHALATION EFFECTS:
LD50/rat: > 2.240 mg/l / 1h
Moderately toxic.
OlyBond 500, Part 1 (Dark Brown) Page 8
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
No information available.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Treat or dispose of waste material in accordance with all local,
state/provincial, and national requirements.
CONTAINER DISPOSAL:
Steel drums must be emptied and can be sent to a licensed drum
reconditioner for reuse, a scrap metal dealer, or an approved landfill.
Recommend crushing, puncturing or other means to prevent unauthorized use
of used containers.
14. TRANSPORTATION INFORMATION
PRODUCT LABEL ...: OlyBond 500, Part 1 (Dark Brown)
15. REGULATORY INFORMATION
Canadian Disclosure List
4,4'-DIPHENYLMETHANE DIISOCYANATE (101-68-8)
SARA Title III - Section 313
4,4'-DIPHENYLMETHANE DIISOCYANATE (101-68-8) --
Polymeric MDI (9016-87-9) --
MDI MIXED ISOMERS (26447-40-5) --
Title V
4,4'-DIPHENYLMETHANE DIISOCYANATE (101-68-8)
SC Toxic Air Pollutants List
4,4'-DIPHENYLMETHANE DIISOCYANATE (101-68-8)
OlyBond 500, Part 1 (Dark Brown) Page 9
MSDS Number: foam00 February 23, 2007
____________________________________________________________________________________________________
16. OTHER INFORMATION
PREPARED BY .......: N/A
APPROVED BY .......: Laura Vollenweider
TITLE .............: Chemist
APPROVAL DATE .....: February 23, 2007
SUPERCEDES DATE ...: June 5, 2006
MSDS NUMBER .......: foam00
RTN NUMBER ........: 00000114 (Official Copy)
ADDITIONAL INFORMATION:
The data in this Material Safety Data Sheet relates only to the specific
material designated herein.
**********************************************************************
To the best of our knowledge, the information contained in this MSDS is
accurate. It is intended to assist the user in his evaluation of the
product's hazards, and safety precautions to be taken in its use. The
data in this MSDS relate only to the specific material designated herein.
We do not assume liability for the use of, or reliance on this
information, nor do we guarantee its accuracy or completeness.
**********************************************************************
END OF MSDS
**********************************************************************
OlyBond 500 Part 2 (Red) Page 1
MSDS Number: foam00ob500 February 23, 2007
________________________________________
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
______________________
Product Identification
Product Name: OlyBond 500 Part 2 (Red)
Product Number: pails, drums, totes
Chemical Name: Polyurethane System Resin
Component
Chemical Family: NA
CAS Number: Blend
Company Identification
______________________
ERSystems- Elastomeric Roofing Systems, Inc.
6900 Bleck Dr.
Rockford, MN 55373 USA
1-800-403-7747 (For product information)
1-800-535-5053 Infotrac (For emergencies)
SPECIAL NOTES:
Polyurethane foam system resin component. Part B (Part 2) of a two part
system.
2. COMPOSITION/INFORMATION ON INGREDIENTS
100.0% OlyBond 500 Part 2 (Red)
CONTAINING:
HAZARDOUS AND/OR REGULATED COMPONENTS
Chemical Name
_____________ ________
Amount CAS Number
__________
ANILINE < 0.1 % 62-53-3
ETHYLENE OXIDE < 0.1 % 75-21-8
NON-HAZARDOUS COMPONENTS
_____________
Chemical Name Amount
________ __________
CAS Number
DIETHYLENE GLYCOL < 10.0 % 111-46-6
DIPROPYLENE GLYCOL < 10.0 % 25265-71-8
1,4-DIOXANE < 0.1 % 123-91-1
ACETALDEHYDE < 0.1 % 75-07-0
OlyBond 500 Part 2 (Red) Page 2
MSDS Number: foam00ob500 February 23, 2007
____________________________________________________________________________________________________
(section 2 continued)
(See Section 8 for exposure guidelines)
(See Section 15 for regulatory information)
3. HAZARDS IDENTIFICATION
***************** EMERGENCY OVERVIEW *****************
* *
* CAUTION *
* *
* May be harmful if swallowed. *
* *
**********************************************************
HMIS Rating - Health: 1
Flammability: 0
Reactivity: 0
Personal Protection Index: S
POTENTIAL HEALTH EFFECTS
EYE:
Contact may cause eye irritation and injury.
SKIN:
Not expected to be a skin irritant. A single, prolonged exposure is not
likely to result in the material being absorbed through skin in harmful
amounts.
INHALATION:
Avoid breathing vapors or mists. Prolonged or excessive inhalation may
cause respiratory tract irritation.
INGESTION:
Harmful if swallowed.
4. FIRST AID MEASURES
OlyBond 500 Part 2 (Red) Page 3
MSDS Number: foam00ob500 February 23, 2007
____________________________________________________________________________________________________
(section 4 continued)
EYE CONTACT FIRST AID:
After initial flushing, remove any contact lenses and continue flushing
for at least 15 minutes. Get medical attention if irritation develops or
persists.
SKIN CONTACT FIRST AID:
Get medical attention if irritation develops or persists.
INGESTION FIRST AID:
If swallowed get immediate medical attention. Do not induce vomiting.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
PMCC Flash Point: 190.6 C (375.1 F)
Autoignition Temperature: N/A
FLAMMABLE LIMITS IN AIR
LEL: N/A
UEL: N/A
FLAMMABLE PROPERTIES:
Full emergency equipment with self contained breathing apparatus and full
protective clothing should be worn.
EXTINGUISHING MEDIA:
Water, carbon dioxide, foam or dry powder. Do not use a direct water
stream.
FIRE FIGHTING INSTRUCTIONS:
As in any fire, wear self-contained breathing apparatus pressure-demand
MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
SAFEGUARDS (PERSONNEL):
Isolate spill area. May be a slipping hazard.
INITIAL CONTAINMENT:
Contain spilled material. Absorb spills with inert material.
OlyBond 500 Part 2 (Red) Page 4
MSDS Number: foam00ob500 February 23, 2007
____________________________________________________________________________________________________
(section 6 continued)
LARGE SPILLS PROCEDURE:
Absorb spill with inert material (e g, dry sand or earth), then place in a
chemical waste container. Treat or dispose of waste material in
accordance with all local, state/provincial, and national requirements.
SMALL SPILLS PROCEDURE:
Absorb spills with inert material. Treat or dispose of waste material in
accordance with all local, state/provincial, and national requirements.
7. HANDLING AND STORAGE
RECOMMENDED STORAGE TEMPERATURE
Minimum: 15.6 C (60.1 F)
Maximum: 26.7 C (80.1 F)
SHELF LIFE: (in original, sealed containers)
18 months @ 26.7 C
HANDLING (PERSONNEL):
Avoid contact with eyes, skin, and clothing. Wash hands thoroughly after
handling.
HANDLING (PHYSICAL ASPECTS):
Provide appropriate ventilation. Close container after each use. Keep
container closed to avoid contamination. Keep out of reach of children.
STORAGE PRECAUTIONS:
Avoid extreme temperatures. Keep container closed when not in use. Store
in a cool dry place.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE / FACE PROTECTION REQUIREMENTS:
Wear safety glasses. A respiratory protection program that meets OSHA's
29 CFR 1910-134 and ANSI Z88-2 requirements must be followed whenever
workplace conditions warrant a respirator's use.
SKIN PROTECTION REQUIREMENTS:
Selection of specific items such as gloves, boots, apron or full-body suit
will depend on operation. Wash hands thoroughly after handling. Product
produces slippery conditions.
OlyBond 500 Part 2 (Red) Page 5
MSDS Number: foam00ob500 February 23, 2007
____________________________________________________________________________________________________
(section 8 continued)
RESPIRATORY PROTECTION REQUIREMENTS:
When there is potential for airborne exposures in excess of applicable
limits, wear NIOSH/MSHA approved respiratory protection.
EXPOSURE GUIDELINES:
ETHYLENE OXIDE
Recommended Exposure Limit: 1 ppm
Odor Threshold: 257-690 ppm
Immediate Lethal Dosage: 800 ppm
ACETALDEHYDE
Recommended Exposure Limit: 25 ppm
Odor Threshold: 0.067 ppm
Immediate Lethal Dosage: 10000 ppm
OSHA PEL: 200 ppm, 360 mg/m^3
OSHA TWA: 100 ppm, 180 mg/m^3
OSHA STEL: 150 ppm, 270 mg/m^3
OSHA Ceiling Limit: 25 ppm, 45 mg/m^3
9. PHYSICAL AND CHEMICAL PROPERTIES
FORM ..................: Liquid
COLOR .................: Amber or red
ODOR ..................: Slight, sweet odor
BOILING POINT .........: NA F
SOLUBILITY IN WATER ...: Slight
BULK DENSITY ..........: 8.5
VISCOSITY .............: 400 cps
10. STABILITY AND REACTIVITY
STABILITY:
Stable. Do not heat.
DECOMPOSITION:
Decomposition will not occur if handled and stored properly.
11. TOXICOLOGICAL INFORMATION
No information available.
OlyBond 500 Part 2 (Red) Page 6
MSDS Number: foam00ob500 February 23, 2007
____________________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
No information available.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Treat or dispose of waste material in accordance with all local,
state/provincial, and national requirements.
14. TRANSPORTATION INFORMATION
PRODUCT LABEL .............: OlyBond 500 Part 2 (Red)
D.O.T. SHIPPING NAME ......: N/A
TECHNICAL SHIPPING NAME ...: N/A
D.O.T. HAZARD CLASS .......: N/A
UN NUMBER .................: N/A
15. REGULATORY INFORMATION
CERCLA Hazardous Substances
1,4-DIOXANE (123-91-1) -- RQ 100 lb
ACETALDEHYDE (75-07-0) -- RQ 1000 lb
RCRA Hazardous Substances
1,4-DIOXANE (123-91-1) -- RCRA Code: U108
ACETALDEHYDE (75-07-0) -- RCRA Code: U001
Clean Air Act - Section 112
ETHYLENE OXIDE (75-21-8)
Title V
ANILINE (62-53-3)
ETHYLENE OXIDE (75-21-8)
1,4-DIOXANE (123-91-1)
CA Proposition 65
ANILINE (62-53-3)
ETHYLENE OXIDE (75-21-8)
1,4-DIOXANE (123-91-1)
ACETALDEHYDE (75-07-0)
OlyBond 500 Part 2 (Red) Page 7
MSDS Number: foam00ob500 February 23, 2007
____________________________________________________________________________________________________
(section 15 continued)
SC Toxic Air Pollutants List
ANILINE (62-53-3)
ETHYLENE OXIDE (75-21-8)
1,4-DIOXANE (123-91-1)
ACETALDEHYDE (75-07-0)
16. OTHER INFORMATION
PREPARED BY .......: N/A
APPROVED BY .......: Laura Vollenweider
TITLE .............: Chemist
APPROVAL DATE .....: February 23, 2007
SUPERCEDES DATE ...: January 30, 2007
MSDS NUMBER .......: foam00ob500
RTN NUMBER ........: 00000026 (Official Copy)
ADDITIONAL INFORMATION:
The data in this Material Safety Data Sheet relates only to the specific
material designated herein.
**********************************************************************
To the best of our knowledge, the information contained in this MSDS is
accurate. It is intended to assist the user in his evaluation of the
product's hazards, and safety precautions to be taken in its use. The
data in this MSDS relate only to the specific material designated herein.
We do not assume liability for the use of, or reliance on this
information, nor do we guarantee its accuracy or completeness.
**********************************************************************
END OF MSDS
**********************************************************************
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