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479-19-8 7732-18-5 7757-82-6 7647-14-5 77-92-9 1344-09-8 68479-09-4 10332-33-9 9000-90-2

File Name: 479-19-8_7732-18-5_7757-82-6_7647-14-5_77-92-9_1344-09-8_68479-09-4.asp

                             MATERIAL SAFETY DATA SHEET
SECTION I: PRODUCT IDENTIFICATION AND USE
Product Name: Automatic Dishwashing Detergent Powder
Manufacturer's Name: Seventh Generation, Inc. Address: 60 Lake Street, Burlington, VT 05401-5281
Emergency Telephone Number: 800-456-1191 Product Use: Automatic Dishwashing
SECTION II: HEALTH HAZARD DATA
Emergency Overview: Contact with eyes may cause irritation.
Potential Health Effects:
Eyes- Ocular Irritant
Skin- Non-Irritant
Inhalation- Unknown
Ingestion- Non-Toxic
SECTION III: PRODUCT INGREDIENTS
Concentration CAS Exposure Toxicity Data
Ingredient Name (%) Number Limits LD50(oral, rat)
Sodium Carbonate 10-100 479-19-8 TLV 10 mg/m3 2,800 mg/kg
Water 1-10 7732-18-5 NAV NAV
Sodium Sulphate 3-30 7757-82-6 NAV Oral LD50 mouse 5,989
Sodium Chloride 3-30 7647-14-5 NAV 3,000 mg/kg
mg/kg
Citric Acid 3-30 77-92-9 NAV NAV
Sodium Silicate 0.1-10 1344-09-8 NAV NAV
Polymeric salt 0.1-10 68479-09-4 NAV >5,000 mg/kg
Ethoxylated/Propoxylated Alcohol 0.5-5 N/A NAV NAV
0.5-5 10332-33-9 NAV (female) 890; (male)
Sodium Perborate Monohydrate 1,300 mg/kg
Enzyme Protease 0.1-1 01/01/9014 TLV 0.00006 mg/m3 >2,000 mg/kg
Enzyme Amylase 0.1-1 9000-90-2 NAV >2,000 mg/kg
SECTION IV: FIRST AID MEASURES
First Aid Procedures:
Eyes- Flush eyes with water immediately after contact. Call a physician if irritation persists.
Skin- Not Applicable
Inhalation- Leave the dusty area and seek fresh air exposure. Call a physician if irritation persists.
Ingestion- Drink 4-8 ounces of water or milk immediately. If prolonged nausea or pain occurs call a doctor.
SECTION V: FIRE FIGHTING MEASURES
Flash Point (C) and Method: Not Applicable
Extinguishing Media: Not Applicable
Special Procedures: None
SECTION VI: ACCIDENTIAL RELEASE MEASURES
Spill and Leak Precautions: Wet the spill and clean up with a paper towel.
SECTION VII: HANDLING, DISPOSAL & STORAGE
Handling Procedures and Equipment: Wear PPE when handling powder or dust.
Waste Disposal: Any disposal practice must be in compliance with local, state, and federal laws and regulations.
Storage Procedures: KEEP OUT OF REACH OF CHILDREN & PETS. Store in a cool, dry place away from excess heat.
Personal Protective Equipment: 3M 8233 mask or equivalent
Engineering Controls: Local Exhaust Ventilation
SECTION VIII: PHYSICAL & CHEMICAL PROPERTIES
Physical State: Solid
Color & Appearance: White Granular Powder
pH: 9.5-10.5
Specific Gravity: Not Applicable
Solubility in Water: Complete at 25C
Automatic Dishwashing Detergent Powder
Percent Volatiles: <5%
Density (g/cc): 1.02 +/- 0.1
Odor Threshold Limit: Not Applicable
SECTION IX: STABILITY & REACTIVITY
Chemical Stability: Stable Unstable under the following conditions:
Incompatible Materials: None Known
Hazardous Decomposition Products: None Known
Possibility of Hazardous Reactions: None Known
SECTION X: TOXICOLOGICAL INFORMATION
Route(s) of Entry:
Skin Contact Skin Absorption Eye Contact Inhalation, Acute Inhalation, Chronic Ingestion
Effects of Acute Exposure to Product: Acute exposure may irritate the respiratory tract;
however no permanent damage is expected.
Effects of Chronic Exposure to Product: NAP
LD50 of Product: >5000mg/kg
Chronic Toxicities: Carcinogenic Reproductive Toxin Teratogenic Mutagenic None
SECTION XI: ECOLOGICAL INFORMATION
Ecotoxicity: LC50 of Product: Not yet known
Environmental Fate: This product is biodegradable.
SECTION XII: PREPARATION INFORMATION
Additional Information: The information in this MSDS relates only to the specific material designated herein and does not
relate to use in combination with any other material or any process.
Sources Used: General MSDS chemical references
Prepared by Telephone Number Issue Date
Seventh Generation, Inc. 800-456-1191 March 9, 2009
The information contained in this Material Safety Data Sheet is provided by Seventh Generation, Inc. free of charge. While
believed to be reliable, it is intended for use by skilled persons at their own risk. Seventh Generation, Inc. assumes no
responsibility for events resulting from, or damages incurred from, its use.

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