CP RA PROF D/R PART A
Safety Data Sheet
1. Identification of Substance & Company
Product
Product name CP RA PROF D/R PART A
Other names Not applicable
Product code 822545
722545
HSNO approval Photographic Chemicals (Subsidiary Hazard) Group Standard 2006,
HSR002638
UN number Not applicable
Packaging group Not applicable
Hazchem code 1T
Poison schedule Not applicable
Uses Fujihunt Photofinishing Color Paper
Company Details
Company FUJIFILM (New Zealand) Limited
Address Cnr William Pickering Dr & Bush Rd
Albany
Auckland
Telephone +64 9 414 0400
Website www.fujifilm.co.nz
Emergency Telephone Number: 0800-764 766
2. Hazard Identification
Hazard Classifications
This product has been approved under the Hazardous Substances and New Organisms Act (HSNO, Approval Photographic
Chemicals (Subsidiary Hazard) Group Standard 2006), and is classified as follows:
Classes:
6.3A skin irritant
6.4A eye irritant
6.6B suspected mutagen
SYMBOLS
WARNING
Other Classifications
There are no other classifications that are known to apply.
Hazard and Precautionary Statements
Hazard Causes skin irritation.
Causes eye irritation.
Suspected of causing genetic defects.
Precautionary Keep out of reach of children. Read label before use.
Obtain special instructions before use. Do not handle until all safety precautions have been read and
understood.
Wear protective gloves, eye/face protection.
Wash hands thoroughly after handling.
Further precautionary statements can be found in Section 4 ?First Aid.
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CP RA PROF D/R PART A
Safety Data Sheet
3. Composition / Information on Ingredients
Component CAS/ Class for ingredient(s) Conc
Identification (% w/w)
Bis Triazinylamino Stilbene Acid 12270-52-9 non-hazardous 1 ?5%
Derivative
Polyvinylpyrrolidone 9003-39-8 6.1D, 9.3C 1 ?5%
Sodium Chloride 7647-14-5 6.1E (oral), 6.4A 1 ?5%
N,N'-Diethyl Hydroxylamine 3710-84-7 3.1C, 6.3A, 6.4A, 6.6B, 9.1C 7 ?15%
Triethanolamine 102-71-6 6.1E (oral), 6.3B, 6.4A, 9.2D 15 ?30%
Water 7732-18-5 non hazardous 50 ?70%
This is a commercial product whose exact ratio of components may vary. Trace quantities of impurities are also likely.
4. First Aid
General Information
You should call the National Poisons Centre if you feel that you may have been poisoned, burned or irritated by this product.
The number is 0800 764 766 (0800 POISON) (24 hr emergency service).
If medical advice is needed, have this MSDS, product container or label at hand. . If exposed or concerned: Get medical
advice/ attention.
Recommended first aid Ready access to running water is required. Accessible eyewash is recommended.
facilities Emergency shower, hand wash, soap. CPR training, oxygen mask.
Exposure
Swallowed IF SWALLOWED: Do NOT induce vomiting. Rinse mouth. Contact a doctor if you feel
unwell. If vomiting occurs, place victim face downwards, with the head turned to the side
and lower than the hips to prevent vomit entering the lungs.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Apply continuous irrigation with water for at
least 15 minutes holding eyelids apart. Immediately call a POISON CENTER or
doctor/physician.
Skin contact IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get
medical advice/attention. Take off contaminated clothing and wash before re-use.
Inhaled Generally, inhalation of fumes is unlikely to result in adverse health effects. If coughing,
dizziness or shortness of breath is experienced, remove the patient to fresh air
immediately. If patient is unconscious, place in the recovery position (on the side) for
transport and contact a doctor.
Advice to Doctor
Treat symptomatically
5. Firefighting Measures
Fire and explosion hazards: There are no specific risks for fire/explosion for this chemical. It is non-flammable.
Suitable extinguishing Carbon dioxide, extinguishing powder, foam, fog sprays, water jets.
substances:
Unsuitable extinguishing Unknown.
substances:
Products of combustion: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water.
May form toxic mixtures in air and may accumulate in sumps, pits and other low-lying
spaces, forming potentially explosive mixtures.
Protective equipment: Self-contained breathing apparatus. Safety boots, non-flammable overalls, gloves, hat
and eye protection.
Hazchem code: 1T
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Safety Data Sheet
6. Accidental Release Measures
Containment There is no current legal requirement for containment of this product.
Emergency procedures In the event of spillage alert the fire brigade to location and give brief description of
hazard.
Wear protective equipment to prevent skin, eye and respiratory exposure.
Clear area of any unprotected personnel.
Contain using sand, earth or vermiculite. Do not use sawdust on concentrate.
Prevent by whatever means possible any spillage from entering drains, sewers, or water
courses. (If this occurs contact your regional council immediately).
Clean-up method Use absorbent (soil, sand or other inert material). Rags are not recommended for the
clean-up of spills, as they may create fire or environmental hazard. Collect and seal in
properly labelled containers or drums for disposal. If contamination of crops, sewers or
waterways has occurred advise local emergency services.
Disposal Mop up and collect recoverable material into labelled containers for recycling or salvage.
Recycle containers wherever possible. This material may be suitable for approved
landfill. Dispose of only in accord with all regulations.
Precautions Wear protective equipment to prevent skin and eye contamination and the inhalation of
vapours. Work up wind or increase ventilation.
7. Storage & Handling
Storage Avoid storage of harmful substances with food. Store out of reach of children.
Containers should be kept closed in order to minimise contamination. Keep from
extreme heat and open flames. Avoid contact with incompatible substances as listed in
Section 10.
Handling Keep exposure to a minimum, and minimise the quantities kept in work areas. See
section 8 with regard to personal protective equipment requirements. Avoid skin and eye
contact and inhalation of vapour, mist or aerosols.
8. Exposure Controls / Personal Protective Equipment
Workplace Exposure Standards
A workplace exposure standard (WES) has not been established by the NZ Department of Labour for this product. There is a
3
general limit of 10mg/m for dusts and mists when limits have not otherwise been established.
NZ Workplace Ingredient WES-TWA WES-STEL
Exposure Stds Bis Triazinylamino Stilbene Acid Derivative Data unavailable Data unavailable
(OSH 2002) Polyvinylpyrrolidone Data unavailable Data unavailable
Sodium Chloride Data unavailable Data unavailable
N,N'-Diethyl Hydroxylamine Data unavailable Data unavailable
3
Triethanolamine 5mg/m Data unavailable
Engineering Controls
In industrial situations, it is expected that employee exposure to hazardous substances will be controlled to a level as far
below the WES as practicable by applying the hierarchy of control required by the Health and Safety in Employment Act 1992
(HSE). Exposure can be reduced by process modification, use of local exhaust ventilation, capturing substances at the
source, or other methods. If you believe air borne concentrations of mists, dusts or vapours are high, you are advised to
modify processes or increase ventilation.
Personal Protective Equipment
Eyes Protect eyes with goggles, safety glasses or full face mask. Avoid wearing contact
lenses.
Skin Avoid repeated or prolonged skin contact. Wear overalls, rubber boots and impervious
gloves. Remove protective clothing and wash exposed areas with soap and water prior to
eating, drinking or smoking.
Respiratory A respirator when airborne concentrations approach the WES (section 8). Use a half face
respirator with organic vapour cartridges.. If using a respirator, ensure that the cartridges
are correct for the potential air contamination and are in good working order.
WES Additional Information
Not applicable
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Safety Data Sheet
9. Physical & Chemical Properties
Appearance Yellowish orange liquid
Odour Slight amine odour
pH 10.87 @25癈
Vapour pressure Not available
Viscocity Like water
Boiling point >100癈
Volatile materials Not applicable
Freezing / melting point Not available
Solubility Completely water soluble
Specific gravity / density 1.052 g/mL
Flash point Non flammable
Danger of explosion Not explosive
Auto-ignition temperature Non flammable
Upper and lower flammable Non flammable
limits
Corrosiveness Non corrosive to metals
10. Stability & Reactivity
Stability This product is unlikely to react or decompose under normal storage conditions. This
product will not undergo polymerisation reactions.
Conditions to be avoided Containers should be kept closed in order to avoid contamination. Keep from extreme
heat and open flames.
Incompatible groups None known
Substance Specific There are no specific incompatibilities for this chemical.
Incompatibility
Hazardous decomposition Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen,
products and under some circumstances, oxides of nitrogen. Water.
Hazardous reactions No specific hazards.
11. Toxicological Information
Summary
No specific data is available for this product. Where available, toxicological data has been researched and data for the
mixture calculated. The results of these calculations are presented below. The product is considered to have the following
toxicity:
Supporting Data
Acute Oral No data for mixture is available. Using LD50's for ingredients, the calculated LD50 (oral,
rat) for the mixture is between 300 and 2,000 mg/kg. Data considered includes: Bis
Triazinylamino Stilbene Acid Derivative: no data, Polyvinylpyrrolidone: 1040 mg/kg
(rabbit), Sodium Chloride: 3000mg/kg (rat), N,N'-Diethyl Hydroxylamine: no data,
Triethanolamine: 2200 mg/kg bw (rabbit).
Dermal No data for mixture is available. Using LD50's for ingredients, the estimated LD50 (dermal,
rat) for the mixture is >2,000 mg/kg. Data considered includes: Bis Triazinylamino
Stilbene Acid Derivative: no data, Polyvinylpyrrolidone: no data, Sodium Chloride: no
data, N,N'-Diethyl Hydroxylamine: no data, Triethanolamine: no data.
Inhaled No data for mixture is available. Using LC50's for ingredients, the estimated LC50
(inhalation, rat) for the mixture is >5,000 ppm. Data considered includes: Bis
Triazinylamino Stilbene Acid Derivative: no data, Polyvinylpyrrolidone: no data, Sodium
Chloride: no data, N,N'-Diethyl Hydroxylamine: no data, Triethanolamine: no data.
Eye The mixture is considered to be irritating to the eye, because some of the ingredients
(N,N'-Diethyl Hydroxylamine, sodium chloride, triethanolamine), present at >3% are
considered eye irritant.
Skin The mixture is considered to be a skin irritant, because some of the ingredients present
(N,N'-Diethyl Hydroxylamine, triethanolamine) are considered skin irritants in more
concentrated form.
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Safety Data Sheet
Chronic Sensitisation The mixture is not considered to be a contact sensitizer, because none of the ingredients
present in greater than 0.1% are known to be sensitizers.
Mutagenicity The mixture is considered to be a suspected mutagen, because at least one of the
ingredients present in greater than 0.1% (N,N'-diethyl hydroxylamine) is suspected to be
a mutagen.
Carcinogenicity No data for mixture is available. No ingredient present at concentrations > 0.1% is
considered a carcinogen.
Reproductive / No data for mixture is available. No ingredient present at concentrations > 0.1% is
Developmental considered a reproductive or developmental toxicant or have any effects on or via
lactation.
Systemic The mixture is not considered to be a target organ toxicant, because none of the
ingredients present in greater than 1% are suspected to be target organ toxicants.
Aggravation of None known.
existing conditions
12. Ecological Data
Summary
No specific data is available for this product. Where available, ecotoxicological data has been researched and data for the
mixture calculated. The results of these calculations are presented below. The product is considered to have the following
ecotoxicity groups:
Supporting Data
Aquatic No data for mixture is available. Using EC50's for ingredients, the calculated EC50 for the
mixture is < 1 mg/L. Data considered includes: Bis Triazinylamino Stilbene Acid
Derivative: no data, Polyvinylpyrrolidone: no data, Sodium Chloride:no data, N,N'-Diethyl
Hydroxylamine: 14.960 mg/l (48hr) daphnia, 16.423 mg/l (96hr) algae, Triethanolamine:
Bioaccumulation This product is biodegradable.
Degradability It will not accumulate in the soil or water or cause long term problems.
Soil No data available for the mixture. This product is not classified as ecotoxic in the soil
environment. The soil toxicity value for the mixture is estimated to be 100 mg/kg.
Triethanolamine has an EC50 of: 525 mg/l (30 mins) Photobacterium phosphoreum
(bacteria).
Terrestrial vertebrate This product is considered harmful to terrestrial vertebrates. No LC50 (diet) data for
ingredients are available and the classification is based on the LD50 (oral) ?see section
11 ?oral toxicity.
Terrestrial invertebrate The mixture is not considered harmful to terrestrial invertebrates.
Biocidal Not applicable
Environmental effect levels: Ingredients EEL
Bis Triazinylamino Stilbene Acid Derivative Data unavailable
Polyvinylpyrrolidone Data unavailable
Sodium Chloride Data unavailable
N,N'-Diethyl Hydroxylamine Data unavailable
Triethanolamine Data unavailable
13. Disposal Considerations
Restrictions There are no product-specific restrictions, however, local council and resource consent
conditions may apply, including requirements of trade waste consents.
Disposal method Disposal of this product must comply with the requirements of the Resource Management
Act for which approval should be sought from the Regional Authority. The substance
must be treated and therefore rendered non-hazardous before discharge to the
environment.
Contaminated packaging Rinse containers with water before disposal. Preferably re-cycle container, otherwise
send to landfill or similar.
14. Transport Information
Transport according to NZS 5433 (Transport of Hazardous Substances on Land). Considered a hazardous substance for
transport.
UN number: Proper shipping name:
Not applicable Not applicable
Class(es) Packing group:
Not applicable Not applicable
Precautions: Hazchem code:
Not applicable 1T
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Safety Data Sheet
15. Regulatory Information
This product has been transferred to HSNO (transferred substance), ERMA approval code: HSR002638, Photographic
Chemicals (Subsidiary Hazard) Group Standard 2006.
Specific Workplace Controls (as per HSNO approval referenced to Controls Matrix)
Key workplace requirements are:
To be available within 10 minutes in workplaces storing any quantity.
MSDS
Labelling No removal of labels and/or decanting of product into other containers can
occur.
Emergency plan Not required.
Approved handler Not required.
Tracking Not required.
Bunding and secondary containment Not required.
Signage Not required.
Test certificate Not required.
Other Legislation
In New Zealand, the use of this product may come under the Resource Management Act and Regulations, the Health, Safety
in Employment Act and Regulations, local Council Rules and Regional Council Plans.
16. Other Information
Abbreviations
Approval Photographic Chemicals (Subsidiary Hazard) Group Standard 2006 Controls,
Approval Code
ERMA. www.ermanz.govt.nz
CAS Number Unique Chemical Abstracts Service Registry Number
Controls Matrix List of default controls linking regulation numbers to Matrix code (e.g. T1, I16).
Ecotoxic Concentration 50% ?concentration in water which is fatal to 50% of a test
EC50
population (e.g. daphnia, fish species).
ERMA Environmental Risk Management Authority
Emergency action code of numbers and letters that provide information to emergency
HAZCHEM Code
services, especially fire fighters
HSNO Hazardous Substances and New Organisms (Act and Regulations)
IARC International Agency for Research on Cancer
LD50 Lethal Dose 50% ?dose which is fatal to 50% of a test population (usually rats).
Lethal Concentration 50% ?concentration in air which is fatal to 50% of a test population
LC50
(usually rats).
MSDS Material Safety Data Sheet (or Safety Data Sheet)
OSH The Occupational Safety and Health Service of the Department of Labour (NZ)
UN Number United Nations Number
WES Workplace Exposure Standard
References
Unless otherwise stated comes from the ERMA HSNO chemical classification information
Data database (CCID) http://www.ermanz.govt.nz/hs/compliance/chemicals.html , for specific
chemicals.
ERMA Transfer Gazettes Classifications and controls assigned for specific ingredients (consolidated gazette, 2004)
Controls Matrix Part of the ERMA New Zealand User Guide to the HSNO Control Regulations
The NZ Workplace Exposure Standards Effective from 2002, published by OSH and
WES 2002
available on their web site ?www.osh.dol.govt.nz.
Other References: Fujifilm MSDS Singapore
Disclaimer
This MSDS was prepared by Datachem LTD and is based on our current state of knowledge, including information obtained from suppliers. The MSDS is given in good faith
and constitutes a guideline (not a guarantee of safety). The level of risk each substance poses is relevant to its properties (as summarised in the MSDS) AND HOW THE
SUBSTANCE IS USED. While guidelines are given for personal protective equipment, such precautions must be relevant to the use. The likely HSNO classifications, are
based on our experience, ERMA Guidelines and international classifications. To contact the MSDS author, email info@datachem.co.nz or phone: (09) 940 30 80.
! Datachem
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