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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 15.01.2009 Revision: 09.09.2008
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: 3.1.1
?Application of the substance / the preparation Coating compound for metal surfaces
?Manufacturer/Supplier:
Pulver Kimya San. ve Tic. A.S.
In鰊?Mah. Genclik Cad. No:219
TR-41400 Gebze Kocaeli
?Further information obtainable from:
Mr. 莂atay Pakkan
Department - Laboratory
cpakkan@pulver.com.tr
?Information in case of emergency: +90 262 643 00 01 Mr. 莂atay Pakkan
2 Hazards identification
?Hazard description:
T Toxic
N Dangerous for the environment
?Information concerning particular hazards for human and environment:
The material is dusty. Do not breathe the dust.
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 46 May cause heritable genetic damage.
R 61 May cause harm to the unborn child.
R 20/22 Also harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitisation by skin contact.
R 62 Possible risk of impaired fertility.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
?Additional information: Dust can combine with air to form an explosive mixture.
3 Composition/information on ingredients
?Chemical characterization
?Description: Resin mixture with colouring agents
?Dangerous components:
CAS: 2451-62-9 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione 0.1-5.0%
EINECS: 219-514-3 Muta. Cat. 2; T, Xi; R 46-23/25-41-43-48/22-52/53
CAS: 1344-37-2 Lead sulfochromate yellow >0.25%
EINECS: 215-693-7 Carc. Cat. 3, Repr. Cat. 1, 3; T, N; R 61-62-33-40-50/53
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First aid measures
?General information: Consult doctor in case of symtoms or or in case of dubt.
?After inhalation: Supply fresh air; consult doctor in case of complaints.
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 15.01.2009 Revision: 09.09.2008
Trade name: 3.1.1
(Contd. of page 1)
?After skin contact:
Change contaminated clothes. Wash the skin with water, soap and rinse thoroughly. Do not use solvents or
thinners.
?After eye contact: Rinse opened eye for several minutes under running water.
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Special hazards caused by the substance, its products of combustion or resulting gases:
In case of combustion wear suitable breathing apparatus. Exposure to decomposition products may cause a
health hazard.
?Protective equipment:
Do not inhale explosion gases or combustion gases.
Mouth respiratory protective device.
?Additional information
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water or foam separately. It must not enter the sewage system.
6 Accidental release measures
?Person-related safety precautions:
Avoid formation of dust.
Ensure adequate ventilation
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Avoid formation of dust. Contain and collect spillage with a vacuum cleaner or by wet brushing.
Dispose of the material collected according to regulations.
Dispose contaminated material as waste according to item 13.
?Additional information:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
?Handling:
?Information for safe handling:
Persons with history of respiratory problems or allergic responses should not exposed or handle with powder
coatings.
Avoid the formation of dust development in concentration above flammable, explosive or occupational
Exposure Limit Values.
?Information about fire - and explosion protection:
Protect against electrostatic charges.
Dust can combine with air to form an explosive mixture.
Wear shoes with conductive soles.
?Storage:
?Requirements to be met by storerooms and receptacles:
Electrical equipments should be protected to the appropriate standards. Floors should be electrically
conductive.
?Information about storage in one common storage facility: Store away from foodstuffs.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 15.01.2009 Revision: 09.09.2008
Trade name: 3.1.1
(Contd. of page 2)
?Further information about storage conditions:
Store the product at room temperature. Avoid heat and direct sunlight. No smoking. Always keep the
containers of the same material as the original one.
8 Exposure controls/personal protection
?Additional information about design of technical facilities:
Avoid the inhalation of dust. Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentration of dust below the
relevant occupational exposure limit, suitable respiratory protection must be worn.
?Ingredients with limit values that require monitoring at the workplace:
1344-37-2 Lead sulfochromate yellow
WEL Long-term value: 0.05 mg/m?br>
as Cr; Carc, Sen
2451-62-9 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
WEL Long-term value: 0.1 mg/m?br>
Carc
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
?Respiratory protection:
Breathing protection equipment (for instance: dust mask, filter type P2) required in inadequately ventilated
places and during the spraying.
?Protection of hands:
Leather gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection: Safety glasses
?Body protection:
Use protective suit.
Use suitable protective suit for avoiding electrostatic charges (for example based on cotton textile)
9 Physical and chemical properties
?General Information
Powder
Form:
Different according to colouring
Colour:
Odourless
Odour:
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 15.01.2009 Revision: 09.09.2008
Trade name: 3.1.1
(Contd. of page 3)
?Change in condition
Melting point/Melting range: >50癈 (Kofler)
Boiling point/Boiling range: Undetermined.
Not applicable.
?Flash point:
450-600癈 (VDE0165)
?Ignition temperature:
5-20 mj
?Decomposition temperature:
Product is not selfigniting.
?Self-igniting:
Product is not explosive. However, formation of explosive air/vapour
?Danger of explosion:
mixtures are possible.
?Explosion limits:
20 g/m3
Lower:
70 g/m3
Upper:
See Technical Data Sheet for this information.
?Density:
?Solubility in / Miscibility with
Insoluble.
water:
No change on the pH-value of water.
?pH-value:
?Solvent content:
0.0 %
Organic solvents:
100 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products:
When exposed to high temperatures may produce hazardous decomposition products such as carbon
monoxide and dioxide, smoke, oxides of nitrogen.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
2451-62-9 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
Oral LD50 > 16 g/kg w/w (rat)
Inhalative LD50 > 11 g/m3 (rat)
1344-37-2 Lead sulfochromate yellow
Oral LD50 >10000 mg/kg (rat)
?Primary irritant effect:
?on the skin:
Powder coatings can cause localized skin irritation in folds of the skin or in contact with tight clothing.
?on the eye: Irritating effect.
?Sensitization: Sensitization possible through skin contact.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 15.01.2009 Revision: 09.09.2008
Trade name: 3.1.1
(Contd. of page 4)
The product can cause inheritable damage.
?Sensitisation May cause sensitisation by skin contact.
12 Ecological information
?Ecotoxical effects:
?Acquatic toxicity: Not known.
?Remark: Harmful to fish
?General notes:
Harmful to aquatic organisms
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation
In accordance with local official regulations pass on to an appropriate incinerating plant or depository or
recycling.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 01 11 waste paint and varnish containing organic solvents or other dangerous substances
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: -
?Maritime transport IMDG:
-
?IMDG Class:
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: -
?Transport/Additional information: Not dangerous according to the above specifications.
15 Regulatory information
?Labelling according to EU guidelines:
Observe the general safety regulations when handling chemicals.
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
T Toxic
N Dangerous for the environment
?Hazard-determining components of labelling:
Lead sulfochromate yellow
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
?Risk phrases:
46 May cause heritable genetic damage.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 15.01.2009 Revision: 09.09.2008
Trade name: 3.1.1
(Contd. of page 5)
61 May cause harm to the unborn child.
20/22 Also harmful by inhalation and if swallowed.
33 Danger of cumulative effects.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitisation by skin contact.
62 Possible risk of impaired fertility.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
53 Avoid exposure - obtain special instructions before use.
24/25 Avoid contact with skin and eyes.
36 Wear suitable protective clothing.
38 In case of insufficient ventilation, wear suitable respiratory equipment.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
?Special labelling of certain preparations:
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
23/25 Toxic by inhalation and if swallowed.
33 Danger of cumulative effects.
40 Limited evidence of a carcinogenic effect.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
46 May cause heritable genetic damage.
48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
61 May cause harm to the unborn child.
62 Possible risk of impaired fertility.
?Department issuing MSDS: Department - Laboratory
?Contact: Mr. 莂atay Pakkan
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