SAFETY DATA SHEET
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
UNDERTAKING
ARNEEL 12
Trade name
Chemical description/Application Chemical intermediate
Supplier Akzo Nobel Surface Chemistry AB
SE 444 85 Stenungsund
SWEDEN
Regulatory.AffairsSE@sc.akzonobel.com
Tel: +46 303 850 00
Fax: +46 303 813 06
Emergency telephone + 31 570679211 (Fax. +31 570679801)
Akzo Nobel Chemicals, Deventer, NL
2. COMPOSITION/INFORMATION ON INGREDIENTS
This product is to be considered as a substance according to EU-legislation.
EU number Risk phrases
Substance name CAS number Concentration Symbols
Dodecanenitrile R-38, 50
219-440-1 2437-25-4 100 % Xi ,N
3. HAZARDS IDENTIFICATION
Irritant. Irritating to skin. Dangerous for the environment. Very toxic to aquatic organisms.
4. FIRST AID MEASURES
Inhalation Not relevant.
Skin Remove contaminated clothing. Wash the skin with soap and water. Seek medical advice
if symptoms appears.
Eyes Immediately rinse with water for several minutes. Hold eyelids apart. Obtain medical
attention.
Ingestion Drink a few glasses of water or milk. Contact physician if larger quantity has been
swallowed (show this Safety Data Sheet).
5. FIRE FIGHTING MEASURES
Extinguishing media Water spray, fog or mist, foam, powder, carbon dioxide.
Special fire fighting procedures Treat as an oil fire. Water spray may be ineffective unless used by experienced fire
fighters.
Unusual fire hazards Non-flammable. If involved in a fire it will support combustion.
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Hazardous combustion products Not known.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions For personal protection see Section 8.
Environmental precautions Dispose of this material and its container at hazardous or special waste collection point.
Methods for cleaning up Collect for reclamation. Cover the remainder with inert absorbent (e.g. vermiculite) for
disposal. Place in container for disposal according to local regulations.
7. HANDLING AND STORAGE
Handling The usual precautions for handling chemicals should be observed.
Storage To maintain quality: Avoid elevated temperatures.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limits
Comments No exposure limits have been established.
Engineering controls Provide eyewash station.
Personal protection
Hand Use protective gloves made of: Nitrile. Butyl rubber.
Eyes Wear approved safety goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Liquid.
Colour Light yellow.
Odour Slightly ammonia like
Boiling point/range (篊) Pressure (kPa)
277
Melting point/range (篊) -10
Flash point (篊) Method
100 - 200 Pensky-Martens ISO 2719
Autoignition temperature (篊) > 100
Vapour pressure Temperature (癈)
< ,1 hPa 100
Density (kg/m3) Temperature (癈)
835 20
Solubility in water Insoluble.
Solubility in other solvents Soluble in hydrocarbons.
(These data are typical for the product and not a specification)
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage and handling conditions (see section 7).
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Hazardous decomposition Not known.
products
11. TOXICOLOGICAL INFORMATION
Toxicological data
Health effects
Respiratory Not relevant.
Skin Irritating. May cause transient redness and pain.
Eyes Practically non-irritating.
Ingestion Low acute toxicity.
Dodecanenitrile
Component
Toxicological data LD50. oral rat > 2000 mg/kg ?
Toxicological information 1) The value is estimated from tests on similar products.
12. ECOLOGICAL INFORMATION
Ecotoxicological data
Dodecanenitrile
Component
Ecotoxicological data LC50 96 hours fish 0,1 - 1 mg/l Ref. APAG
EC50 48 hours Daphnia 0,01 - 0,1 mg/l ? Ref. Analogi APAG
Ecotoxicology Very toxic to aquatic organisms.
Degradation Readily biodegradable. (The data are estimated from tests on similar products.)
Other information ? The data are estimated from tests on similar products.
13. DISPOSAL CONSIDERATIONS
Disposal methods Incineration is recommended. Dispose of in accordance with local authority requirements.
14. TRANSPORT INFORMATION
Proper shipping name Environmentally hazardous substance, liquid, n.o.s. (Dodecanenitrile)
Land transport
UN number RID-class
3082 9
ADR class RID packing group
9 III
ADR packing group III
Classification code M6
CEFIC number Tremcard internal code
90GM6-III 900
Sea transport
UN number 3082
IMDG class EmS
9 F-A,S-F
IMDG packing group Marine pollutant
III No.
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Air transport
UN number Subsidary risk
3082 -
IATA/ICAO class Packing group
9 III
15. REGULATORY INFORMATION
Substance name Dodecanenitrile
Symbols
Risk phrases R-38 Irritating to skin.
R-50 Very toxic to aquatic organisms.
Safety phrases S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S-28 After contact with skin, wash immediately with plenty of soap and water.
S-61 Avoid release to the environment. Refer to special instructions/ Safety Data Sheets.
EU number 219-440-1
EU directive Safety Data Sheet according to EC-directive 2001/58/EC
Water hazard classification WGK: 2 (Germany).
16. OTHER INFORMATION
This information only concerns the above mentioned product as supplied and may not be valid if used with other product(s) or in any process. It
remains the user磗 own responsibility to make sure that the information is appropriate and complete for his special use of this product.
Important changes were made in 14
section
Composed by Ann-Christin Borg
Thomas Dahl
Explanations to R-phrases in R-38 Irritating to skin. R-50 Very toxic to aquatic organisms.
section 2
Date of printing 2007-02-22
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