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MSDS Material Safety Data Sheet
CAS

65996-93-2 1330-20-7 1333-86-4 101-68-8 100-41-4 56-55-3 50-32-8 205-99-2

File Name: 65996-93-2_1330-20-7_1333-86-4_101-68-8_100-41-4_56-55-3_50-32.asp

Material Safety Data Sheet



NEO SEAL
Version 3. Print Date 10/31/2009
REVISION DATE: 10/30/2009


SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION

Product Information
Trade name : NEO SEAL
Product code : 071 2A

Supplier : Euclid Canada
2835 Grande-All閑
St-Hubert, QC J4T 2R4
Telephone : 1-800-667-0920
Emergency Phone: : (613) 996-6666


Product use : Coating

Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 10/30/2009
Telephone : (416) 421-3300

SECTION 2 - HAZARDS IDENTIFICATION

Emergency Overview
Black. Liquid. May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and throat.
May cause moderate irritation to the respiratory system. May cause allergic respiratory sensitization. Move to
fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel.
Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.

Acute Potential Health Effects/ Routes of Entry
Inhalation May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and
:
throat. May cause moderate irritation to the respiratory system. May cause allergic
respiratory sensitization.
Eyes Vapor and/or mist may cause eye irritation.
:
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal
:
irritation, nausea, and vomiting.
Skin May cause sensitization resulting in irritation, itching and redness.
:

Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.

Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.
Repeated overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless
suitable engineering controls and/or personal protective equipment are used. Prolonged or repeated exposure
to xylene may cause defatting, drying, and irritation of the skin, dermatitis, central nervous system (CNS)
effects, heart muscle sensitization and arrhythmia, hearing loss, and brain, liver, kidney damage. Xylene
overexposure may affect fetal development. Carbon black is classified by IARC to be a known animal
carcinogen and a possible human carcinogen (Group 2B). Carbon black is encapsulated by resin and not
expected to have adverse effects unless made airborne. Coal tar and pitch may cause rashes, skin sensitivity,
or changes to skin pigmentation. Prolonged or repeated exposure may increase the risk of skin, bladder, kidney


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Material Safety Data Sheet



NEO SEAL
Version 3. Print Date 10/31/2009
REVISION DATE: 10/30/2009

and respiratory cancer unless suitable engineering controls and/or personal protective equipment is used. The
International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and classified it as a possible
human carcinogen (Group 2B) based on sufficient evidence for carcinogenicity in experimental animals, but
inadequate evidence for cancer in exposed humans. Fillers are encapsulated and not expected to be released
from product under normal conditions of use.
Target Organs: Eye, Lung, Liver, Kidney, Skin, Nerve

SECTION 3 : HAZARDOUS INGREDIENTS


Chemical Name CAS-No. Weight % Range
Coal tar pitch 65996-93-2 7.0 - 13.0
Xylene 1330-20-7 1.0 - 5.0
Carbon Black 1333-86-4 0.5 - 1.5
4,4'-Methylene bis(phenylisocyanate) 101-68-8 0.1 - 1.0
Ethylbenzene 100-41-4 0.1 - 1.0
Benzo(a)anthracene 56-55-3 0.1 - 1.0
Benzo(a)pyrene 50-32-8 0.1 - 1.0
Benzo(b)fluoranthene 205-99-2 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).

SECTION 4 - FIRST AID MEASURES

Get immediate medical attention for any significant overexposure.

Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.


SECTION 5: FIRE / EXPLOSION HAZARDS

Flash point : > 200 ?> 93 ?br> F, C
Method : Setaflash Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke,
products fumes.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).



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Material Safety Data Sheet



NEO SEAL
Version 3. Print Date 10/31/2009
REVISION DATE: 10/30/2009

Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Closed
container, may burst when exposed to extreme heat.Empty containers
may contain ignitable vapors.Vapors may travel to sources of ignition
and flashback.


SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES

Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.

SECTION 7 - HANDLING AND STORAGE

Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Change soiled work clothes frequently. Clean hands
thoroughly after handling. Do not smoke, weld, generate sparks, or use flame near container. To prevent
generation of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignition
sources including pilot lights, non-explosion proof motors and electrical equipment until vapors dissipate. Store
under dry warehouse conditions away from heat and all ignition sources.

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved respirator when
airborne contaminant level(s) are expected to exceed exposure limits
indicated on the MSDS. Select positive pressure supplied air respirator
(TC19C or equivalent) for isocyanates.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.

Exposure Limits

Chemical Name CAS Number Regulation Limit Form
Coal tar pitch 65996-93-2 Ontario TWAEV: 0.2 mg/m3 as benzene solubles
ACGIH TWA: 0.2 mg/m3 Aerosol.as benzene
solubles

Xylene 1330-20-7 Ontario TWAEV: 435 mg/m3
Ontario STEV: 650 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm




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Material Safety Data Sheet



NEO SEAL
Version 3. Print Date 10/31/2009
REVISION DATE: 10/30/2009

Chemical Name CAS Number Regulation Limit Form
Carbon Black 1333-86-4 Ontario TWAEV: 3.5 mg/m3
ACGIH TWA: 3.5 mg/m3

4,4'-Methylene 101-68-8 Ontario TWAEV: 0.005 ppm
bis(phenylisocyanate) ACGIH TWA: 0.005 ppm

Ethylbenzene 100-41-4 Ontario TWAEV: 435 mg/m3
Ontario STEV: 540 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 125 ppm

Benzo(a)anthracene 56-55-3
Benzo(a)pyrene 50-32-8
Benzo(b)fluoranthene 205-99-2


SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State : Liquid
Form : Liquid
Color : Black
Odor : Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Evaporation Rate: : Not available.
Specific Gravity : 1.32
% Volatile Weight : 2%


SECTION 10 - REACTIVITY / STABILITY

Substances to avoid : Strong acids.Strong bases.Amines.Water or moisture.Alcohols.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.


SECTION 11 - TOXICOLOGICAL INFORMATION

Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 4,300 mg/kg ( Rat ) 1,590 mg/kg ( Mouse ) 6,670 mg/kg (
Rat ) 3,523 - 8,600 mg/kg ( Rat ) 5,627 mg/kg ( Mouse )


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Material Safety Data Sheet



NEO SEAL
Version 3. Print Date 10/31/2009
REVISION DATE: 10/30/2009

Acute inhalation toxicity (LC-50) 6,350 mg/l for 4 h ( Rat ) 3,907 mg/l for 6 h ( Mouse ) 8,000
mg/l for 4 h ( Rat )

4,4'-Methylene bis(phenylisocyanate), CAS-No.: 101-68-8
Acute inhalation toxicity (LC-50) 0.369 mg/l for 4 h ( Rat ) 0.38 mg/l for 4 h ( Rat )

Ethylbenzene, CAS-No.: 100-41-4
Acute oral toxicity (LD-50 oral) 5,460 mg/kg ( Rat ) 3,500 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 17,800 mg/kg ( Rabbit )



SECTION 12 - ECOLOGICAL INFORMATION

No Data Available


SECTION 13 - WASTE DISPOSAL CONSIDERATIONS

Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.


SECTION 14 - TRANSPORTATION / SHIPPING DATA

TDG / DOT Shipping Description:
NOT REGULATED


SECTION 15 - REGULATORY INFORMATION

North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.


Canadian Regulations:
WHMIS Classification : D2A, D2B
This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System
(WHMIS).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.

Other Regulations:
Regulatory VOC (less water and : 37 g/l
exempt solvent)




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Material Safety Data Sheet



NEO SEAL
Version 3. Print Date 10/31/2009
REVISION DATE: 10/30/2009



SECTION 16 - OTHER INFORMATION

HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe

Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.

Prepared by: Sewnauth Raghunandan

Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System




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