LITHIUM ION PRODUCT SAFETY DATA SHEET Page 1 of 5
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PRODUCT SAFETY DATA SHEET
PRODUCT NAME: Energizer ACCU Rechargeable Battery Type No.: Volts:
TRADE NAME: Lithium Ion Battery Approximate Weight:
CHEMICAL SYSTEM: Lithium Ion Designed for Recharge: Yes
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SECTION I - MANUFACTURER INFORMATION
Manufactured for:
Eveready Battery Company, Inc. Telephone Number for Information
(440) 835-7368
25225 Detroit Road
(800) 383-7323 (USA)
Westlake, OH 44145 Date Prepared: October 17, 2001
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SECTION II - HAZARDOUS INGREDIENTS
IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within
or their combustion products could be harmful.
MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.
Acetylene Black 3.5 mg/m3 TWA 3.5 mg/m3 TWA 0-2
(CAS# 1333-86-4) (as carbon black) (as carbon black)
Biphenyl 1.3 mg/m3 0-15
1 mg/m3 TWA
(CAS# 92-52-4) TWA
0.2 ppm TWA
0.2 ppm TWA
Diethyl Carbonate None established None established 0-15
(CAS# 105-58-8)
Dimethyl Carbonate None established None established 0-15
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LITHIUM ION PRODUCT SAFETY DATA SHEET Page 2 of 5
(CAS# 616-38-6)
Ethyl Methyl Carbonate None established None established 0-15
(CAS# 623-53-0)
Ethylene Carbonate None established None established 0-15
(CAS# 96-49-1)
MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.
Graphite 5 mg/m3 TWA (respirable 2 mg/m3 TWA (respirable 7-22
(CAS# 7782-42-5) fraction) fraction)
15 mg/m3 TWA (total
dust)
Lithium Cobalt Oxide 0.1 mg/m3 TWA (as Co) 0.02 mg/m3 TWA (as Co) 15-30
(CAS# 12190-79-3)
Lithium Hexafluorophosphate None established None established 0-5
(CAS# 21324-40-3)
Lithium Tetrafluoroborate None established None established 0-5
(CAS# 14283-07-9)
n-Methyl Pyrrolidinone None established None established 0-1
(CAS# 872-50-4)
Oxalic Acid 1 mg/m3 TWA 1 mg/m3 TWA 0-1
(CAS# 144-62-7) 2 mg/m3 STEL
Propylene Carbonate None established None established 0-15
(CAS# 108-32-7)
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SECTION III - FIRE AND EXPLOSION HAZARD DATA
If fire or explosion occurs when batteries are on charge, shut off power to charger.
In case of fire where lithium ion batteries are present, flood the area with water. If any batteries are burning, water
may not extinguish them, but will cool the adjacent batteries and control the spread of fire. CO2, dry chemical,
and foam extinguishers are preferred for small fires, but also may not extinguish burning lithium ion batteries.
Burning batteries will burn themselves out. Virtually all fires involving lithium ion batteries can be controlled with
water. When water is used, however, hydrogen gas may be evolved which can form an explosive mixture with air.
LITH-X (powdered graphite) or copper powder fire extinguishers, sand, dry ground dolomite or soda ash may also
be used. These materials act as smothering agents.
Fire fighters should wear self-contained breathing apparatus. Burning lithium ion batteries can produce toxic
fumes including HF, oxides of carbon, aluminum, lithium, copper, and cobalt. Volatile phosphorus pentafluoride
may form at a temperature above 230?Fahrenheit.
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LITHIUM ION PRODUCT SAFETY DATA SHEET Page 3 of 5
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SECTION IV - HEALTH HAZARD DATA
Under normal conditions of use, the battery is hermetically sealed.
Ingestion: Swallowing a battery can be harmful.
Contents of an open battery can cause serious chemical burns of mouth, esophagus,
and gastrointestinal tract.
If battery or open battery is ingested, do not induce vomiting or give food or drink.
Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION
HOTLINE for advice and follow-up (202-625-3333) collect, day or night.
Inhalation: Contents of an open battery can cause respiratory irritation. Inhalation of
vapors may cause irritation of the upper respiratory tract and lungs. Provide fresh air
and seek medical attention.
Skin Absorption: N-methyl pyrrolidinone, ethylene carbonate, ethyl methyl carbonate,
dimethyl carbonate, and biphenyl may be absorbed through the skin causing localized
inflammation.
Skin Contact: Contents of an open battery can cause skin irritation and/or chemical
burns. Remove contaminated clothing and wash skin with soap and water. If a
chemical burn occurs or if irritation persists, seek medical attention.
Eye Contact: Contents of an open battery can cause severe irritation and chemical
burns. Immediately flush eyes thoroughly with water for at least 15 minutes, lifting
upper and lower lids, until no evidence of the chemical remains. Seek medical
attention.
Note: Acetylene black and cobalt compounds are listed as possible carcinogens by
the International Agency for Research on Cancer (IARC).
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SECTION V - PRECAUTIONS FOR SAFE HANDLING AND USE
Storage: The lithium ion battery should be between 25% and 75% of full charge when
stored for a long period of time. Store in a cool, dry, well ventilated area. Elevated
temperatures can result in loss of battery performance, leakage, or rust. Do not
expose the battery to open flames.
Mechanical Containment: Containment of this battery in a manner that obstructs or
defeats the safety vent or electrical disconnect mechanisms designed into this battery
can result in fire and/or explosion and cause personal injury and device damage. This
battery is not designed to be potted, enclosed in hermetic overpackaging, or sealed by
any means that prevents free operation of the designed safety mechanisms.
Handling: Do not expose the battery to excessive physical shock or vibration. Short
circuiting should be avoided, however, accidental short circuiting for a few seconds will
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LITHIUM ION PRODUCT SAFETY DATA SHEET Page 4 of 5
not seriously affect the battery. Prolonged short circuits will cause the battery to rapidly
lose energy, could generate enough heat to burn skin, and may cause the safety
release vents of the enclosed cells to open. Sources of short circuits include jumbled
batteries in bulk containers, coins, metal jewelry, metal covered tables, or metal belts
used for assembly of batteries in devices. To minimize risk of short circuiting, the
protective case supplied with the battery should be used to cover the terminals when
transporting or storing the battery. Do not disassemble or deform the battery. Should
an individual cell within a battery become ruptured, do not allow contact with water.
If soldering or welding to the battery is required, consult your Eveready Battery
Company representative for proper precautions to prevent damage to the integrity of
the battery.
Charging: This battery is made to be charged many times. Use an Energizer
approved battery charger. Never use a modified or damaged battery charger. Do not
charge for over 180 minutes or repeat charging without intermittent discharging. A
backup charge termination based on time is recommended to prevent overcharging.
The charging temperature should be between 0?C and 50?C (32?F and 120?F). The
battery pack will normally warm during charging.
Charging Voltages and Currents: Charging voltages are prevented from exceeding
the specified limits by an internal battery protection circuit. Never use a battery which
shows signs of a damaged protection circuit or broken case. (Such damage to the
protection circuit may be indicated by voltages at the battery terminals outside of their
specified ranges.) Adhere to all specified charging and discharging voltages and
currents. Do not use battery if its voltage drops below the specified minimum voltage.
Labeling: If the Eveready label or package warnings are not visible, it is important to
provide a package and/or device label stating:
WARNING: CHARGE ONLY WITH SPECIFIED CHARGERS
ACCORDING TO DEVICE MANUFACTURER'S INSTRUCTIONS. DO
NOT OPEN BATTERY, DISPOSE OF IN FIRE, OR SHORT CIRCUIT -
MAY IGNITE, EXPLODE, LEAK, OR GET HOT CAUSING PERSONAL
INJURY.
Disposal: Dispose in accordance with all applicable federal, state and local
regulations.
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SECTION VI - SPECIAL PROTECTION INFORMATION
Ventilation Requirements: Not necessary under normal conditions.
Respiratory Protection: Not necessary under normal conditions.
Eye Protection: Not necessary under normal conditions. Wear safety glasses with
side shields if handling an open or leaking battery.
Gloves: Not necessary under normal conditions. Use neoprene or natural rubber
gloves if handling an open or leaking battery.
Open Battery Storage: Battery should not be opened. Should a cell become
disassembled, the electrode should be stored in a fireproof cabinet, away from
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LITHIUM ION PRODUCT SAFETY DATA SHEET Page 5 of 5
combustibles.
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SECTION VII - REGULATORY INFORMATION
The transportation of lithium ion batteries manufactured or sold by Eveready Battery Company is not regulated by
the U.S. Department of Transportation or the major international regulatory bodies.
SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency
Planning and Community Right-To-Know Act.
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