Material Safety Data Sheet
Revision Date: 09/25/2003 Issue date: 11/17/2004
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: FREKOTE FMS/PINT Item No. : 38412
Product type: Mold Release Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Hydrotreated heavy naphtha 60-100 None None None
64742-48-9
Dibutyl Ether 10-30 None None None
142-96-1
Octane 1-5 None 2350 mg/m?TWA None
111-65-9 500 ppm TWA
Non hazardous components
Proprietary resin blend less than 5% NJ TSRN 06-070-1067-5411P
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: 1
Color: Colorless FLAMMABILITY: 3
Odor: Mild, Solvent PHYSICAL HAZARD: 0
Personal Protection: See Section 8
WARNING: FLAMMABLE LIQUID AND VAPOR.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION
Relevant routes of exposure: Skin, inhalation, eyes
Potential Health Effects
Inhalation: Vapors and mists will irritate nose and throat and possibly eyes.
Skin contact: Prolonged or repeated contact may cause irritation.
Eye contact: Moderate eye irritation.
Ingestion: May be harmful if swallowed.
Existing conditions aggravated by Skin disorders.
exposure:
See Section 11 for additional toxicological information.
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4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If discomfort persists seek medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Wash clothing before reuse. If skin irritation persists, call a physician.
Eye contact: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Ingestion: Keep individual calm. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents.
DO NOT induce vomiting unless directed to do so by medical personnel. Get medical attention
immediately.
5. FIRE-FIGHTING MEASURES
Flash point: 31癈 (87.8癋)
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Use water
spray to keep fire exposed containers cool.
Unusual fire or explosion hazards: Containers exposed to fire should be cooled with water to prevent vapor pressure buildup which could
result in container rupture. If a leak or spill has not ignited use water spray to disperse vapors. The
liquid is volatile and gives off invisible vapors.
Hazardous combustion products: Oxides of carbon. Acrid smoke and fumes.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Do not allow material to contaminate ground water system.
Clean-up methods: Maintain good ventilation for large spills. Remove all ignition sources. Soak up with inert absorbent
material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable and closed
containers for disposal.
7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Keep container closed. Avoid contact with eyes, skin and
clothing. Do not wear contact lenses.
Storage: Store away from heat, sparks, flames, or other sources of ignition. Keep container closed. Store at or
below 48.8癈 (120癋).
Incompatible products: Oxidizing and spontaneously flammable products.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Ensure adequate ventilation, especially in confined areas.
Respiratory protection: Use a NIOSH approved respirator if ventilation is inadequate.
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Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to
prevent skin contact.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Colorless
Odor: Mild, Solvent
Vapor pressure: Not available
pH: Not applicable
Boiling point/range: 140癈 (285癋)
Melting point/range: Not available
Specific gravity: .755
Vapor density: Heavier than air
Evaporation rate: Slower than ether.
Solubility in water: Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available
VOC content: 99.24%; 749 grams/liter
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: None under normal use.
Incompatability: Oxidizing agents.
Conditions to avoid: Heat, flames and sparks. High temperatures.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Hydrotreated heavy naphtha No No No
64742-48-9
Dibutyl Ether No No No
142-96-1
Octane No No No
111-65-9
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Hydrotreated heavy naphtha Irritant
64742-48-9
Dibutyl Ether Irritant
142-96-1
Octane No Target Organs
111-65-9
12. ECOLOGICAL INFORMATION
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Ecological information: No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this
material; however, commonly available data on the material indicate that uncontrolled releases to soil,
groundwater, or surface waters could entail acute and/or chronic ecological effects, depending on the
quantity and concentration of such releases. Releases of volatile components to the atmosphere are
not believed to entail significant ecological consequences provided such releases are within the
exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to
avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which
may occur should be contained and cleaned up immediately in accordance with Section 6.
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Recommended method of disposal: Dispose of according to Federal, State and local governmental
regulations.
EPA hazardous waste number: Not available
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
International Air Transportation (ICAO/IATA):
Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
WaterTransportation (IMO/IMDG):
Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
Marine pollutant: None known
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None.
CERCLA/SARA Section 311/312: None.
CERCLA/SARA 313: None.
California Proposition 65: Benzene (CAS# 71-43-2). Trace. Toluene (CAS# 108-88-3). Trace.
Canada Regulatory Information
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic
Substances List or the Non-Domestic Substances List.
WHMIS hazard class: B.2, D.2.A, D.2.B
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16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format.
Prepared by: Lou Fabrizio, Senior Health & Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
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