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3,5-Dinitrobenzoyl Chloride DX2045
Material Safety Data
Sheet
3,5-Dinitrobenzoyl Chloride
Section 1. Product and Company Identification
: 3,5-Dinitrobenzoyl Chloride
Product name
: DX2045
Product code
: None.
Synonym
: Other non-specified industry: Analytical reagent.
Material uses
: EMD Chemicals Inc.
Manufacturer
P.O. Box 70
480 Democrat Road
Gibbstown, NJ 08027
856-423-6300 Technical Service
Monday - Friday: 8:00 - 5:00 PM
Validation date : 10/18/2006.
Print date :
: 800-424-9300 CHEMTREC (USA)
In case of emergency
613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
Section 2. Hazards Identification
: Solid. (Flakes.)
Physical state
: Acrid.
Odor
: This material is considered hazardous by the OSHA Hazard Communication
OSHA/HCS status
Standard (29 CFR 1910.1200).
: DANGER!
Emergency overview
CAUSES EYE AND SKIN BURNS.
FLAMMABLE SOLID.
HARMFUL IF INHALED OR SWALLOWED.
CAUSES SEVERE RESPIRATORY TRACT IRRITATION.
LACHRYMATOR.
Do not ingest. Do not get in eyes or on skin or clothing. Avoid breathing dust. Keep
away from heat, sparks and flame. Keep container closed. Use only with adequate
ventilation. Wash thoroughly after handling.
: Inhalation. Ingestion.
Routes of entry
Potential acute health effects
: Corrosive to eyes.
Eyes
: Corrosive to the skin.
Skin
: Toxic by inhalation. Severely irritating to the respiratory system.
Inhalation
: Toxic if swallowed. May cause burns to mouth, throat and stomach.
Ingestion
: No known significant effects or critical hazards.
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Teratogenicity /
Reproductive toxicity
: Repeated skin exposure can produce local skin destruction or dermatitis. Repeated
Medical conditions
or prolonged exposure to the substance can produce lung damage. Repeated
aggravated by over-exposure
exposure of the eyes to a low level of dust can produce eye irritation.
See toxicological information (section 11)
Section 3. Composition/Information on Ingredients
United States
Name CAS number % by Weight
3,5-Dinitrobenzoyl Chloride 99-33-2 100
Section 4. First Aid Measures
: Get medical attention immediately. Immediately flush eyes with plenty of water for
Eye contact
at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Chemical burns must be treated promptly by a physician.
: Get medical attention immediately. Flush contaminated skin with plenty of water.
Skin contact
Continue to rinse for at least 10 minutes. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing or wear gloves.
Chemical burns must be treated promptly by a physician. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
: Get medical attention immediately. Move exposed person to fresh air. If it is
Inhalation
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. Keep person warm and at rest. If not
breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
: Get medical attention immediately. Wash out mouth with water. Remove dentures if
Ingestion
any. Move exposed person to fresh air. Keep person warm and at rest. If material has
been swallowed and the exposed person is conscious, give small quantities of water
to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Chemical burns
must be treated promptly by a physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
: No action shall be taken involving any personal risk or without suitable training. If it
Protection of first-aiders
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing or wear gloves.
Section 5. Fire Fighting Measures
: Flammable solid. Runoff to sewer may create fire or explosion hazard.
Flammability of the product
: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2 etc.),
Products of combustion
halogenated compounds, hydrogen chloride.
Extinguishing media
: Use dry chemical powder.
Suitable
: Do not use water jet.
Not suitable
: Not available.
Special exposure hazards
Special protective equipment : Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
for fire-fighters
mode.
: Flammable solid
Special remarks on fire
hazards
Section 6. Accidental Release Measures
: Immediately contact emergency personnel. Eliminate all ignition sources. Keep
Personal precautions
unnecessary personnel away. Use suitable protective equipment. Do not touch or
walk through spilled material.
: Avoid dispersal of spilled material and runoff and contact with soil, waterways,
Environmental precautions
drains and sewers.
: If emergency personnel are unavailable, carefully scoop up spilled materials and use
Methods for cleaning up
a non-sparking or explosion-proof means to transfer material to an appropriate
container for disposal by incineration. Avoid creating dusty conditions and prevent
wind dispersal.
Section 7. Handling and Storage
: Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use
Handling
only with adequate ventilation. Avoid breathing dust. Keep away from heat, sparks
and flame. To avoid fire, eliminate ignition sources. Wash thoroughly after handling.
: Keep container in a cool, well-ventilated area. Keep container tightly closed and
Storage
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Section 8. Exposure Controls/Personal Protection
Consult local authorities for acceptable exposure limits.
: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or
Engineering measures
mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or
statutory limits. The engineering controls also need to keep gas, vapor or dust
concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
Personal protection
: Safety eyewear complying with an approved standard should be used when a risk
Eyes
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Recommended: safety glasses with side-shields , face shield
: Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks involved and should be approved by a specialist before
handling this product.
Body: Recommended: safety apron
: Use a properly fitted, particulate filter respirator complying with an approved
Respiratory
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
: Chemical-resistant, impervious gloves complying with an approved standard should
Hands
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Recommended: nitrile rubber
: Wash hands, forearms and face thoroughly after handling chemical products, before
Hygiene measures
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Section 9. Physical and Chemical Properties
: Solid. (Flakes.)
Physical state
: Greenish-yellow
Color
: Acrid.
Odor
: 230.57 g/mole
Molecular weight
: C7-H3-Cl-N2-O5
Molecular formula
Section 10. Stability and Reactivity
: The product is stable.
Stability and reactivity
: Reactive or incompatible with the following materials: oxidizing materials and
Incompatibility with various
moisture.
substances
Water reactive. Reacts with water or steam to produce free acid and heat.
: carbon oxides (CO, CO2) , nitrogen oxides (NO, NO2 etc.) , halogenated
Hazardous decomposition
compounds
products
: Will not occur.
Hazardous polymerization
: Flammable in the presence of the following materials or conditions: open flames,
Conditions of reactivity
sparks and static discharge and heat.
Flammable solid
Explosive in the presence of the following materials or conditions: open flames, sparks
and static discharge and heat.
Section 11. Toxicological Information
Toxicity data
: Extremely hazardous in case of inhalation (lung irritant).
Other toxic effects on
Very hazardous in case of skin contact (corrosive), of eye contact (corrosive), of
humans
ingestion, .
Specific effects
: No known significant effects or critical hazards.
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Teratogenicity /
Reproductive toxicity
Sensitization
: May cause burns to mouth, throat and stomach.
Ingestion
: Severely irritating to the respiratory system.
Inhalation
: Corrosive to eyes.
Eyes
: Corrosive to the skin.
Skin
Section 12. Ecological Information
: No known significant effects or critical hazards.
Environmental precautions
: These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2
Products of degradation
etc.), halogenated compounds.
: The products of degradation are as toxic as the product itself.
Toxicity of the products of
biodegradation
Section 13. Disposal Considerations
: The generation of waste should be avoided or minimized wherever possible. Avoid
Waste disposal
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements.
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated
to determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL
PROTECTION for additional handling information and protection of employees.
Section 14. Transport Information
Regulatory UN number Proper shipping Class PG* Label Additional
information name information
UN3261 CORROSIVE SOLID, 8 II Not available.
DOT Classification
ACIDIC, ORGANIC,
N.O.S. (3,5-
DINITROBENZOYL
CHLORIDE)
PG* : Packing group
Section 15. Regulatory Information
United States
: Flammable solid
HCS Classification
Toxic material
Corrosive material
: TSCA 8(b) inventory: Listed
U.S. Federal regulations
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: 3,5-Dinitrobenzoyl Chloride
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: 3,5-
Dinitrobenzoyl Chloride: Fire hazard, reactive, Immediate (acute) health hazard
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
: No products were found.
State regulations
Canada
: Class B-4: Flammable solid.
WHMIS (Canada)
Class E: Corrosive material
: CEPA DSL: 3,5-Dinitrobenzoyl Chloride
CEPA DSL/CEPA NDSL
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
EU regulations
: This product is not classified according to EU legislation.
Risk phrases
International regulations
: Australia (NICNAS): 3,5-Dinitrobenzoyl Chloride
International lists
China: 3,5-Dinitrobenzoyl Chloride
Korea (TCCL): 3,5-Dinitrobenzoyl Chloride
Philippines (RA6969): 3,5-Dinitrobenzoyl Chloride
Section 16. Other Information
: DANGER!
Label requirements
CAUSES EYE AND SKIN BURNS.
FLAMMABLE SOLID.
HARMFUL IF INHALED OR SWALLOWED.
CAUSES SEVERE RESPIRATORY TRACT IRRITATION.
LACHRYMATOR.
1 Flammability
National Fire :
Protection Health
3 1 Instability
Association (U.S.A.)
Special
Notice to reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable,
are offered for information purposes only and as a guide to the appropriate precautionary and emergency
handling of the material by a properly trained person having the necessary technical skills. Users should consider
these data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use, storage and
disposal of these materials and the safety and health of employees and customers and the protection of the
environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND,
EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE,
WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE
INFORMATION REFERS.
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