3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR
FABRICS (CAT. NO. 5014S & 5014SC)
MANUFACTURER: 3M
DIVISION: Protective Materials Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 01/19/2004
Supercedes Date: 12/08/2003
Document Group: 08-2023-3
Product Use:
Intended Use: WATER REPELLENT FOR CAMPING AND OUTDOOR GEAR
Limitations on Use: NOT RECOMMENDED FOR USE ON MATERIALS WITH PROLONGED
CONTACT WITH SKIN
Specific Use: WATER REPELLENT FOR OUTDOOR FABRICS
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
NAPHTHOL SPIRITS 64742-48-9 40 - 70
HYDROCARBON PROPELLANT Unknown 10 - 30
POLYDIMETHYLSILOXANE 63148-62-9 1- 5
TRIMETHYLATED SILICA 68988-56-7 1- 5
2-ETHYLHEXYL TITANATE 1070-10-6 1- 5
XYLENE 1330-20-7 0.5 - 1.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
Specific Physical Form: Aerosol
Odor, Color, Grade: spray container. Contains colorless to light yellow colored liquid with faint petroleum hydrocarbon odor.
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains
flammable material under pressure. Aerosol container contains flammable gas under pressure. Combustible liquid and vapor.
Flammable liquefied gas. Flammable liquid and vapor. NOTE: This product is not intended for use on fabric which may be in
contact with cuts, scratches, or irritated areas of the skin. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Delayed Dermal Irritation: Signs/symptoms may include localized redness, swelling, itching, and pain. These effects may not appear
immediately following exposure.
Moderate Skin Irritation on abraded skin: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:
Single exposure, above recommended guidelines, may cause:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness,
and nose and throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
May be harmful if swallowed.
Target Organ Effects:
Single exposure, above recommended guidelines, may cause:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. Get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
559 篎 [Details: CONDITIONS: (For CAS# 64742-48-9)]
Autoignition temperature
Approximately 90 篎 [Test Method: Closed Cup] [Details:
Flash Point
CONDITIONS: (Liquid only; propellant FP < 0 F)]
Approximately 1.8 % volume
Flammable Limits - LEL
Approximately 9.5 % volume
Flammable Limits - UEL
Class IC Flammable Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Vapors may
travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material
under pressure. Combustible liquid and vapor. Flammable liquefied gas. Flammable liquid and vapor.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build
dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film
forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or
commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an
absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible
using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the
area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing
solution. Place in an approved metal container. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this
product. Wash exposed areas thoroughly with soap and water. Aerosol container contains flammable gas under pressure. No smoking
while handling this material. Do not spray near flames or sources of ignition. Ground containers securely when transferring contents.
Wear low static or properly grounded shoes. Do not pierce or burn container, even after use. Avoid static discharge. Keep away from
heat, sparks, open flame, pilot lights and other sources of ignition. Avoid contact with oxidizing agents. Keep out of the reach of
children. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational
Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGE
Store away from heat. Do not store containers on their sides. Keep container tightly closed. Store away from areas where product
may come into contact with food or pharmaceuticals. Store away from acids. Store out of direct sunlight. Store away from oxidizing
agents. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Do not use in a confined area or areas with little or no air movement. Provide
appropriate local exhaust ventilation on open containers.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray. Avoid eye contact.
8.2.2 Skin Protection
Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure
assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
This product is not intended for use on fabric which may be in contact with cuts, scratches, or irritated areas of the skin.
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid
breathing of vapors, mists or spray.
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
NAPHTHOL SPIRITS 3M TWA 100 ppm
NAPHTHOL SPIRITS CMRG TWA 300 ppm
XYLENE ACGIH TWA 100 ppm Table A4
XYLENE ACGIH STEL 150 ppm Table A4
XYLENE OSHA TWA 100 ppm Table Z-1A
XYLENE OSHA STEL 150 ppm Table Z-1A
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Aerosol
Specific Physical Form:
spray container. Contains colorless to light yellow colored liquid
Odor, Color, Grade:
with faint petroleum hydrocarbon odor.
Liquid
General Physical Form:
559 篎 [Details: CONDITIONS: (For CAS# 64742-48-9)]
Autoignition temperature
Approximately 90 篎 [Test Method: Closed Cup] [Details:
Flash Point
CONDITIONS: (Liquid only; propellant FP < 0 F)]
Approximately 1.8 % volume
Flammable Limits - LEL
Approximately 9.5 % volume
Flammable Limits - UEL
>=320 篎 [Details: CONDITIONS: (For CAS# 64742-48-9)]
Boiling point
Approximately 5 Units not avail. or not appl. [Ref Std: AIR=1]
Vapor Density
[Details: CONDITIONS: (For CAS# 64742-48-9)]
Approximately 2 mmHg [Details: CONDITIONS: (For CAS#
Vapor Pressure
64742-48-9)]
Approximately 0.8 Units not avail. or not appl. [Ref Std:
Specific Gravity
WATER=1]
Not Applicable
pH
Not Applicable
Melting point
Negligible
Solubility in Water
Approximately 0.3 Units not avail. or not appl. [Ref Std:
Evaporation rate
BUOAC=1] [Details: CONDITIONS: (For CAS# 64742-48-9)]
Approximately 90 % weight
Volatile Organic Compounds
Approximately 90 % weight
Percent volatile
Approximately 90 %
VOC Less H2O & Exempt Solvents
<=50 centipoise
Viscosity
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents; Heat; Sparks and/or flames
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in
a permitted hazardous waste facility.
Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
70-0707-9080-6, 70-0709-3420-6, 70-0710-9824-1, 70-0712-2028-2
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
XYLENE 1330-20-7 0.5 - 1.5
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
INTERNATIONAL REGULATIONS
Contact 3M for more information.
ADDITIONAL INFORMATION
TSCA: All components used in the manufacture of this material are in compliance with the U.S. TSCA inventory.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).
Revision Changes:
Copyright was modified.
Section 14: ID Number(s) was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
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3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) HEAVY DUTY WATER REPELLENT, FOR OUTDOOR FABRICS
(CAT. NO. 5014S & 5014SC) 01/19/2004
3M MSDSs are available at www.3M.com
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