IsleChem, LLC
MATERIAL SAFETY DATA SHEET
MSDS NUMBER: M105
MSDS DATE: 3/11/09
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE
24 HOUR EMERGENCY PHONE: 1-800-424-9300
I. PRODUCT IDENTIFICATION
HMIS HAZARD RATINGS
HEALTH HAZARD 3 FIRE HAZARD 1 REACTIVITY 0
Based on the National Paint & Coatings Association HMIS rating system.
SARA/TITLE III HAZARD CATEGORIES (See Section X)
Immediate (ACUTE) Health: YES Reactive Hazard: NO
Delayed (Chronic) Health: NO Sudden Release of Pressure: NO
Fire Hazard: NO
MANUFACTURER'S : IsleChem, LLC
NAME AND : 2801 Long Road TELEPHONE: (716) 773-8100
ADDRESS : Grand Island, NY 14072
CHEMICAL NAME: Phosphoric Acid CAS NUMBER: 1070-03-7 (monoester)
Mono-2-ethylhexyl ester/ 298-07-7 (diester)
di-2-ethylhexyl ester mixture
SYNONYMS/COMMON NAMES: Phosphoric acid, Diisooctyl Este (CAS NUMBER: 27215-10-7)
Phosphoric acid, Monoisooctyl ester (CAS NUMBER: 26403-12-3)
CHEMICAL FORMULA: C8H19O4P + C16H35O4P
PRODUCT USE: Curing catalyst, oil additive, pigment dispersion agent and others
DOT PROPER SHIPPING NAME: Corrosive Liquid Acidic Organic NOS (2-Ethylhexyl Acid
Phosphate)
DOT HAZARD CLASS: 8
DOT IDENTIFICATION NUMBER: UN3265
DOT PACKING GROUP: III
DOT HAZARDOUS SUBSTANCE: Phosphoric acid RQ 5000 lbs.
DOT MARINE POLLUTANT: Not applicable
ADDITIONAL DESCRIPTION REQUIREMENT: Not applicable
CAS = Chemical Abstract Service Number ND = No relevant information found or not available
PEL = OSHA Permissible Exposure Limit CORP = Corporate Exposure Limit
TLV = ACGIH Threshold Limit Value, Current * = See Chronic Effects Information NA = Not applicable
IMPORTANT: The information presented herein, while not guaranteed, was prepared by competent technical personnel and is true and accurate to the best of our knowledge. NO WARRANTY, EXPRESS OR IMPLIED IS MADE REGARDING
PERFORMANCE, STABILITY, OR OTHERWISE. This information is not intended to be all-inclusive as to the manner and conditions of use, handling and storage. Other factors may involve other or additional safety or performance
IsleChem
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MSDS NUMBER: M105
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE 1/27/06
considerations. While our technical personnel will be happy to respond to questions regarding safe handling use procedures, safe handling and use remains the responsibility of the customer. No suggestions for use are intended as, and
nothing herein shall be construed as a recommendation to infringe any existing patents or violate any Federal, State or local laws.
II. HEALTH HAZARD INFORMATION
EMERGENCY AND FIRST AID PROCEDURES
EYES:
OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION. IMMEDIATELY
flush eyes with large amounts of water for at least 15 minutes forcibly holding lids apart to ensure complete
irrigation of all eye and lid tissue. Washing eyes within one (1) minute is essential to achieve maximum
effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN:
SEEK MEDICAL ATTENTION IMMEDIATELY. Flush thoroughly with cool water under shower while removing
contaminated clothing and shoes. CONTINUE TO FLUSH UNTIL MEDICAL ATTENTION ARRIVES. Discard
non-rubber shoes. Wash clothing before reuse.
INHALATION:
Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops,
administer artificial resuscitation. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING. This material is not soluble. DO NOT GIVE FLUIDS. If spontaneous vomiting
is inevitable, PREVENT ASPIRATION by keeping the victims head below the knees. GET IMMEDIATE
MEDICAL ATTENTION. A qualified physician can perform gastric lavage only when the airway (trachea) has
been secured to prevent aspiration.
ROUTES OF EXPOSURE
INHALATION:
Inhalation of vapors, mist or liquid may cause irritation to the mucous membranes of the nose and throat
and can produce serious chemical burns.
SKIN:
Exposure to vapor, mist or liquid may irritate skin and can produce serious burns.
EYE CONTACT:
May irritate eyes and can produce chemical burns.
INGESTION:
Can cause irritation and burning of the mouth, throat and gastrointestinal tract.
EFFECTS OF OVEREXPOSURE
ACUTE:
Irritating and corrosive to the eyes, skin, respiratory and digestive tracts.
CHRONIC:
No known chronic effects.
TOXICOLOGY DATA:
Acute Oral LD50 (rat) 3.2 g/kg.
SYNERGISTIC MATERIALS:
Not Applicable.
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MSDS NUMBER: M105
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE 1/27/06
III. IMPORTANT COMPONENTS
CAS NUMBER / NAME
1070-03-7 Phosphoric acid, mono-2-ethylhexyl ester
EXPOSURE LIMITS PERCENTAGE
PEL: Not established VOL
TLV: Not established WT 20-50
COMMON NAMES:
none
Listed On (List Legend Below):
04
298-07-7 Phosphoric acid, di-2-ethylhexyl ester
EXPOSURE LIMITS PERCENTAGE
PEL: Not Established VOL
TLV: Not Established WT 40-75
COMMON NAMES:
none
Listed On (List Legend Below):
01, 02, 03, 04
7664-38-2 Phosphoric acid
EXPOSURE LIMITS PERCENTAGE
PEL: 1 mg/m3, TWA VOL
STEL 3 mg/m3 WT 0-5
TLV: 1 mg/m3, TWA
STEL 3 mg/m3
COMMON NAMES:
ORTHOPHOSPHORIC ACID
Listed On (List Legend Below):
02, 03, 05, 06, 07, 08, 09, 10, 11
All components of this product that are required to be on the TSCA Inventory are listed on the inventory.
Not listed as carcinogen - IARC, NTP, OSHA
LIST LEGEND
01 New Jersey Right to Know Haz. Substance 07 CERCLA Hazardous Substance
02 Canadian HMIS ?disclose at 1% 08 SARA Title Section 313 Toxic Chemical
03 DOT Hazardous Material 09 Massachusetts Substance List
04 TSCA PAIR Substance 10 New Jersey Right to Know ?Special Health Haz.
05 CWA Section 311 Hazardous Substance 11 PA Haz. Substance ?Environmental Hazard
06 NIOSH Recommendation Substance
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MSDS NUMBER: M105
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE 1/27/06
IV. FIRE AND EXPLOSION DATA
FLASH POINT: >200oC (392oF) AUTOIGNITION TEMPERATURE: Not Applicable
FLAMMABLE LIMITS IN AIR, % BY VOLUME - UPPER: Not Applicable
LOWER: Not Applicable
EXTINGUISHING MEDIA:
Use dry chemical, foam, carbon dioxide or water spray.
SPECIAL FIRE FIGHTING PROCEDURES:
In fire conditions wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus and full
protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARD:
Under fire conditions, will liberate toxic and corrosive oxides of phosphorus.
SENSITIVITY TO MECHANICAL IMPACT:
Not Available.
SENSITIVITY TO STATIC DISCHARGE:
Not Available.
V. SPECIAL PROTECTION
VENTILATION REQUIREMENTS:
Provide good general room ventilation plus local exhaust at points of emission.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY:
NIOSH/MSHA approved respirator, following manufacturer's recommendations, should be used as a
precautionary measure where airborne contaminants may occur.
EYE:
Wear chemical safety goggles plus full face shield to protect against splashing when appropriate.
GLOVES:
Wear chemical resistant gloves such as neoprene, rubber or vinyl.
OTHER CLOTHING AND EQUIPMENT:
Eyewash facility and emergency shower should be in close proximity. Impervious clothing and rubber boots
should be worn for splash protection.
IsleChem
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MSDS NUMBER: M105
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE 1/27/06
VI. PHYSICAL DATA
Colorless to light yellow liquid. Slight Ethylhexyl Alcohol
APPEARANCE AND ODOR:
odor
No Data
BOILING POINT @ 760 mm Hg:
No Data
FREEZING POINT:
No Data
VAPOR PRESSURE:
0.99-1.01
SPECIFIC GRAVITY (H2O=1):
Insoluble
SOLUBILITY IN H2O % BY WT:
No Data
VAPOR DENSITY (Air=1):
No Data
ODOR THRESHOLD (ppm):
2 @ 10 GM/L
pH:
No Data
EVAPORATION RATE:
COEFFICIENT WATER/OIL DISTRIBUTION: No Data
VII. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY:
Stable under normal conditions. Avoid exposure to heat or to most metals or plastics, especially at elevated
temperatures. Thermal degradation occurs above 257 oF.
INCOMPATIBILITY:
Reacts with alkalies producing heat. Reacts with many metals such as Aluminum and Zinc liberating
flammable hydrogen gas.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal degradation occurs above 257oF, producing oxides of phosphorus.
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION:
Material is not known to polymerize.
VIII. HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS:
Store away from heat and separate from alkalies, aluminum, zinc and other metals. Protect from
atmospheric moisture. Storage areas for drummed material should have adequate drainage. Storage tanks
should be vented and diked. FOR INDUSTRIAL USE ONLY.
IsleChem
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MSDS NUMBER: M105
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE 1/27/06
IX. ENVIRONMENTAL PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Soak up with vermiculite, sand, earth or other absorbent material and place in marked lined steel container
for disposal. Neutralize with soda ash. Flush spill area with large quantities of water. Pump large spills
into marked containers for disposal or reclamation.
WASTE DISPOSAL METHOD:
Product should be completely removed from container. Material that cannot be used or chemically
reprocessed should be disposed of in accordance with all local, state and federal regulations. Incinerate in
RCRA permitted equipment designed to handle oxides of phosphorus as combustion products or send to a
waste disposal firm. Empty containers should be disposed of in a manner meeting government regulations.
X. ADDITIONAL INFORMATION
OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the
hazards of chemicals by means of a hazard communication program including labeling, material safety data
sheets, training and access to written records. We request that you, and it is your legal duty to, make all
information in this Material Safety Data Sheet available to your employees.
To aid our customers in complying with regulatory requirements, SARA Title III hazard categories for this
product are indicated in Section I. If the word "YES" appears next to any category, this product may be
reportable by you under the requirements of 40 CFR Part 370. Please consult those regulations for details.
This product contains a toxic chemical or chemicals subject to the reporting requirements of SECTION 313
of TITLE III of the SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 and 40 CFR PART
372. (See Section III, List Legend 08).
XI. PREPARATION INFORMATION
For additional Non-Emergency health, safety or environmental information telephone (716) 773-8438, or
write to:
IsleChem, LLC
2801 Long Road
Grand Island, NY 14072
For Emergencies: 24 HOUR EMERGENCY PHONE: 1-800-424-9300
To request an MSDS: 716-773-8438
IsleChem
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MSDS NUMBER: M105
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE 1/27/06
WARNING LABEL INFORMATION
SIGNAL WORD: DANGER
STATEMENT OF HAZARDS:
LIQUID CORROSIVE
CAUSES IRRITATION OR BURNS TO THE SKIN, EYES, RESPIRATORY AND DIGESTIVE TRACTS.
PRECAUTIONARY STATEMENTS:
Keep container closed.
Insure adequate ventilation or use an approved respirator.
Avoid breathing vapor.
Do not get in eyes, on skin, on clothing.
Wash thoroughly after handling.
Use goggles, impervious clothing and rubber shoes.
Reacts with aluminum, zinc, and other metals liberating flammable hydrogen gas.
FIRST AID:
FOR EYES:
OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION. IMMEDIATELY
flush eyes with large amounts of water for at least 15 minutes forcibly holding lids apart to ensure complete
irrigation of all eye and lid tissue. Washing eyes within one (1) minute is essential to achieve maximum
effectiveness.
FOR SKIN:
SEEK MEDICAL ATTENTION IMMEDIATELY. Flush thoroughly with cool water under shower while removing
contaminated clothing and shoes. CONTINUE TO FLUSH UNTIL MEDICAL ATTENTION ARRIVES. Discard
non-rubber shoes. Wash clothing before reuse.
IF INHALED:
Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops,
give mouth-to-mouth resuscitation. GET MEDICAL ATTENTION IMMEDIATELY.
IF SWALLOWED:
DO NOT INDUCE VOMITING. This material is not soluble. DO NOT GIVE FLUIDS. If spontaneous vomiting
is inevitable, PREVENT ASPIRATION by keeping the victims head below the knees. GET IMMEDIATE
MEDICAL ATTENTION. A qualified physician can perform gastric lavage only when the airway (trachea) has
been secured to prevent aspiration.
IN CASE OF:
SPILL OR LEAK:
Soak up with vermiculite, sand, earth or other absorbent material and place in marked metal container for
disposal. Neutralize with soda ash. Flush spill area with large quantities of water.
FIRE:
Use dry chemical, foam, carbon dioxide or water spray. Use air supplied respirator and full protection
equipment. Fire will liberate toxic gases.
IsleChem
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MSDS NUMBER: M105
PRODUCT NAME: 2-ETHYLHEXYL ACID PHOSPHATE 1/27/06
HANDLING AND STORAGE:
Store in a cool, dry place separate from alkalies, aluminum, zinc and other metals.
DISPOSAL:
Product should be completely removed from container. Material that cannot be used or chemically
reprocessed should be disposed of in accordance with all local, state and federal regulations. Incinerate in
equipment designed and permitted to handle oxides of phosphorus as combustion products or send to a
waste disposal firm. Empty containers should also be disposed of in a manner meeting government
regulations.
INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS:
This product contains:
CAS# NAME
1070-03-7 Phosphoric acid, mono(2-ethylhexyl) ester
298-07-7 Phosphoric acid, di (2-ethylhexyl) ester
7664-38-2 Phosphoric acid
HMIS RATING SYSTEM: HEALTH 3 FLAMMABILITY 1 REACTIVITY 0
FOR INDUSTRIAL USE ONLY
For additional information, see Material Safety Data Sheet (MSDS) for this product.
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