1. Identification of the substance/preparation and the company.
Product
Trade Name: Statis
Code: MS011
Company
Manufacturer / Supplier: AgriGuard Ltd
Address: Units 1&2, Block B, Broomfield Business Park,
Malahide
Co. Dublin
Ireland
Telephone Number: +353-1-8462044
Fax Number: +353-1-8462489
e-mail: info@agriguard.ie
Emergency Telephone No.: 0870-600-6266 [UK National Poisons Control
Information Service (NPIS) Centre]
01-8379964/66 (Poisons Information Centre, Beaumont
Hospital, Beaumont, Dublin 9, Ireland)
2. Composition/Information on Ingredients
Component CAS No. Symbol Conc. % w/w R Phrases
Glyphosate in the form of its 1071-83-6 N 41 R51/53
isopropylamine salt
Inert materials including 61791-83-6 59 R22,R41,
Xn
ethoxylated tallow amines R51/53
3. Hazards Identification
Harmful if swallowed or inhaled.
MSR338/01 Page 1 of 7
4. First Aid Measures
Wash the affected area immediately with soap and water. Seek
Skin Contact:
medical attention if necessary.
Rinse out with plenty of water with the eyelid held wide open
Eye Contact:
and seek medical attention.
Immediately seek medical attention.
Inhalation:
Immediately seek medical attention.
Ingestion:
See part 11 for information on toxicology. The active ingredient
Further Information:
belongs to the amino acid phosphate group of chemicals.
For further advice on treatment contact the nearest Poisons
Information Centre.
5. Fire-fighting Measures
Suitable extinguishing media: Water spray, foam, carbon dioxide, dry powder or sand.
Fight fire in early stages if safe to do so.
Measures in case of fire:
Hydrogen cyanide, carbon monoxide and nitrogen
Special risks:
oxides may be released.
Special protective
Wear self contained breathing apparatus.
equipment for fire-fighting:
Contain fire-fighting water with sand or some such
Other Information:
bunding material.
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6. Accidental Release Measures
Personal precautionary measures:
Wear the personal protective equipment outlined in section 8. below.
Environmental-protection measures:
Keep the area isolated and do not allow contamination to enter drains or waterways.
Spillage or uncontrolled discharges into watercourses must be alerted to the National
Rivers Authority. If the product has entered a watercourse or sewer, or grossly
contaminated soil or vegetation in a public place, advise police.
Procedures for cleaning/absorption:
The spillage should be absorbed with earth sand or suitable absorbent material. Collect
in containers for disposal Compatible materials for storage: stainless steel,
aluminium, fibreglass, plastic, glass lining.
Incompatible materials for storage: galvanised steel, unlined mild steel,
All cleaned up product and cleaning materials should then be transferred to secure
containers and sent for disposal. Flush residues with small quantities of water.
7. Handling and Storage
No specific measures.
Handling:
Store in a dry area in the original containers, access should only be for
Storage:
authorised persons. Store away from animal foodstuffs, seeds and
fertilisers. Protect from temperatures >600C.
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8. Exposure Controls/Personal Protection
Personal protective equipment:
Respiratory protection: No special requirements when used as recommended.
Eye protection: Wear safety goggles conforming to BS 2092.
Hand protection: Wear nitrile gauntlet type gloves.
Industrial Hygiene:
Avoid contact with product. Immediately change contaminated clothing, dispose of if
decontamination is not feasible. Keep the work area clean and wash hands before
finishing work.
9. Physical and Chemical Properties
Form: Liquid
Colour: Amber-Brown
Odour: Slight amine
pH 4.4 - 4.9 @ 80g/l
Solubility in Water: Miscible
Stability Stable under normal Storage Conditions
SG/Density 1.172 @ 20C
Flash Point Does not flash
Auto ignition temp 443 oC
Other: N/a
10. Stability and Reactivity
None under normal conditions of use.
Substances to be avoided:
Stable at ambient conditions.
Further information:
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11. Toxicological Information
Acute toxicity:
LD50(oral, rat, male): 5,600mg/kg
LD50(skin, rabbits): >5,000mg/kg
Irritation of the skin/rabbit: Non Irritant
Irritant to the mucous membranes/rabbit: Eye irritant
Note: Symptoms of poisoning have not been recorded. There is no specific antidotal
treatment. Therapy should be symptomatic.
12. Ecological Information
Rainbow Trout LC50(96hr): 86mg/l
Aquatic toxicity:
Fathead Minow LC50(96hr): 97mg/l
Blurgill sunfish LC50(48hr): 120mg/l
13. Disposal Considerations
Dispose of product concentrate, diluted product and empty containers according to the
`Code of Practice for the Safe Use of Pesticides on Farms and Holdings' available from
HMSO. Do not re-use container for any purpose.
Contact the Local Council Authority for advice on the disposal of pesticide waste, or ask
an approved waste disposal contractor.
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14. Transport Information
UN proper shipping name: Environmentally hazardous substance, liquid, n.o.s
(contains glyphosate)
UN Number 3082
Road/Railway
Proper shipping name: Environmentally hazardous substance, liquid,
n.o.s (contains glyphosate)
UN Number 3082
Class: 9
Packaging group: III
Hazard Identification No.: 90
Inland waterways
Proper shipping name: Environmentally hazardous substance, liquid,
n.o.s (contains glyphosate)
UN Number 3082
Class: 9
Item: 11
c
Letter:
Hazard Identification No.: 90
Sea
Proper shipping name: Environmentally hazardous substance, liquid,
n.o.s (contains glyphosate)
UN Number 3082
Class: 9
Packaging group: III
Marine pollutant: P
Air
Proper shipping name: Environmentally hazardous substance, liquid,
n.o.s (contains glyphosate)
UN Number 3082
Class: 9
Packaging group: III
MSR338/01 Page 6 of 7
15. Regulatory Information
Hazard classification: Xi ?Irritant
N- Dangerous to the environment
R36 Irritating to eyes
R phrases:
R51/53 Toxic to aquatic organisms, may cause long term effects
in the aquatic environment.
S25 Avoid contact with eyes.
S phrases:
S26 In case of contact with eyes rinse immediately with
plenty of water and seek medical advice.
S35 This material and its container must be disposed of in a
safe way.
S37 Use appropriate containment to environmental
contamination.
Statis (contains glyphosate) MAPP 13079
Designated name:
This product is covered by the Control of Pesticides Regulations, 1986, and is labelled
accordingly.
16. Other Information
Text of R phrases mentioned in Section 2
R22 Harmful if swallowed.
R41 Risk or serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause log term effects
in the aquatic environment.
7th September 2005
Date of First Issue:
27th March 2009
Revision Date:
MSR338/01 Page 7 of 7
The information contained in this MSDS is designed to give general
Disclaimer:
health and safety guidance on the storage and transport of the
substance/preparation to which it relates. Requirements arising from a
Risk Assessment of the substance/preparation in a particular working
environment should take precedence over any of the guidance contained
in this MSDS where there is a difference in the information given. The
information contained in this MSDS is accurate at the date of publication
and will be updated as and when appropriate. Liability will not be
accepted for any injury, loss or damage resulting from any failure to take
account of information or advice contained in this MSDS.
Compiled in accordance with EC Directive 91/155/EEC.
MSR338/01 Page 8 of 7
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