Created on October 08, 2004
Reviewed on June 16, 2006
Page 1 of (8)
Material Safety Data Sheet ADIPIC ACID DIHYDRAZIDE
acc. to OSHA and ANSI
1. Identification of the chemical and manufacturer/importer/undertaking
1.1. Identification of the substance or preparation
Trade Name : Adipic Acid Dihydrazide
EINECS : 213-999-5
CAS : 1071-93-8
Formula : C6H14N4O2
Mol. Weight : 174,2
1.2. Identification of the manufacturer/importer/undertaking
Manufacturer : Carboshale O?br>
Address : Akadeemia tee 23A
12618 Tallinn, ESTONIA
Phone : +372-670 3645
Fax : +372-656 0159
Emergency Contact : Estonia: Call 112
USA : CHEMTREC, call 800 424 9300
2. Composition and information on ingredients
2.1. Description
CAS Name of Content of dry EINECS Warning symbol,
Number ingredient weight Number R-phrases
Adipic Acid
1071-93-8 100 % 213-999-5 Xi, R36/37/38
Dihydrazide
3. Hazards identification
EMERGENCY OVERVIEW
Caution! The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
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Reviewed on June 16, 2006
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Ingestion: May cause irritation of the digestive tract. The toxicological properties of this
substance have not been fully investigated.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance
have not been fully investigated.
Chronic: No information available.
4. First aid measures
4.1. After inhalation
Supply fresh air. If required, provide artificial respiration Seek immediate medical advice.
4.2. After skin contact
Immediately wash with water and soap and rinse thoroughly. Remove contaminated
clothing. Seek immediate medical advice.
4.3. After eye contact
Rinse opened eye for several minutes under running water. Seek medical advice.
4.4. After swallowing
Seek immediate medical advice.
5. Fire fighting measures
5.1. Suitable extinguishing agents
Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or
alcohol resistant foam.
5.2. Special hazards caused by the material, its products of combustion or resulting gases
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
5.3. Protective equipment
Wear self-contained respirator. Wear fully protective impervious suit.
6. Accidental release measures
6.1. Person-related safety precautions
Wear MSHA/NIOSH (approved or equivalent) protective equipment. Keep unprotected
persons away. Ensure adequate ventilation.
6.2. Measures for environmental protection
Do not allow material to be released to the environment without proper governmental
permits.
6.3. Measures for cleaning/collecting
Ensure adequate ventilation.
6.4. Additional information
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Reviewed on June 16, 2006
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See Section 7 for information on safe handling. See Section 8 for information on personal
protection equipment. See Section 13 for disposal information.
7. Handling and storage
7.1. Handling
Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure
good ventilation at the workplace.
Information about protection against explosions and fires: No information available.
7.2. Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers.
Shelf life:
In closed package for 2 years.
8. Exposure control / personal protection
8.1. Additional information about design of technical systems
Facilities storing or utilizing this material should be equipped with an eyewash facility and
a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1071-93-8: none listed
8.2. Personal protective equipment
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs,
beverages and feed. Remove all soiled and contaminated clothing immediately. Wash hands before breaks
and at the end of work. Avoid contact with the eyes and skin.
Breathing equipment:
Use suitable respirator with filter against fine dust and ammonia when packing, unpacking, loading or
otherwise being in the same room with larger quantities of open product. A respiratory protection program
that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be
followed whenever workplace conditions warrant a respirator's use.
Protection of hands
Wear appropriate protective gloves to prevent skin exposure.
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Reviewed on June 16, 2006
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Eye protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166.
Body protection
Wear appropriate protective clothing to prevent skin exposure.
8.3. Additional information
Chemical Name ACGIH NIOSH OSHA - Final PELs
Adipic Dihydrazide none listed none listed none listed
9. Physical and chemical properties
Physical state, color and odor: White odorless powder
Molecular Formula: C6H14N4O2
Molecular Weight: 174.2
Information on changes in the physical state:
180-182 oC / 356-362 oF
Melting point/Melting range
Boiling point/Boiling range Not available
Sublimation temperature / start Not available
>150 oC / 303 oF
Flash point
360 oC / 680 oF
Ignition temperature
Decomposition temperature Not available
Explosion limits:
a) Lower: Not available
b) Upper: Not available
Vapor pressure: Not available
700 (kg/m3) 4,6 lb/gal
Bulk density:
Solubility in water: 50 g/l; 0,1875 lb/gal
pH value @10g/l, 20oC:
0,083lb/gal @ 68篎 9,5
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Reviewed on June 16, 2006
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10. Stability and reactivity
10.1. Thermal decomposition / conditions to be avoided
Decomposition will not occur if used and stored according to specifications.
10.2. Materials to be avoided
Oxidizing agents, strong bases.
10.3. Dangerous reactions
No dangerous reactions known
10.4. Dangerous products of decomposition
Carbon monoxide and carbon dioxide. Nitrogen oxides.
11. Toxicological information
11.1. Acute toxicity
LD50 (oral)mouse >5000 mg/kg
Primary irritant effect:
a) on the skin Irritant to skin and mucous membranes.
b) on the eye Irritating effect
Sensitization No sensitizing effects known
11.2. Subacute to chronic toxicity
Other than potential irritation (see above), no information on illness or injury from acute or
chronic exposure to this product is available.
11.3. Additional toxicological information
RTECS#: CAS# 1071-93-8 unlisted.
Carcinogenicity: CAS# 1071-93-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: No data available.
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known. No classification data on
carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12. Ecological information
12.1. General notes
Do not allow material to be released to the environment without proper governmental
permits.
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Reviewed on June 16, 2006
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13. Disposal considerations
13.1. Product
Recommendation:
Consult state, local or national regulations for proper disposal.
13.2. Uncleaned packagings
Recommendation:
Disposal must be made according to official regulations.
13.3. Additional information
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
14. Transport information
Not regulated as a hazardous material material for transportation.
DOT regulations
No information available
Hazard class None
Land transport ADR/RID (cross-border)
ADR/RID class None
Maritime transport IMDG
IMDG Class None
Air transport ICAO-TI and IATA-DGR
ICAO/IATA Class None
15. Regulatory information
15.1. European/International Regulations
European Labeling in Accordance with EC Directives
Product related hazard information
Hazard symbols Xi - Irritant
Risk phrases
R 36/37/38 Irritating to eyes, respiratory system and skin.
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Reviewed on June 16, 2006
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Safety phrases
S 24/25 Avoid contact with skin and eyes.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
S 28A After contact with skin, wash immediately with plenty of water.
15.2. National regulations
US FEDERAL
TSCA
CAS# 1071-93-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain
any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 1071-93-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed.
Canada - DSL/NDSL
CAS# 1071-93-8 is listed on Canada's NDSL List.
Canada - WHMIS
WHMIS: Not available.
Canadian Ingredient Disclosure List
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Reviewed on June 16, 2006
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Exposure Limits for CAS#1071-93-8. none listed
15.3 Information about limitation of use
For use only by technically qualified individuals.
16. Other information
The information contained on the MSDS has been compiled from data considered accurate. This data is believed to
be reliable, however, it must be pointed out that values for certain properties are known to vary from source to
source. Carboshale O?expressly disclaims any warranty expressed or implied as well as any liability for any injury
or loss arising from the use of this information or the materials described. This data is not to be construed as
absolutely complete since additional data may be desirable when particular conditions or circumstances exist. It is
the responsibility of the user to determine the best precautions necessary for the safe handling and use of this
material for his application. This data relates only to the specific material designated and not to be used in
combination with any other material. Many local regulations pertain directly or indirectly to the product's end use
and disposal of containers and unused material. It is the purchaser'' responsibility to familiarize themselves with all
applicable regulations.
Employers should use this information only as a supplement to other information gathered by them, and should
make independent judgement of suitability of this information to ensure proper use and protect the health and safety
of employees. This information is furnished without warranty, and any use of the product not in conformance with
this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the
user.
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