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MATERIAL SAFETY DATA SHEET
Date-Issued: 02/11/2005
MSDS Ref. No: 10
Date-Revised: 02/11/2005
Revision No: New MSDS
SPAL-PRO 2000 "A"
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SPAL-PRO 2000 "A"
PRODUCT DESCRIPTION: Part A of a two component poured polyurethane elastomer
PRODUCT CODE: SPAL-PRO 2000 "A"
PRODUCT FORMULATION NAME: SPAL-PRO 2000 "A"
CHEMICAL FAMILY: polyol
MANUFACTURER
Metzger McGuire Co. Inc.
557 Route 3-A
Bow, NH 03304
Product Stewardship: 800-223-6680
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS# EINECS#
6-METHYL-2,4-BIS(METHYLTHIO)PHENYLENE-1,3-DIAMINE 5 - 15 106264-79-3 403-240-8
N,N,N',N'-TETRAKIS(2-HYDROXYLPROPYL)ETHYLENEDIAMINE <10 102-60-3
Polyether Polyol 70 - 85 9082-00-2 --
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Gray viscous liquid
IMMEDIATE CONCERNS: May cause skin, eye, and respiratory tract irritation.
POTENTIAL HEALTH EFFECTS
EYES: "B" Component liquids, vapors, or mists are irritating to the eyes and can cause stinging, burning, lachrymation or tearing.
SKIN: Exposure of skin to this product may cause minor irritation, reddening, swelling, or blistering. In some individuals,
prolonged contact may cause rashed resulting in dermatitis.
INGESTION: Ingestion could result in irritation and corrosive action in the mouth, stomach tissue and digestive tract. These
irritations would likely be followed by vomiting and cramps.
INHALATION: When breathing high concentration of vapors for extended periods of time without adequate ventilation, a person
may experience dizziness due to a lack of oxygen, and should leave the area immediately. Respiratory track irritation may also
occur.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
EYES: Can cause severe eye irritation experienced as pain with excess blinking, and tear production, and seen as extreme redness
and swelling of the eye and chemical burns of the eye. May cause severe eye damage.
SKIN: Causes severe irritation with pain, severe excess redness and swelling with chemical burns, blister formation, and possible
tissue destruction.
SKIN ABSORPTION: None.
INGESTION: None.
INHALATION: Vapors or mist, especially as generated from heating the material or as from exposure in poorly ventilated areas or
confined spaces, are irritating and cause nasal discharge, coughing, and discomfort in nose and throat.
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SPAL-PRO 2000 "A"
ACUTE TOXICITY: Inhalation may result in respiratory irritation. Ingestion may result in gastric disturbances.
CHRONIC: There are no known chronic effects associated with this material.
CARCINOGENICITY: None.
MUTAGENICITY: None.
REPRODUCTIVE TOXICITY
REPRODUCTIVE EFFECTS: None.
TERATOGENIC EFFECTS: None.
MEDICAL CONDITIONS AGGRAVATED: No data available. Contact Env. Dept.
ROUTES OF ENTRY: Skin, eyes, and lungs.
TARGET ORGAN STATEMENT: Not yet Known.
CANCER STATEMENT: Not yet Known.
IRRITANCY: Not yet Known.
SENSITIZATION: None known.
WARNING CAUTION LABELS: Corrosive to the eyes and may cause severe damage including blindness.
COMMENTS HEALTH: No data available. Contact Env. Dept.
HEALTH HAZARDS: No data available. Contact Env. Dept.
PHYSICAL HAZARDS: None.
COMMENTS: None.
4. FIRST AID MEASURES
EYES: Flush with copious quantities of clean running water immediately and for at least 15 minutes. Follow with ophthalmic boric
acid solution and obtain medical attention immediately.
SKIN: Remove contaminated clothing and shoes. Wash affected areas with soap and water. If swelling or reddening occurs, obtain
medical atttention.
INGESTION: Give affected person one or two glasses of water and induce vomiting. Obtain medical attention.
INHALATION: Remove person to fresh air. Administer oxygen or artiticial respiration if necessary. Obtain medical attention.
ANTIDOTES: Not yet Known.
NOTES TO PHYSICIAN: Exposures require specialized first aid with contact and medical follow-up.
ADDITIONAL INFORMATION: None.
COMMENTS: None.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: > (300癋)ASTM D93
AUTOIGNITION TEMPERATURE: Not Determined
FLAMMABLE CLASS: Material will burn in a fire.
FLAME PROPAGATION OR BURNING RATE OF SOLIDS: Not yet Determined.
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SPAL-PRO 2000 "A"
GENERAL HAZARD: None.
EXTINGUISHING MEDIA: Dry Chemical, Carbon Dioxide, Chemical Foam, Water Fog or spray.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, Carbon dioxide, Nitrous Oxide, and HCN.
OTHER CONSIDERATIONS: None.
EXPLOSION HAZARDS: Closed containers could rupture explosively at elevated tempertures generated under fire conditions.
During a fire, gases of a highly toxic nature may be generated by thermal decomposition or combustion.
FIRE FIGHTING PROCEDURES: Use water spray to cool fire-exposed surfaces and containers. Fire fighters should wear self-
contained breathing apparatus in addition to emergency fire fighting protective clothing.
FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved
or equivalent) and full protective gear.
AUTOIGNITION TEMPERATURE: Not Established.
FLAMMABLE LIMIT: Not Established.
FLASHPOINT: > 300 degrees F. (ASTM D-93 Closed Cup)
FIRE EXPLOSION: Not Established.
SENSITIVE TO STATIC DISCHARGE: None Expected.
SENSITIVITY TO IMPACT: None Expected.
HAZARDOUS DECOMPOSITION PRODUCTS: None Expected.
COMMENTS: None.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: None.
LARGE SPILL: Absorb spilled material with saw dust, dirt, or other absorbent material. Sweep or shovel into open top containers.
Hose down spill area with detergent and water. Remove containers to a safe place and cover.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: None.
LAND SPILL: None.
AIR SPILL: None.
GENERAL PROCEDURES:
Clean-up crews should wear protective clothing, gloves, boots, and goggles. Respiratory protection is also recommended.
Absorb spilled material with saw dust, dirt, or other absorbent material. Sweep or shovel into open top containers. Hose down spill area with
detergent and water. Remove containers to a safe place and cover.
RELEASE NOTES: None.
SPECIAL PROTECTIVE EQUIPMENT: None.
COMMENTS: Dispose of by any standard method of disposal in accordance with good industrial practice and in compliance with federal, state,
and local environmental protection regulations.
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SPAL-PRO 2000 "A"
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Precautions: Keep containers tightly sealed. Keep containers away from heat source and/or open flames. Do not
store containers in open sunlight.
HANDLING: Use with adequate ventilation.
STORAGE: Keep container closed when not in use.
STORAGE TEMPERATURE: (55癋) minimum to (100癋) maximum
LOADING TEMPERATURE: (55癋) minimum to (100癋) maximum
LOADING/UNLOADING VISCOSITY: Not Available
STORAGE PRESSURE: Not Available
STORAGE PRESSURE: None.
STORAGE TEMPERATURE: None.
LOADING TEMPERATURE NOTES: None.
SHELF LIFE: 6 months.
SPECIAL SENSITIVITY: None.
ELECTROSTATIC ACCUMULATION HAZARD: No data available. Contact Env. Dept.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
mg/m3 mg/m3 mg/m3
ppm ppm ppm
6-METHYL-2,4-BIS(METHYLTHIO)PHENYLENE-1,3- [1]
STEL
DIAMINE
N,N,N',N'-TETRAKIS(2-
HYDROXYLPROPYL)ETHYLENEDIAMINE
OSHA TABLE COMMENTS:
1. Not established
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear safety glasses with side shields (or goggles) and a face shield.
SKIN: Wear rubber gloves, coveralls, and boots.
RESPIRATORY: NOISH approved organic vapor respirator for exposure of less than one hour. An positive-pressure air-supplied respirator
must be worn during spray applications or whenever long-term exposure is anticipated.
PROTECTIVE CLOTHING: Where contact is likely, wear chemical resistant gloves, a chemical suit, rubber boots, and chemical safety
goggles plus a face shield.
WORK HYGIENIC PRACTICES:
Avoid contact with skin as required by good normal hygiene practices.
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SPAL-PRO 2000 "A"
OTHER USE PRECAUTIONS: Safety showers and eye wash stations should be available. Employees should be trained concerning
the safe use of product.
COMMENTS: Other Protective Equipment: Safety showers and eye wash stations.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: None.
APPEARANCE: Liquid.
COLOR: Gray
pH: Not Available
PERCENT VOLATILE: None
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Available
BOILING POINT: Not Established
FREEZING POINT: Not Determined
MELTING POINT: Not Applicable
POUR POINT: Not available
SOLUBILITY IN WATER: Partially Soluble
EVAPORATION RATE: Not Established
DENSITY: 1.03 at (74癋)
SPECIFIC GRAVITY: 1.03 to 1.09 (water=1)
VISCOSITY: 1350 to 1520Centipoise at (74癋) Brookfield
MOLECULAR WEIGHT: Not Determined
(VOC): 0
OXIDIZING PROPERTIES: Not Established.
COMMENTS:
PHYSICAL STATE: None.
EVAPORATION RATE: Slower than ether.
DENSITY: Liquid Density: 8.78 lbs./gallon
COMMENTS: End Product Precautions:
This product, when properly mixed with a polyurethane system "A" componet or poly,eric diisocyanate, will create a polyurethane product.
Exposed polyurthane is considered to be a fire hazard and should never be applied without an approved thermal barrier.
10. STABILITY AND REACTIVITY
STABLE: YES
HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: Avoid high temperatures. Avoid freezing.
STABILITY: Stable under normal conditions.
POLYMERIZATION: None.
HAZARDOUS DECOMPOSITION PRODUCTS: None.
INCOMPATIBLE MATERIALS: Strong oxidizing or reducing agents.
COMMENTS: Conditions To Avoid: Temperature extremes. Container contamination.
11. TOXICOLOGICAL INFORMATION
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SPAL-PRO 2000 "A"
ACUTE
No applicable data.
EYE EFFECTS: The vapor, aerosol, and liquid are irritant.
SKIN EFFECTS: Not yet Known.
SENSITIZATION: No applicable data.
TARGET ORGANS: No data available. Contact Env. Dept.
SUBCHRONIC: No applicable data.
CHRONIC: No applicable data.
CARCINOGENICITY:
IARC: Not Established.
NTP: Not Established.
OSHA: Not Established.
CARCINOGENICITY COMMENTS: None.
MUTAGENICITY: No applicable data.
SYNERGISTIC MATERIALS: None known.
REPRODUCTIVE EFFECTS: No applicable data.
NEUROTOXICITY: Not Established.
TERATOGENIC EFFECTS: Not Established.
GENERAL COMMENTS: None.
COMMENTS: None.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No applicable data.
ECOTOXICOLOGICAL INFORMATION: No applicable data.
DISTRIBUTION: No applicable data.
CHEMICAL FATE INFORMATION: No applicable data.
GENERAL COMMENTS: No applicable data.
COMMENTS: None.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Disposal should be in accordance with local, state, provincial or national regulations.
FOR LARGE SPILLS: None.
PRODUCT DISPOSAL: None.
RCRA/EPA WASTE INFORMATION: None.
RCRA HAZARD CLASS: None.
GENERAL COMMENTS: None.
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SPAL-PRO 2000 "A"
COMMENTS: None.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Polyalkylamines, N.O.S.
PRIMARY HAZARD CLASS/DIVISION: Not Regulated
BULK FREIGHT CLASS: Compound Resin
OTHER SHIPPING INFORMATION: Freight Class Drummed: Liquid Plastic Material - NOIBN
CANADA TRANSPORT OF DANGEROUS GOODS
PROPER SHIPPING NAME: Polyalkylamines, N.O.S.
TECHNICAL NAME: Tetrahydroxypropylethylenediamine
PRIMARY HAZARD CLASS/DIVISION: Not Regulated
AIR (ICAO/IATA)
PROPER SHIPPING NAME: Polyalkylamines, N.O.S.
TECHNICAL NAME: Tetrahydroxypropylethylenediamine
PRIMARY HAZARD CLASS/DIVISION: Not Regulated
VESSEL (IMO/IMDG)
PROPER SHIPPING NAME: Polyalkylamines, N.O.S.
TECHNICAL NAME: Tetrahydroxypropylethylenediamine
PRIMARY HAZARD CLASS/DIVISION: Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
DOT LABEL SYMBOL AND HAZARD CLASSIFICATION
DOT Class 9
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: No data available. Contact Env. Dept.
FIRE: NO PRESSURE GENERATING: NO REACTIVITY: NO ACUTE: YES CHRONIC: YES
313 REPORTABLE INGREDIENTS: Not Listed
302/304 EMERGENCY PLANNING
EMERGENCY PLAN: Not Established.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: None.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: All of the components of this product are either listed on the TSCA Inventory or are not subject to the notification
requirements(exempt).
RCRA STATUS: NA = Not Applicable
OSHA HAZARD COMM. RULE: None.
CLEAN WATER ACT: None.
NATIONAL RESPONSE CENTER: None.
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SPAL-PRO 2000 "A"
CARCINOGEN: None.
FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): NA = Not Applicable
SDWA (SAFE DRINKING WATER ACT): NA = Not Applicable
FDA (FOOD AND DRUG ADMINISTRATION): NA = Not Applicable
DEA (DRUG ENFORCEMENT PRECURSOR & ESSENTIAL CHEMICALS) LISTED SUBSTANCE: No applicable data.
CLEAN AIR ACT
40 CFR PART 68---RISK MANAGEMENT FOR CHEMICAL ACCIDENT RELEASE PREVENTION: Not Established.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA)
29 CFR 1910.119---PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: Not Established.
CANADA
WHMIS (WORKER HAZARDOUS MATERIALS INFORMATION SYSTEM): This material is a marine pollutant.
WHMIS CLASS: Class D-2B: Material causing other toxic effects (TOXIC).
CANADA INGREDIENT DISCLOSURE LIST: Not Available.
CANADIAN ENVIRONMENTAL PROTECTION ACT: Not Available.
DOMESTIC SUBSTANCE LIST (INVENTORY): Not Established.
EUROPEAN COMMUNITY
EUROPEAN COMMUNITY REGULATORY: None known.
MEXICO None.
STATE REGULATIONS No data available. Contact Env. Dept.
CALIFORNIA PROPOSITION 65: None.
REGULATIONS
STATE REGULATIONS: No data available. Contact Env. Dept.
LOCAL REGULATIONS: No data available. Contact Env. Dept.
COMMENTS: None.
16. OTHER INFORMATION
REVISION SUMMARY New MSDS
NFPA CODES
HMIS RATING
* 2
HEALTH:
1
1
FLAMMABILITY:
2 1
1
PHYSICAL HAZARD:
PERSONAL PROTECTION:
MANUFACTURER DISCLAIMER: The information in this MSDS was obtained from sources that we believe are reliable. The information
is provided without warranty, implied or expresed, concerning accuracy. Isotec International assumes no legal responsibility for use or
relieance on this information. This MSDS is provided solely for the purpose of conveying health, safety, environmental information. This
MSDS is not a specification data sheet. Some of the information and conclusions are derived from sources other than test data on the material
itself.
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